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1
AITS-FT-IV-PCM (Sol)-JEE (Main)/14
From Classroom/Integrated School Programs 7 in Top 20, 23 in Top 100, 54 in Top 300, 106 in Top 500 All India Ranks & 2314 Students from
Classroom /Integrated School Programs & 3723 Students from All Programs have been Awarded a Rank in JEE (Advanced), 2013
FIITJEE JEE(Main), 2014
ANSWERS, HINTS & SOLUTIONS
FULL TEST – IV
(Main)
ALL INDIA TEST SERIES
S. No. PHYSICS CHEMISTRY MATHEMATICS

1. C A A
2. D C B
3. C B A
4. A C A
5. D D B
6. A D C
7. A D C
8. A D B
9. C D B
10. B D C
11. A A C
12. C A B
13. C C B
14. D C A
15. C B B
16. C A D
17. D D A
18. C C B
19. A D A
20. C C D
21. C D D
22. B D A
23. C C C
24. D D B
25. D A A
26. C C D
27. B D A
28. C C D
29. C A D
30. C D C
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
2
Physics PART – I
SECTION – A
1. Zero after decimal point is also significant.
2. a2  v12 t 2  v 2 t 2 A
a vt
t
a
v 2  v12 B C
v1t
3. 600  T = ma
600  360 2
amin   4 m/s
60
mv 0
4. mgt 0   mv 0
2
v0

2gt 0
5. Friction force on upper block is f = ma

So work done = ma  s
7. mu = m(v/2) + mv
 v = (2/3)u
u 2u

e  3 3
u
 e = 1/3
2 R 2
8. T
GM
R2
GM 4 2
 
R32 T2
GM 42R32
g 
R12 T 2R12
 dv 
9. m     6rv
 dt 
0.5 t
dv  1 
 
2
v
 6   dt
 18  
0
2 t
n   t = 3n4 sec
0.5 3
3
 mg  qE qE
12. T  2 where geff =  g
geff m m
13. Maximum will be corresponding to source position A B

and minimum to source friction B.
C 
3
2cos1    O
2 5
So, time interval = 
 5 A
18. VP  Vpindued  VPq  V0 P r1

kq kq O 
Vpinduced   O
r r1 R
r
16
20. vi  CV 2 …(i)
25
6
qi  CV ….(ii)
5
11
qf  CV …(iii)
5
16 1 
Uf   CV 2  CV 2 
2 5 2 
Charge flown from battery = CV
Work done = CV2
Heat produced H = U + W
 1 6 1  16  1
  CV 2  CV 2   CV 2   CV 2   CV 2
 2 5 2  25  2
21. As A and B will be at same potential so B

charge flown equal to Q. A Q
r
2 0I0  0I0
22. B  B 2A  BB2  
2a 2 2 a
   P
23.  
Using e  B  d   v 
So, e = BvR
R2 45
v
  /2
24. e 
 / 2
B(x)dx  0
4
1 q2 1
25.  LI20
2 (C1  C2 ) 2
q  L  C1  C2  I0
q L
q1  C1  C1I0
C1  C2  C1  C2 
Icoherent 4I
27.  2
Iincoherent 2I
29. Using Einstein equation

E = W + eV
o
12400 ev A
o
= 4.6 eV + eV
4
0.2  10 A
V = 1.6 Volts
5
Chemistry PART – II
SECTION – A
0.529
1. For H, rH  r3  r2    9  4
1
0.529
For Li2 , rLi2  r3  r2  9  4 
3
rH 3
 
rLi2 1
2. 2Cu2S  3O2 
 2Cu2 O  2SO2
Cu2O  FeS  FeO  Cu2 S
2FeS  3O2  2FeO  2SO2
FeO  SiO2  FeSiO3  Slag
4. This is a 3o and resonance stabilized carbocation.
5. Cumulated diene is least stable, evolve max heat in the hydrogenation reaction.
11. Number of revolution made by an electron per sec

 
 2 
v 2Ze
 n  
2rn   n2h2  
 nh  2  
2 
  4mZe  
42mZ 2 e4 42me4  Z 2 
   
n3h3 h3  n3 
Z2 1
  6.66  1015   6.66  1015
n3 8
= 8.3 × 1014
13. Vapour pressure depends on temperature not on size of container.
14. There is no intermolecular forces of attraction in ideal gases.
16. 3A  B 
 2C
1 dA  d B  1 d C 
r    K   A B 
3 dt dt 2 dt
dA 
  3K   A B   K  A B
dt
i.e. K  3K 
d C  2
So that  2K   A B  = K  A B 
dt 3
17. KP  PCO2 , which will depends temperature of the system only.
6
+ -
18. Water will be neutral as [H ] = [OH ]
20. Zinc is more electropositive than silver therefore, it displaces less electropositive silver.
21. Carnalite is a double salt KCl.MgCl2.6H2O which give test of K+, Mg+2 and Cl.
22. 2Cu2  2CN  2Cu   CN2

3KCN
Cu   CN  CuCN   K 3 Cu  CN 4 
23. Mass number change only by -particles and atomic number reduces by 2 unit by each -particle
and increase by 1 unit by -particle.
27. CH 2OH CH 2OH

H O OH
OH O O
H OH
H H
OH OH
H H
H
H OH H OH
Galactose unit Glucose unit
28. The 1st step is electrophilic addition i.e. rate determining step, more stable will be the intermediate
better will be the rate of reactions.
29. O CH2OH
,dry HCl O O O
CH2OH
CH2 C OEt CH2 C OEt
O
LAH / THF
O
O O
CH2
H
CH2 OH  

CH2 CH2 OH  EtOH
H2 O
7
Mathematics PART – III
SECTION – A
12 7!
1.  HHH , RR  , I,I, P,P  , AYU = C7   1  198  7!
 2!2!
x
2.  a  b   a  b   a  b 2  |a + b| = |a – b|
a a
 1  1
b b
a
 is perpendicular bisector of (–1, 0) and (1, 0)
b
a
 is purely imaginary
b
dV  t 
3.  K  T  t 
dt
2
K T  t
 V t  C
2
KT2
At t = 0, V = I  C  I 
2
KT 2
 Scrap value V(T)  V(t = T) = C = I 
2
2 3 2
4. 2  tan1 x     tan1 x   0
8

 tan1  x   
4
 x = –1
 t2  2 
5. lim 1
t   1 1 1 1
t  2   2  1   2   2  1
2
 t t t t 
Now ||x – 1| – 6| = k has four distinct solutions if k  (0, 6)
 Number of integral values of k is 5
xx
6. f x 
2
p2
7. Case–I: when  2  p  6 and f(2) = 8
2
P=2
p2
Case–II: when 2 p>6
2
8
2
D p  2   4  3p  2 
 8   8
4a 4
 P = 82 5
 p  8  2 5 and p  8  2 5 (rejected)
 Sum of values of p is 2  8  2 5  10  2 5  10  20
 m + n = 30
2 2
8. We have (x – y) + (y – 3) = 0
x=y=3
9. We have f(x) > f(2)  x < 2

 lim f  x   f  2   1
x 2
2
 a – 9a – 9  1
 a2 – 9a – 10  0
 a  –1 or a  10
But a is positive. Hence a  10. That is a  [10, [
Note that when a = 10
3  x, x  2
f x  
2x  3, x  2
So that f is continuous at 2, f(2) does not exist and f(x)  0  x  R. Therefore, x = 2 is a critical
point and f(x) changes sign from negative to positive at x = 2
1
10. We have a  b 
1
a
a
1 1
 a  b   and b  a 
1 1
a b
a b
1
 ab 
1
b
b
1 1
 a   b   (ab – 1)(a – b) = 0
a b
 ab = 1  a  b
1
 a  b    a2 – b2 = 1
ab
11. Probability that calculator of brand r is selected and is defective

6 6
7r  k  7r  r 2   8k
=  kr  
1

21  21 r 1  3
….. (1)
 Let Er denote the event that calculator of brand r is selected P(Er) = kr

Since Er(r = 1, 2, ….., 6) are mutually exclusive and exhaustive events we must have
6 6
1
r 1
P  Er   1   kr  1  k  21
r 1
8k 8 p
 required probability =  
3 63 q
 (p + q) = 71
9
2
12. P(r) = (2r + 1)
n 1 n 1
2
r 1
P r     2r  1  n
r 1
1
1 n2  1
  lim 3
2 n an  bn2  c
 a = 0, b = 2
So, (a + b) = 2
–1 –1
13. Let tan x =  and tan y =  then a tan  + b sec  = c and a tan  + b sec  = c
Obviously a tan  + b sec  = c has roots tan  and tan 
2 2 2 2 2
 (a – b ) tan  – 2 ac tan  + c – b = 0
2ac c 2  b2
 tan   tan   2 and tan  tan  
a  b2 a2  b2
xy 2ac
So 
1  xy a2  b2
14. lim e2
5
 x  x 2 

 2  1

1 
 e2 ln5
x o  
2x x  2 tan x 2
2 x
lim
  x
 e2  5   1  ex  1  2
e2
 e2 ln 5   ln5
x o 2sin x  1  cos x  2 2
x  x
x  x2 
=1
 1  3tan2 1º  cot1º  1  3 tan2 1º  1 1

15.  2   3  = 1
 3  tan 1º  cot 3º  3 tan1º  tan 1º  cot 3º tan3º cot 3º
1  sin2x 1/ x
16. lim  e2
x 0 1
2
17. f(x) = x + 3x – 2
x 3 3x 2
 f  x  dx 
   2x  c
3 2
4 3 2
18. f(x) = (x – 1) (x – 2) (x – 3) (x – 4)
f  1  f   2   f '  3   0
4 3 2 4 3
f '  x    x  1  x  2   x  3   1   x  1  x  2   2  x  3   x  4 
4 2 2 3 3 2
  x  1 3  x  2   x  3   x  4   4  x  1  x  2   x  3   x  4 
3
 f(4) = 3(6 )
19. a + ar = 12 ….. (1)

ar2 + ar3 = 48 ….. (2)
 r2 = 4  r = –2,  r  –1, 2
10
 3k  2 5k  3 6k  4 
20. P , , 
 k 1 k 1 k 1 
3k  2 13 3
 Hence  k
k 1 5 2
1 2a a2 1 p p2
1
21.   1 2b b2  1 q q2 = 2 · 21 · 22 = 812 = 8   4  16
2
1 2c c 2 1 r r 2
22. (a + b)x + (2b – 2a)y + (3b – 3a) = 0

a
 a + b = 0    
b
3
 y
2
2 2
 x  y  1 xy3
   
 2  2 
23.  1
10 5/2
2 2
Here a = 10 and b = 5/2 and centre is (1, 2)
 Locus of feet of perpendicular lie on auxiliary circle of ellipse
 Equation of circle is (x – 1)2 + (y – 2)2 = 10
 
 4; 0  x  2

 2   x  
 2
24. f  x  
0;   x  3n
 2
 3 
 2  x  2
 2
 Range of function = {0, –2, 4}
 a 

2 1  cos   1 b  c 
25.  tan   
2  1  cos 
  
 1  a


 bc 
bc a abc
=   a  b  c   a  b  c  1
26. 34 = 81
27. We have, cos2 x – (c – 1)cos x + 2c – 6  0  x  R

 (cos x – 2)(cos x – (c – 3))  0
 cos x  c – 3
c–31c4
11
28. px2 + qx + r = 0
2
rx + qx + p = 0 (on subtract)
 x = –1
So common root is – 1
p–q+r=0
29. [{x}] = 0
1
f  x    3  x7  7
1
 1 7 7
  
f f x    3  3  x
  7  7  x

–1
f(f(x)) = x  f (x) = f(x)
 f –1(50) = f(50) and f(f(100)) = 100
–1
 f (50) – f(50) + f(f(100)) = 100
30. Put a = 2R sin A, b = 2R sin B

2R sin B (sin2 A + cos2 A) = 2a
 2R sin B = 2a
b
   2
a

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1

AITS-FT-IV-PCM (Sol)-JEE (Main)/14

S. No. PHYSICS CHEMISTRY MATHEMATICS

5. Friction force on upper block is f = ma

13. Maximum will be corresponding to source position A B

18. VP  Vpindued  VPq  V0 P r1

21. As A and B will be at same potential so B

29. Using Einstein equation

4. This is a 3o and resonance stabilized carbocation.

11. Number of revolution made by an electron per sec

13. Vapour pressure depends on temperature not on size of container.

14. There is no intermolecular forces of attraction in ideal gases.

17. KP  PCO2 , which will depends temperature of the system only.

22. 2Cu2  2CN  2Cu   CN2

27. CH 2OH CH 2OH

Mathematics PART – III

9. We have f(x) > f(2)  x < 2

11. Probability that calculator of brand r is selected and is defective

 Let Er denote the event that calculator of brand r is selected P(Er) = kr

 1  3tan2 1º  cot1º  1  3 tan2 1º  1 1

19. a + ar = 12 ….. (1)

22. (a + b)x + (2b – 2a)y + (3b – 3a) = 0

27. We have, cos2 x – (c – 1)cos x + 2c – 6  0  x  R

30. Put a = 2R sin A, b = 2R sin B

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