__PREFARATION OF ETHENE cumovcrrenosim (penydration. of ethanol) Ethene a (CoHy) As the Ala03 ats roms hot, the heat reaches the ethanal © end of Wooiltrig tuloe . Etanoi changes +o vapour+ passes aver hot Al2Os. Dehydraitd to form Ethene. - FUSt Feat tude Consists maimy of ai, So iS discarded . Combustion>burns w/yelloun;tuminousetlame uttle SOT. ~ Jurns timewoator MiKY Possible Errors )\, % precautions) tS * COtalUSt Mant Not We Mot enough. K Arrangement of Alz0; wii Arrow some ethanol t escape widut OUCH he Cotdlyst,— ¥ Remove tube OUrL oF tne water efore burg Burke OUKTEr OFF. ae y(tes For_unsaruraron > Fthene gas will change Grommenwarer trom ‘red tO colourless. Will Change acidieredeKMAOW SoLtion from PuUrPIe tO COLOUTLESS.2012 Q2. (e) when ethanol converts to ethene ,a 60! Yield con be expectad. asvuming Haid Yreld, Whak Ws He Max noc! FH cm? test twloes of ethene gas tat would Loe collected @ room tampa pressure when 2-4 cn? OF ethansl, donsity O-&Gcm™, react ? Balanced FaN> CHs0H— CrHu+ Hid mass of ethranel wied = GEMM ERA ——mass= density x vol 142 O€ x 2-4 = 1-91g ethandl No. of moles ethanel = aE = 0-042 mole From loalanced eqn , A mole ethanol > 4 mole ethene 0-042 mole etandl > 0-042 mole etnene = Q:0U2 x 2UL = 1-008 L = 100% em? Rut eld iy ony 64> — yoL. of ethene = bOF>¥ 1008 = bOU-Gom’ = To. OF task hubes > bie > & eet tuboes .| bees ETHYNE (ACETYLENE) Cnc. so QH:.0 > Ca(OH}o+Cr Ho Caluum corbide: sreyswuMeYsotid - Fizzed when wot added. LD white sold formed. (Calaum hydroxide) FIOSK Gers WOM PexotnemMie 1 AudifredsCuSOy -> removes IMPUTINesct Clove safety tube an a hot Pale \ Sieam distillation separation process to (SOICTEUOMIPOUIAGS © iemnPs ¥ decomp. temps. DONC by HOUIAANIAg STEAM tincugn the matenal « dugilling: Of ammMsctare hquids . SOFeNY TUNE 'STOPS build Up Of pressure GUE vo SieaNy SHON) +O? Collects tug water +0 stop it thing the HOSK Contarning Cloves . 02509, pure agane lq ota > SE x 100= 4-95%s _ a disnillate collected: Wo, w/-rrMagmenlome eugenoiacan bekextOtd by S USING ayclonexamne! a Percentaye Yield: 20.09 plot matenal hoo Uses “OAMISEPMIRS, FlovouNng, perfumesVGENOL— SOLVENT &X A cytionA. Li wiclave al SeParating IE : | annudeus : O Keiten | IO « ‘aa im woe gy fea . vt Fit Locka WHO Aqusous ayer th x rape cucioner. wales Age BOE! S Magnesia suitGle Clumps. AS hy) fens omy Lf —— lousy | | / CY¥CIONEX. —_ 3 jess N we | 3 Sou. contowns foe \ |} WY, “ave on ae @BCIONEXANME = Mon=pOldr ’- doesn't thx wi H20 VAS dense thon H20 R. Separating Funnel = ‘washing’ > shake funnel *10 , ExtracRd clove cit From 8g clever by Steom dist, 4 @rreasrasiwosingsmecded 10 get Max omt eugenol, Solvent exnocnion «got 0-7g uve ci. Cale fo EMUNSION LECOMES IGS MIIKY b/c oil 19 eG erracled Original Clivey g-ax100 _——— From emuis. by d\SselVvinng Fins Oil an Cyclolex . ail in cloves = 5 = Yo (RYOONESTUMVESUNEORE = ArUINqHageNt3CaHag—C-ONdt + HOCH Dishib Most Of ervranel LiaeS orahuN OF sca” Caster ) | ie POUT CONS OF FAS wiv CONC. NOLL Sol. Linn) 0 {QAP GORINMTAIGOIVE INV SaWISOH: *- Precipitaatas Gut CrHas— C-O— Cs Filter off Soap residue ¥ WON Wi Str Sole coid water FxCQSS tel, Hast stay ia sol. Cas Cis Has (O0)a+ 3NaQH= Cols (OW + 3Cabas COONBr — REACTION OF HCL with NDOb > Qvdid SpiasMINg: LOSS OF UY= Ud: prevent heat loss Wudrocnione acd (4.0m) heat Given Out =(MGSSRSInICIseMeNAIsE Sodium nydroude (1.0M) = mx C x Cta-ti) M= Mss 1 Kg Procedure C= SpeciFIC Heat cap. J kg'K™ to-b, = FeMP. riSe. Known vol. of HCL+NQOH placed in diff cups Both Soluhony Stand unrweremprisiequelt Temp. recorded . HCL quickly added tO NaOH . Lid immadiaioly piawd . Srirred conninususly Max tenp recordod.> neat change uMen the no. oF metus OF reactants UnduccuRd Un the balanced eqn neact conpiorelig CALCULAHING Wear OF Keaction 50cm} 4-0M HCL 50 con® 4 OM NadH . No. mols OF Acid nounaused: Volxmolanty » 50%! _, 0:05 males 1000 1000 Tot. heat cop = 4205 kK", temp T= 69°C. heat released = Cx (tr-t.) > 420% 6-7 > ASi4 Joules > 2-14 kJ neat of xn: NaOH t HCL — NaCl + H.0 0-05 mol HCL releases 2814 kK) when noutraised. A mol would release 254+ = 56.28 kJ b exothermic mn * AH = -5b-28kdKEACTIONS = ETHANAL ACIDIFIED POTASSIUM PERMANGANATE H 0 --ll - heat, erin Pree onineeinecond H-C-C-H_ ——> t= be PUTPLA dYSdPpcarS fle Me™ ions ef _ e) Wave een reduced > Win ions Ls: \ RePeCIt W) propane: Mn0u +$HT+5E— Mn>* + 4a NO COUNE Chiaunnge. Ketones ore Nor OXIdUS WY ParaMUM ReMAaNqainde. FEHLING'S REAGENT Fehung's teagertt Oxidises Ethanal. neat 1 Cu’ ions have been Feduced> Cut ins bby ethanal — | etnanal+ nck Cu*4+e7 —> Cut Fehlings = Ped. . lus red)TOLLEN'S REAGENT (ammomacal shee futrate Agt+e — > Agv colourless Shuny stlver Tollens reagent > SiiveraniraKes dilute sodium hydroxide % ammo solution