M ABDURAHMAN AZIZ

3335160048
Perpindahan Massa QUIZ DESTILASI

Destilasi MultiKomponen Minimun dan Maksimum Total Reflux

F 1000 Mol/Jam
B 82 % 0.82 Destilat 0.18 Bottom
C 97 % 0.97 Bottom 0.03 Destilat
P 4 Atm = 405.3 Kpa

Asumsi Awal
Feed, F Destilat, D Bottom, W
komp
Xf Xf.F Xd Xd.D Xw Xw.W
A 0.35 350 0.581 350 0.000 0
B 0.3 300 0.409 246 0.136 54
C 0.20 200 0.010 6 0.487 194
D 0.15 150 0.000 0 0.377 150
602 398

Dew Point Di Destilat

Trial T= 67 C
Komp yi Ki ∝ yi/∝ xi
A 0.581 1.75 7 0.0831 0.3322259136
B 0.409 0.65 2.6 0.1572 0.6286736519
C 0.010 0.25 1 0.0099667774 0.0398671096
D 0.000 0.09 0.36 0.0000 0.0000
1.000 0.2502
Kc = ∑ yi / ∝i
0.2502
 ∝LD 2.6 (T 67 C at the coloumn Top)
∝LW 2.043 (T 132 C at The Coloumn Bottom)
∝Lav 2.305
Bubble Point Di Bottom
trial = 132 C
Komp Xiw Ki ∝i xi . ∝i yi
A 0.000 5.0 4.348 0.0000 0.0000
B 0.136 2.35 2.043 0.2772558444 0.3188442211
C 0.487 1.15 1.000 0.4874371859 0.561
D 0.377 0.597 0.519 0.1956521739 0.225
1.000 0.9603452043 1.104
Kc = 1/0,9603452 1.0412922307

Total Reflux
〖 [((𝑋_𝐿𝐷 𝐷)/(𝑋_𝐻𝐷 𝐷)).((𝑋_𝐻𝑊 𝑊)/(𝑋_𝐿𝑊 𝑋))] 〗 /log 〖 (∝_𝐿𝑉) 〗
∝𝐿𝑎�=√(∝𝐿𝐷∗∝𝐿𝑊)

Nm = = 5.978
√(∝_𝐴𝐷 ∝_𝐴𝑊 )
∝ A.av = 5.5167728437

Distribusi komposisinya komponen A

(𝑋_𝐴𝐷 𝐷)/(𝑋_𝐴𝑊 𝑊)=( 〖∝
_(𝐴.,𝑎�)) 〗 ^𝑁�.(𝑋_𝐻𝐷 𝐷)/
(𝑋_𝐻𝑊 𝑊)

XAD*D = 840.2922909359 XAW*W

XAF = 350 = XAD *D + XAW*W
350 = 840.2922909359 XAW*W +XAW*W
XAW*W = 350/840,2922909 0.4165217315
XAW*W = 0.4165217315
XAD*D = 349.583478268
 √(∝_𝐵𝐷
Distribusi ∝_𝐵𝑊Untuk
Komposisi ) Komponen B
(𝑋_𝐵𝐷 𝐷)/(𝑋_𝐵𝑊 𝑊)=( 〖∝
_(𝐴.,𝑎�)) 〗 ^𝑁�.(𝑋_𝐻𝐷 𝐷)/ ∝ B.av = 2.3050040083
(𝑋_𝐻𝑊 𝑊)

XBD*D = 4.5555555556 XBW*W

300 = XBD *D + XBW*W
300 = 4.5555555556 XBW*W +XBW*W
300 = 5.5555555556 XBW*W
XBW*W = 54
XBD*D = 246

√(∝_𝐷𝐷
Distribusi ∝_𝐷𝑊Untuk
Komposisi ) Komponen C
(𝑋_𝐶𝐷 𝐷)/(𝑋_𝐶𝑊 𝑊)=( 〖∝
_(𝐴.,𝑎�)) 〗 ^𝑁�.(𝑋_𝐻𝐷 𝐷)/ ∝ D.av = 1
(𝑋_𝐻𝑊 𝑊)

XCD*D = 0.0309278351 XCW*W

200 = XCD *D + XCW*W
200 = 0.0309278351 XCW*W +XCW*W
200 = 1.0309278351 XCW*W
XAW*W = 194.000000
XDD*D = 6.0000
√(∝_𝐷𝐷 ∝_𝐷𝑊 )
(𝑋_𝐷𝐷 𝐷)/(𝑋_𝐷𝑊 𝑊)=( 〖∝
_(𝐴.,𝑎�)) 〗 ^𝑁�.(𝑋_𝐻𝐷 𝐷)/ Distribusi Komposisi Untuk Komponen D
(𝑋_𝐻𝑊 𝑊) ∝ D.av = 0.4323042407

XDD*D = 0.0002055692 XDW*W

150 = XDD *D + XDW*W
150 = 0.0002055692 XDW*W +XDW*W
150 = 1.0002055692 XDW*W
XDW*W = 149.969
XDD*D = 0.031
 Destilate , D Bottom, W
Komp Feed Masuk
YD = XD XD.D Xw Xw,W
A 350 0.581 349.583 0.000 0.417
B (L) 300 0.409 246.000 0.136 54.000
C (H) 200 0.010 6.000 0.487 194.000
D 150 0.000 0.031 0.377 149.969
∑ 1000 1.000 601.614 1.000 398.386

Minimim Reflux Ratio, Number of Stages at 1,75 Rm and feed tray location
1−𝑞= ∑▒(∝_𝑖 𝑋_𝐼𝐹)/(𝛼_𝑖−𝜃)
�_�+1=∑▒(𝛼_𝑖 𝑋_𝑖𝐹)/(𝛼_𝑖−𝜃)
Shortcut Methode For Minimum Reflux Ratio for Multicomponent Distillation

log 〖
〖�_𝑒/𝑁_𝑠 〗 =0,206 log 〖 [(𝑋_𝐻𝐹/𝑋_𝐿𝐹 )𝑊/𝐷(𝑋_𝐿𝑊/𝑋_𝐻𝐷 )^2] 〗
Estimate of Feed-plate Location t = (67 +132)/2
t = 99,5 C

Component Xif Xid Ki (99,5 C) ∝ (99,5 C) Xiw

A 0.35 0.5814 3.12 5.2 0.0000
B (L) 0.3 0.4086 1.38 2.3 0.1357
C (H) 0.2 0.0100 0.6 1 0.4874
D 0.15 0.0000 0.28 0.467 0.3769
1.000 1.000

q = 0.27
(2,3 (0,3))/(2,3
(5,2 (0,35))/(5,2
(1−(0,2))/(1−−(0,15))/(0,467
𝜃)(0,467 𝜃)𝜃) − 𝜃)
Subtituting to eq. shortcut Method Reflux Ratio

1-q = + + +

1,82/(5,2
0,69/(2,3
− 𝜃) −0,2/(1
𝜃) − 𝜃)0,7005/(0,467
∑▒ 〖− (𝑠𝑢�)
𝜃) 〗
 ∑▒ 〖 (𝑠𝑢�) 〗
Trial And Error , so As a value of � = 1,210 will be used for the frst trial (tetha between 2,3 and 1)

Assumed �
1.6700 0.5156 1.0952 -0.2985 -0.5823 0.7300
1.66 0.5141
(5,2 (0,35))/(5,2 −(2,3 1.0781
𝜃) (0,3))/(2,3 -0.3030
(0,467 -0.5872
(0,15))/(0,467 − 𝜃) 0.7020
(1 (0,2))/(1
− 𝜃) − 𝜃)
1.6696 0.5155 1.0945 -0.2987 -0.5825 0.7289

1-q = 0.73

(2,3 (1 (0,2))/(1(0,467 (0,15))/(0,467 −1,6696)

−1,6696)
= (0,3))/(2,3
0.73(5,2 (0,35))/(5,2 −1,6696)−1,6696)+ + +

maka nilai � = 1,4017 kemudian disubtitusi dalam persamaan Rm

Rm + 1 = + + +

Rm + 1 = 0.5155223204 + 1.0945431472 + -0.2986857826 + -0.05825

Rm = 1.2531308908 - 1
Rm = �/((�+1)) 0.2531308908

Maka, R = 1,75 Rm
��/((��+1))
R= 0.4429790589

= 0.3069892499

= 0.2019987638

Dari grafk 11.7-3 nilai Nm/N yang didapatkan adalah Nm/N 0.48
N = 5,978/0,48
N = 12.4549737225
Dari persamaan diatas diperoleh jumlah stages secara teori dalam kolom destilasi yaitu sebanyak 12 buah
dari stages (12 - 1) dimana ada 11 tray yang ada di destilator
log 〖〖�_𝑒/𝑁_𝑠 〗 =0,206 log 〖 [(𝑋_𝐻𝐹/𝑋_𝐿𝐹 )𝑊/𝐷(𝑋_𝐿𝑊/𝑋_𝐻𝐷 )^2] 〗
untuk mengetahui lokasi feed yang masuk pada tray keberapa yaitu menngukan cara sebagai berikut:

log Ne/Ns = 0.3940380721

Ne/Ns = 1.4829570069
Maka : Ne = 1,482957007 Ns
Ne + Ns = N
1,482957007 Ns + Ns = N
Ns = 12/2,482957007
Ns = 4.0459702958
Ne = 7.9540297042

Jadi Feed Tray dalam Alat Distilasi berada pada posisi 7,954029704 atau TRAY 8 dari Atas (from the top)
Perpindahan Massa

DISTILASI KOMPONEN

F 100 Mol/Jam
B 95 % 0.95 Destilat 0.05
C 95 % 0.95 Bottom 0.05
P 4 Atm = 405.3 Kpa

Asumsi Awal
Feed, F Destilat, D Bottom, W
komp
Xf Xf.F Xd Xd.D Xw Xw.W
A 0.40 40 0.618 40 0.000 0
B 0.25 25 0.367 23.75 0.035 1.25
C 0.20 20 0.015 1 0.539 19
D 0.15 15 0.000 0 0.426 15
64.75 35.25

Dew Point Di Destilat Bubble Point Di Bottom

Trial T= 67 C trial = 132 C
Komp yi Ki ∝ yi/∝ xi Komp Xiw Ki
A 0.618 1.75 7 0.0883 0.353006 A 0.000 5.0
B 0.367 0.65 2.6 0.1411 0.564301 B 0.035 2.35
C 0.015 0.25 1 0.015444 0.061776 C 0.539 1.15
D 0.000 0.09 0.36 0.0000 0 D 0.426 0.597
1.000 0.2448 1.000
Kc = ∑ yi / ∝i
0.2448
∝LD 2.6 (T 67 C at the coloumn Top)
∝LW #DIV/0! (T 132 C at The Coloumn Bottom)
∝ =
Bubble Point Di Bottom
132 C
∝i xi . ∝i yi
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! 0.083
#DIV/0! #DIV/0! 0.620
#DIV/0! #DIV/0! 0.254
#DIV/0!