TCVN TIEU CHUAN QUOC GIA TCVN 301 : 2010 Xuat ban lin 3 THEP VA GANG - XAC BINH HAM LU'ONG BO - PHU'ONG PHAP PHAN TICH HOA HOC ‘Stoel and iron - Determination of boron content ~ Methods of chemical analysis: HANOI -2010‘TOWN 301 : 2010 Lei néi aay TOVN 201 : 2010 thay tné TOVN 201 : 1989, ‘TOWN 201 : 2010 do Ban Ky thuGttéu chun quée gia TCVNITC 17, ‘Thép bién soan, Téng cye Tiéu chudn Bo lvong Chit ivong ab ng, 1B Khoa hoe va Cg nghé cng bd,TIEU CHUAN QUOC GIA TOVN 301 : 2010 Thép va gang - Xéc dinh ham lwgng bo - Phuong phép phan tich héa hoc Steel and ion - Determination of boron content Methods of chemical analysis 1. Pham vi dp dung isu chun nay quy nh phuong php xe dink him long tng bo hose bo trong thép v8 gang kong tan rong at ki = Ham kong bo ts 0,0005 % an 0,1000 5 si dung phuong phap so mau Rade cht so mau = Ham tong bo ti 0,05 abn 2.00% si dung phuong phép chun 6 ain thé 2 Taiigu vign din Ct eu vgn dn sau rt en thiét ve vie &p dung teu chun nay, 86 v6 ce tl Kb vn din hina cng bé th dp dung phién bén dug nbu, BE voit eu vgn di Khéng gh nm o8ng BS th ‘ip dung phen bin méi nh, bao gdm ed cc sia a, bb sung (nu €6). TOVN 1086 1978 Hod ohdt— Phén nnd va hy niu moe a tinh ki TOWN 1811 = 2000 (ISO 14284 : 1098) Thép va gang Ly mbu vi chun bj mB thir oxo ih thanh phdn hoa hos 3 Quy inh chung 3.4 Ly méu va chun b| méu thi theo TEVN 1811 : 2009, 3:2. Tit cd cc nda chit sir dung phi c6 a8 th Hist hoa hoe. Trung hop khong ed, cho phép «dong log tinh hid ph ih, 8 tinh Kiét ea ec ha chit, theo TEVN 1058: 1978 AteTOWN 301 : 2010 33 B6i vbl ede nda chét dang King, vi dy ax loki (p = 1,18), ky RiGu (9 = 1,18) 8 eh 6D «44m ase cia dung dich c0 kn lygng riéng bang 1,18 giml & 20°C, ky hiGu (1 + 4) 6 chi ning {26 dung den khi pha long: 86 thu nhdt la phn th tich hoa cht dm dc edn ly tho ha la phan thé tich nue cn pha thém vo, ‘3.4 Néng ab phan tram (%) a8 chi s6 gam hoa chat trong 100 mi dung dich 3.5 Néng 69 g/l. d8 chi #6 gam hoa ehét trong 1 L dung dich 3. Dung can c6 46 chin xae an 0,1 mg. 3.7. 6 chi £6 sau du phdy cia KBt qua phan tch lay bing 96 cho 96 ele gid sai lbch ong Bang 2. 4. Phuong phap s0 mau 4.1 Ban chit phurong phap Phuong php da vae qué trinh chung et méu wb etanol ab ich bo dir dang elemety! bo. Axt orc aut hin sau Ki cho ext sunfire vao dung dich chung eft Bu, th dung WOH chinalzarin tao thanh phuc nop mau anh. Cuemg a mau phy huge vo nbng 4 bo rong dung ch mB 42 Twit bj, dung ey va thube thir 4.24, Thidt bj va dyng oy ‘Thiét bi chung eft (xe Hinh 4) bing thach nh hoe thuy th Khéng chia bo. Cho phép ding cc tht bi chug ct dong kde May so mau quang ain hoge phd quang kb Dung cu théng thug st dung rang pong thi nghibm ccHU DAN 1 Binh dn 23+ Ong si hi, 4 in 5 Ong roan is Hint 4 = Thidt bi chumg edtTCVN 301 : 2010 422 Thude thor 42.2.1 Axi unfuric p= 184, dung deh 3 + 2 Trude kl ding pha lam sgch bing céch chung cBt li val lin vi etanol Ding 10 ml etano vi 250 ml ext sunt; 42.22 Axi pheiporicp = 1,70, Trude kh dng ph am sech bing ech chung At lvl An vos fugu metic. Ding 10 ml uu mete vei 260 ml at phophor 42.2.3 Aattclonidie p= 118; 4.224 A bor 42.2.8 The lh conve, dung leh 1 % tong ext conde: 4226 Nat hidroxt, dang dich 0.1 M; 422.7 Hiro peoxt, dung sch 30%; 42.2.8 Kal nate cacbonat khan 422.9 Ruou metyic, 142.2.10 Chinalizarn, dung dich pha nh sau: ho an 0,012 g chinaizarn trong 118 ml nue bi thee ‘at sunure ln td ten 2 000 mi 422.414 Dung dich gu chudn bo Dung dich A: hod tan 0.5720 9 anit boric bdng mét It nude trong binh dinh me dung eh 1 000 mi ‘Tném nue aén vec, ric. 1 mildung dich chia 0.1 mg bos ‘Dung ach 8: chuyn 50 mi dung dich A vao inn nh me dung tich 1/000 ml thém aude én vach le. 1 mi dung deh 8 chia 0,008 mg bo. 422.12 ét kim ogi tng cha bo; 142.2:13 Bi thuy tinh node thach anh kong cit bo 43. Gach tin hanh (Cho 1 g miu vo binh 1 eda tit bj chung et thm 18 mid 20 ml dung dich ait sunnier bk bioh vo ede dn kde (xem Hh 1). Thing nse qua 8g sinh han 2b dun néng binh cho én ki mnBu tan nt Cothé ding ext photphoric a8 phan huy mi ‘Sau kim phn hy xong, ly binh ra km ngugl i cho tng got hdropscuit a oxy od dung ch “Turong hop hams kong bo 80,0005 % abn 0,005 5% dang tod bo dung dich mBu cho qua tinh phan tic tibp theo. Trudag hop ham lugng bo Wen 0,005 %, chuyén dung den mBu vo Binh ginh mae ung toh 26 mi thom nue bn vac, tc ky iby vo binh 1 phén dung den theo Bang 1TOVN 301 : 2010 Bang 1 Ham twona Bo, ‘hb eh dung dich ly | Kher wgna mba wong Ung vor % phan tich, phn dung djch iy phn tich, mi ° Tin 0006 aa 007 25 080 ‘Tren 9,01 a6 0,02 50 020 Tren 0,02 abn 0,04 25 0.10 Tren 0,04 aén 010 10 0.04 ‘Sau 66 cho wo bint 18 ml ant photphore, tien bi thu inh (hogethach anh ri ghd bin vi hi bi chung ct, Noting cho née vio ng sinh han 2, cho nude qua éng sinh hn 3. Hing bag dong xéng 426i au ra cia 6ng sinh han 3 181 dun Binh + cho a Kn tc nude inh ab chuybn Nt sang Sng ong (khong 12 mi én 15 mh ‘Sau kn chung cét nt nude 6 binh 1, ngting dun miu, cho chay qua éng sinh han 2 dng thoi brig sloh hin 3 vn dB nue chy qua shu e0. Chuyén nude chung cét duce vae ae tach anh hoi en plain va gia (Cho 50 mi ruou metylc, 7 ml dn 8 mi dung dich nati hidoxt vii bi thu tinh (node thach anh) ‘vo binh 4, Rot vdo ng naan kh 5 khong 3 ml dung ich nat hicronit. Ghép nh 4 v6 ht chung i dun néng tt cho én kh dung dich trong bin 4 chi dn lal mot nia. Nging cp nude eho dng ‘sinh han 2 i dun nhe chai Binh 1 va 4 Khong $0 min, Sau th glan 4, 18 cd bo eb nim & binh 4, [ging dun bin 4 va chung edt ttc rrgu mete to binh + sang, Sau 46 nglng dun Binh 1, mi ‘nude chay qua éng sinh han 2. Cho 0,5 g kal nat eacbonat va ton bo nati hiroxt & ng nga kh 5 ‘We Binh 4. Ghép Binh 4 vl ht bi chung vi dun nhe a chung cbt ton rug metyle sang bin 1 ‘bing nude cnuyén ton B9 Bn ong Binh 4 vao eb thach anh ode chen plain d8 amg nude chug ct duge & pi tren, “Twéng hop xée dinh lzgng bo hod tan trong axl. dem cb Khd dung dich trong cbe thach anh node ch platin rtp tue ibn nh nh pin dui ma ng en WY 8m & Binh 1 “Truéng hp xe dinh tBng ham kzgng bo, hal ai W c@n & binh 1 nur sau: thém nude vo bin én 250 ml, lc qua iy lo chdy chm kindng tan cing mt tbo iy foc, na bing née ri chuyén gidy ge cbng edn vao chén plain. Sy Kho, hod ro ri nung chdy vb Og kal nari cacbonat & 900°C an 950°C knodng 20 min, LAy Khoi chay ra bang 20 mi dung dch at photphorc. Chuyé dung dich thu age vio bint 1 va tpl ton bp qua trnh phan huy va chung ct nhu dl ve dung ach mB & phn frén. Np dung ach thu due v8o cécthach anh hee chén plain d& aung dung dich & tr wi aha,‘TOWN 301 : 2010 Hoa tan cn rong abe tach anh hee chén plain Rng S minute i cho tng got 1.5 mV al suntric CChuyén ton 66 dung dich th dupe vao binh gin mie dung ich 10 ra. Lam ngudi,thém nage bn veeh 18 Hc 7. Loc dung ach qua gy le KNd veo ec kné. Dang bg ht ky 4 mil dung dh oe vo inn ga mae dung tch 80 mi hem 40 mi dung leh chinalzarn,LAe, tam ngul. Sau 30 min, cho 0:2 ‘dung ech thie ()clorua doa bb anh hung cla ce ehét oxy hod (vid erm), thém rude dn vach ie va do 40 hép thy queng & bub s6ng 620 nm vér cuvé hich hep, Ding dung dich thi ohio kiém tra ty mu gang hode thép knéng cha bo va duge tin han dog thd hy mBu phn {ich lim dung ich so sénh 1b dung a8 thi chun, cho 1 st km ogi vio Binh cba 4, rt vo 48 1,0 ml (eel ip theo: 20; 4,0; 8.0; 80 va 10,0 mi dung leh teu chudn 8. 6 ln tha 7 Kidng cho dung dich eu chin ding am ‘ung dich kiém tra. Ghap binh 1 v6 Ne théng chung cét rt tén han tbs tue nt ab vi ms phn {ic mung king pha xi cn khong tan. V6i do Np thy quang do dupe dung thi chub 44 Tinh két qua Ham tung bo (@) tinh bing phn ram (%) theo e8ag thie: Trong 48 Ls kn trong bo trong dung doh mB, xe nh theo 6 th chun, inh ing gam: m —_knditrong méu, tong eng vb phn dung deh mau dem xe dn, nh Bing gam, Sal ech cho phép gina cae Két qua xc dinh song song Khong duge lem hen git sal lich cho phép néu @ Bang 2. Néu sai l8ch 1m hom th pal xe din lt. Kt qua cubi cng Ia trang binh ‘ng cia ba KBt qua xd dinh song song ‘Bang 2 - Sai lgch cho phép Haim lirgng bo, % [__Saligch cho pha, 96 uye aby [te 0,0008 an 0,002 ‘0,000 | tren 0,002 aén 0,008 0.0007 Tren 0,005 an 0,01 0,001 Tren 0,01 aén 0,02 .002 Tren 0.02 aén 0,05 | 0,004 Tren 0.05 dén 0,10 | 0.008 Tren 0,10 aén 0.25 oor Tren 0.25 aén 0.50 0.02 | 180 0.80 dén 9,00 0.04 Tren 1,00 a8n 2,00 I 0.08 |‘TOWN 301 : 2010 ‘5. Phuong php chiét so mau 154 Ban chit phuong phap Phuong phap dya vao phan Ung cia floroberat véi metylen xenh, chiét hop phic nubt hn v6r 1,2 dicloetan vi do 6 hap tu quang & lop hou co tal bude ng 978m, 5.2. Thidt bj va thube thir 524 Thiétbi end quang kb vi ce pu kien Kem theo Dung cu thong thudng si dyng trong phng thir ng. 6.2.2 Thube thor ‘et suntie p= Hidropeost, ung dich 15% m6 pha: Kal nat cacbonat khan, Koifforua KF. 24:0, pha dung dich nhuy sau: hod tan 150 g kal rua trong cfc ri pha long én +1000 rl. ng dung ich trong bin poyetien: (4, dng dich 2,5 Ms Metyen xanh, CreHeNsS013H.0, pha ding deh nhu sau: hod tan 37389 metyien xenh rong nude ri ‘halting én 1000 ml. Ly 100 mi dung den ny pa long dn 1000 mi: 41.2 dost; it bot Dung ae ou chun bor ‘Dung dich A: hod tan 0.5720 9 ax boric wl mt it nBéc rong binh gh mie dung tch 1000 ma, Them ute dén vach bite. t dung deh A choa 01 @ bo: ‘Dung sich 8: chuyBn 50 ml dng dich A vo binh ann moe dung teh 1000 ml, thém nue in vac, 1c kf 4 mi dung dich B cha 0,005 g bo. ‘4 kim loa knong chi bo Nat posit it (aunt FeSO, 7H.0. 53 Cachén hint 15.3.4 64 vb gang thép tan trong ax sunfire, ibn Kan xc nh ham ugg tng bo nh Sau | 10 |TOWN 301 : 2010 CCho 0.2500 g m&u vo binh thach anh, thém 15 mi dung dich ax sunt, 48y nit cao su c6 nf thdng ding voi éng sinh han bing khéng kh (ng thach enh di Khodng 35 em, auéng kin trong ‘knoding 4 mm). Bun ndng e& binh cing éng sinh hn tn bp efch thuy & nig a6 80°C bn 90 °C {én tan miu, Sau 40 cho tong giot 0.5 ml dung dich hicropeoxt qua 6ng sin han i tring thand éng bing it got au va al un tp khong 5 rin ‘Sau kh ngul, mnt va tng ng sinh han Bag It let nude «Boe dung dich qua phe bing chét «dbo v6 ly loc chy via va met it ot gidy te vo bin nnyao chia 50 ml va 100 mi, Ria gidy 4c cing b8 al ln bing nude ri cho v2o chén plain, cn thén sy va hod tro, ri nung chay W059 al nat cacbonat khan & 800 °C dn 960 °C trong 20 min. Ly Kh6ichdy ra bing nue. Sau Ki a8 gud nip vaobinh 6g nude ria va. dung dich & pha tn, kn ham lzong bo tr 0,0005 % dn 0,01: cho nude vo dung dich thu duge dén 50 mL Cho 10 mi dung dich kal flora, tbe va dB yén 2 h. Sau dé ding bng hit cho 10 mi dung dich metyen xen rb ‘thém nue an 100 ml, Thém 25 ml 1.2-ccloetan Bay binh ng nat nhva vale 1 min. ChuyBn dng lich vo ph chiét dung tch 150 ml. Chuyén Isp hau ou (Isp dus vo phy cht her 2 i ara bing ‘eh ibe vai chinh xc 10 ml nuée Khodng 30 8. Loe kip hu ea qua giy le Kno vito cb nha ko ‘Ong 6ng hut iy 5 el ung dich wae Binh dinh me dung tich 25 mi Thém 1,2- cctoetan én vech cb le va do do hép thy queng cia dung dich & bude séng 657 am. Dung dich so sé la dung dich thi ngiém, kim tra dg tién anh qua ttc cdc babe nhu adi vb mB phn ich vi 0,25 gat ki os ‘ni nam kvong bo t 0,01 % dn 0,1 5: eho 0,2 gst kim lei vo Binh thach anh, thénn 12 mil dung ‘ich ant sunfurie, dun néng ten bép cach thu cho tan ri oxy hoa bang céch cho 0,6 mi dung dich hiropeonit va dun ip 5 min, Chuyén dung dich th dug vo Binh nhac chia 8650 mt v8 100m ‘Chuyén dung dich méu thu duge te binh nya & tén vo Binh nh me dung ch 100 my, thém made bn vach rib Dang ng hut lly mot phn dung doh mau: 20 ml (ks ham luong bo Wen 0.0% én 0.05 5) hoe 10 mi (kh ham kzong bo tré 0.05 % dn 0,1 %) cho vo dung deh st trong binh nya, Tare hop fy 10 ml dung olen mu phi thm 15 mi dung dich at sunrie dB dat vor a9 ext cn thie ‘Sau 66 them nude vo dung deh tong binh potyetyien ain thd ten 50 ml pte tin Rann nh i ‘i miu 66 nam hong bot 0,005 % dn 0,01 %. Khi do 46 hp thy quang, ding dung ach thi gig kam tra thu due bing ech phan hy 02 gt ky lal tong 15 ml dung dich at sunfurc lam dung dch so sénh.B& tinh kN zomg bo trong dung dich mau, nh kt qu thu doe vl § (ki hat 20m dung leh nu) hoe wi 10 (ki ht 40m dung dich mi), hi xd¢ dh ham lagng bo od tan trong ant, hh tong ty nh xd din tng Bo tr phn x cn khéng tan ‘Truéng hop xe anh ham haong bo king tan tong ax, cho 0.25 g et kn lai vo bin thach anh. ‘Théo 1 mi dung dich at sunfuric. Bun dn tan 8 ony hod bing 0.5 mi dung dich hiropecxt. Bun {ham 5 min va sau ki ngul,chuydn vo binh plyeylen dng ich 260 miTOWN 301 : 2010 io tne 8 iy ee cong cn cia ms khong tan ong ax, Su Kc ra (xem phi xe in bo) 1 ho ro v8 nung chy wi 0.5 kali nat cacona. Ly Kc ra Bing nue vt ny ly met pn Pes tn b6 cng cen ph the vo ham hxong bo cho vo dung ch et ton (0.0005 % an 0.01% bo, 5.32 fi vor thép va gang khong tan tong dung dich asl surf, th ibn Ranh xe inh ha kr (6g bo nb sou un 0.2 9 sét Kim loa 6i 18 mt dung ch anit sunturictong Binh thgch anh dén tan, Thém 0. <9 en hropeont cu ip kong 5 min va sa Ki lam nau, chuydn dung ch va bin shy ung ich 280 Gi 0.25 9 miu vao ch nikon, cn than nung chy vi 0,109 all ai cacbonat vi 29 nat pox ‘Ay ih chy ra bing nude, chuyén vaobinh din mie ding ich 80m, tm re Abn vec hh oe dung deh qua gy le xp kh vo obc Kd. Dang bg hit ly mot phn dung dich mau, ext he Di elt suture ri ahp voi duna deh skim toa tong Beh ahve. Thém 0.5 gs) surat ‘Kh crm V), cho ue bn th tch 50 lh ip tye tn hh xc inh bony 6 phan Wen, 8 tp 08 ti ch, cho vo 8 binh thes ank, mB Binh 0,25 gs ki bi 15 mi dung deh an sunt rd rn bp ich thu an tan hod edn. Them 05 dung dich Hopson un sodng 8 min Sau thi ab gut huyln dung ce vo binhpottyen ding ch 260 mi, Cho 08. nat cacbonat khan va tui ty cho vio 7 trong 8 inh 0.5; 1.0; 1.5 2.0: 3,0;-40 v8 5,0 ml dung eh tieuchusn ‘Thém nude vao tt ccc binh dn th tch 50 mi, 10 rl dung deh kal forua va ip tc én han nr 261% dung oh mB Ding dung fh King cha dung cch tb chun bo lam dg deh ty aim dm i 5.4 Tinh két qua Ham iwong bo (8) tinh bang phan trim (4) theo cong thae: B= 100 Trong a6: 1m rong be rong dung den mBu, ac inh theo 0 thi cud, tinh ng gam; m —_kh6t ong ma, tin bing gam, Salen 9 i nx og sng doen on ghana eng Bing 2Tovn 301 : 2010 66 Phuong phip chuin a0 aign thé 6.4 Ban chét phuong phép Phong phap diva vao qué trinh téch bo khdi ca nguyén 16 anh huding (sé, niken, crom, ‘mangan, ttan) trong dich kibm va xe dinh bo trong dung dich bang phuong pap chudn 6 sign th. Trude khi chun 46, didu chinh pH eda dung dich v8 6,9, théen manit va chun phe chit 180 thanh bing dung éich nari hidrox abn 46 pH = 6,9 ban au, 6.2 Thiét bj va thube thir 2.4 Thiéto} May chudin 40 lén thé May Khudy tr Dung eu thing thing ek dung trong phong thd nghiém, 62.2 Thude thir ‘Asi elohydric (p = 1,19), dung dich 1 +1 v8 1+ 10; Hiaro peoxit, dung dich 3% moi pha Bari hidroxt, Ba(OH)s 84:0, dung dich 5% pha nhu sau: hod tan 50 @ bari hidoxt trong nude Bi pha loan dén 1000 ml Nate hldrout, dung deh § M, 0,1 M va 0.2 MA. Pha dung dich 0,1 M nh sau rot 10 ml bn 15 ml ‘dung dich hidroxt bart vao $000 mi dung dich nar hidroxit 4 g/L, khuby va dB King ta qua nay. ‘Ding dung dich chudn axitcohidrie 0,1 M kibm tra lal ndng dO cia dung dich Wen, Pha dung dich nati hidroxit 0,02 M nu sau: phe logng dung dieh nat hidroxt 0.1 M bang nude 3 avoc dun $011 h va a8 ngudi theo ty 18 1+ 4 180 chudn cia dung dich duoc xe dinh nr sau: cho 5 mi dén 10 mi dung dich teu chudn bo va 6c dung tch 400 mi, thém 250 mi nude. ua dung dich vao may chun & din thd. Vira khuby via cho dung dich nati hidroxt 0,1 M én Khi pH dat gn 6.98 dng microburet cho dung dich nati hidroxit 0,02 M dén chinh xe 6.9. Thém 30 mi dung dleh manit (lac nay pH eda dung dich ‘idm xung). Dung dung dich nati hidroxt 0,02 M chudn &@ dén pl dat 6,9. D6 chuan eta dung lich nar hidrexit 0,02 M () tinh bang gam bo trong 1 mi dung dich theo cng thi: 7 _¥«00004 ws “rong a: 2.0004 dng 46 bo trong dung dich tgu chun, tinh bing gam tén mit; v {hi tich dung dich ti chuain bo ly dem xe dinh, tinh bing mit vs {th tich dung dich nat hidroxt 0,02 M teu hao trong khi chun 46, tinh bang mi 8‘TOVN 301 : 2010 Ait bore: ‘bung den teu chub bo: nod tan 2,2880 9 axt bore Bang nude trong Binh dh mae dung teh 1000 mi, thém nue dn vach le. 1 mi dung dich chia 0.4 mg be damanit, dung dich B80 hoa Kali natn cacbonat kan; Metyl da cam, dung dich 0.1 % Etylendiamintetraaxetat nati (EDTA), dung dich 0,008 M. 6.3. Céch tién hanh -Tuy ham trong bo by khbi Kwong mau theo Bing 3. Cho Khbilzong mau vo bin tam ge dung tien 250 ml Day Binh bang nit eao su cb 15 nb thing dng vai bg sinh han bing khéng Kh. Bing 3 -Kndi wong miu Tm wong bo] Rama ‘Trén 0,05 dén 0,25 2.0 Tron 026n 100 ‘a | _ Tan ton 290 os ‘Qua migng éng sinh han, r6t 20 mil xitclohirc, dun néng dén tan mu, thém 10 mi én dm ‘dang dich hiropeoxt ri dun 861 khodng 10 min. Thwbag hop mu Khdng tan Hel we ‘dung ‘le tua oidy loc chdy ehbm cing moti bgt ety loc. Roa gidy Inc cing cn bing dung deh ex Goniarie 1» 10 v8 nude néng. Nhép nude rita voi dung dich ee. Cho gi lc cong cn veo che plat, fy, abt va nung chy v6t 0,59 Kalina eachonat& niet db 200 °C dén 950°C. Sau it vou y td chy ra bing 20 mi an 30 mi gung chet oi 1 +1 rip wt dura dh lo Cyn ding deh mu vo bane mc dng teh 000m hem ate dnb sh 300 i 40 meh tng dich nati Next bn Kt tia Bobn tn st (i) rot vc King 29 hn 40m lm tang den, tem nue dn vach te Lge mot pin dong ch cua gy ae KP v2 Binh KN. Ly 2507 dng do lo ve cbc dng ten 400 mi thm It got met cam va cho dung sen ant coh ++ Sd au eit, Sau & cho 5 ml dung dich EDTA. Bun si dung dich 3 min dn $ min & tim ngud tug en on may chun ai th, Khuby, tem ding dh ra hiro dn ti pH gn dt 9 v8 pure hd dung deh nati Ndr 002 M dln pH hinh xc 6.9. Cho vo dung de 20 mung den ma {tc nay pl iim 08g chun ong dung sch rai iro nH pH = 6). 6.4 Tinh kat qué vom ong b(t ing rn) cng TW=¥) 100 “TOWN 301 : 2010 Trong 46 V_thbtich dung deh nt idroxit 0,02 Mtb hae ki chun db Gung ach mu, tinh ng i Vi th ch dung den nat Narot 0,02 4 teu hao ki chun 86 ung oh tt nghigen Kim ‘ra toh bang mii Tb chun dung dich nat hiseout 0,02 m ——_kbiivong méu, tinh bing gam Sal lech gi han gida de két qua xe alah song song khong duge lem han gle tr aa léch che phép nd & Bing 2 6