Bs Ns * ( 5 solic UNNTDIN 19 energy, - MAme Ga = consr. Gi) adseroate molecules don't intercet wl clners Gi) ncadsorbed spectes/sihe. Cn mondiayer Max Cv) ads. fot =des take @equil. at equi). Ui Gas. (Cas Yo Cate o)= kab)” flac, vacancies Cy Ler Qy = total conc of sites Cz: CasfCe (-€)= Cv/ce ¢ Kas Anexp (AEA) ete. RT Ka- Ka solve tor © 5 ©> Kats kd tke Qa > -(Ea-Ea) = CAHne) Fer conc, Nore. CAT Fol “Cok ts, Note. Cr isconsr. Chemp. dep. bn Pey= dn C8) On ka Pmt ¥OnCr) Wnt \= Ge 2. Ga \ ag ete OTe er, TW thermo tonal cheriser BRON he RT when use paral o YHeagy's hows oe Note! Yuin (a) ~ Lame kU + =Ke(E)Ce wv kle 0 Cas Ch =¥ Table Sor Langmuir 3 paper ey Boctr? a Lectin 12. Mluthiconponent Langmuir Mace lc. kala (Cv) = kd Cae ae Ca-ECjs) Sitsy $ ACY Cea Cy + FCjs Ov = GE = 1-76; siteYbalance. ee to equi to) Ce=Cv Er Fy J On eal Kg sakads ge Cv gen 1 Cnn aKa Cae a kaj WZ byCy 1+ ZIG Gy Azu* 25 = 28 (dissec ice , cecupy Zsites)d ee Caz, Cy? = Sn = CKa2 Caz ) *Cv Gime Ce Tr CkneGra) FZ Gj 4— agian feb claser itive. 8A Crs = KaoCna "Ce Cos. Ka Ca Ce Cenon denom Sages Cat. Sequence =K_overa\ = katy Cv — ae Ars =AS AS SRS oo KeceCas — S3t> Rys = RS wer ="1G- (SE- Gc) eg tol c dissocicinonT=" molec hme ” dCs = ~1y dt Cas =fa—Ge doe Serle TA aere Yse= td Kppro x! eee -d@ To aw atv Stcmhorw Stok Oppre | (0) surtacd immeciately, adqusts te a yan. event to Keep Cas, Cas const CC¥ako (2) Ce ~ Const - Crs + Ces + Ge eons. Cas + Crs Veomb \F tar ra O= ACCas t Ces). py tC) — rar sain. tae Ce(Gr- Ge) K= Kee : Wah A/C Kae pv, Atte kei. a Rise Kke hoch (eat Le Temltin — Ref 13 314 eae nie gee re oes pee Oia... Con #02 Fa. Pin te ty ee + may ao) molrcrLartty of Uth ren te times Hratstcp must talee place te Ge overall rxae —_ .No ton = ANHs No + 3H25= &NHs > Ne + eae oe No+25= QNs 1 Nest HS SSN +S -2 Areca ans s NHS r HSS Nikses -2 as ris = NIES +S Nie St Hs Sys425 -2 Ne eh See Rael xo woke Corre pontsto re dcALneuung piip > conuntcih onvef verennt si Hes ta Cy C Cun Of) fea pales le kn kseKA Kkr Fer a let oF homog. Cal. rans CvY Ce \TRy Neterog vxns., Combi ne this wi made site balance we "ixn veloci hy” or lari “assumps @— Not in observables (A) Rn Ve locity. y rene the k's ond climemionLeas toasis | suppose ks << ke, ka | a= kee Kae (Cm OY "reduced generat Vb Ka Ce + Keele 2 soln | CY MARI = look at suit farce spectroscopically | Ad most abundantr wtermediatc. E.G — Cas is MARL lout ) AcUcil ct sites CoHeas) RxN Crem Wat & adsorp > On Ch.10 — > C+D overall a ArL=—al BOS BL okCALYGQ) (2) -MHAD EOL 09 Cr 0 ek = Re @ | m = aes Lr el cerol a (Ley 1 Ka(A)r Ke(B Kerk) = (Le¥ Kn CA Ke (8) Re also U fal ain OP rl u + KnCA) Kie( BD Ke(O) + Koo)” XfolLAt betel presure, depercimce 3 PP Atperndina Dissoc_Adsorp Ettr=P Hr ral = ane ¢ ErhTeE EL+H2 —s EYL EL (Rds) EYL tHe SP rad= kCEL, ‘aS: CPC ee eye) CEH) Ke ~ CEQ Kn = CHL\2 Kp = L) CEM). CNL) Gis T= k Ke CE) (Kn (Ha %(t0*)) ( Yeo)* =k Ou (2. Kiw 4 Ke t Get CEHC) wena & (ho) [F KeCE) + (ku (He) )! -_Ko(P) (Kuta) "2 1 keke kw’ (EY H2)*(.\" (DENoM )2 Actin 13 Young Talole, (for LHHW> R -surf rxn rds C= (luckr Ke) (Pare “S8 > AM Prods , adsorbed in wae Vdesorbclwie dissoc (I Ki + ISePs t Keli ie t= Cluneh > Cdiavirng for L gusup > K=_ka Keke - WH ediorphen roupy Ke Ke R+%* (4)