100 ml de ácido sulfúrico 0,2 N:

𝑚(𝑠)#𝑒𝑞 98 ×0.1 ×0.2

𝑁= → 𝑚(𝑠) =
𝑀 𝑉 (𝐿) 2

100
𝑚(𝑠) = 0.98 × 98

𝑚(𝑠) = 1 𝑔

𝑚 1
𝜌= 𝑣
→ 𝑣 = 1,84

𝑣 = 0.544 𝑚𝐿
V pH= 1

100 ml de hidróxido de amonio 0,1 M:

𝑛
𝑀=
𝑉 (𝐿)
𝑛 = 0.1 𝑀 × 0.1 𝐿
35.04 𝑔 100
𝑛 = 0.01 𝑚𝑜𝑙𝑒𝑠 𝑁𝐻4𝑂𝐻 × ×
1 𝑚𝑜𝑙 𝑁𝐻4𝑂𝐻 27
𝑛 = 1.297 𝑔

𝑚 1.297
𝜌= → 𝑣= → 𝑣 = 1.41 𝑚𝐿
𝑣 0.92

50 ml de ácido acético 0,1 M:

𝑛 = 0.05 × 0.1
60.05 𝑔
𝑛 = 5 × 10−3 𝑚𝑜𝑙 ×
1 𝑚𝑜𝑙
0.300 𝑔 𝐶𝐻3𝐶𝑂𝑂𝐻

0.300
𝑣 = 1.049
 100%
0.2859 × 5%

5.71 𝑚𝐿

50 ml de solución buffer (ácido acético-acetato de sodio trihidratado) (0,1M):

[𝑠𝑎𝑙]
𝑝𝐻 = 𝑝𝐾𝑎 + log[ ]
[á𝑐𝑖𝑑𝑜]
[𝑠𝑎𝑙]
4.7 = 4.8 + log[ ]
[0.1]

[𝑠𝑎𝑙]
−0.1 = log[ ]
[0.1]
−0.1 = log[ 𝑠𝑎𝑙] − log[ 0.1]
log[ 𝑠𝑎𝑙] = 0.1 − log[ 0.1]
[ 𝑠𝑎𝑙] = 0.079

𝑛
𝑀=
𝑉 (𝐿)

𝑛 = 0.0794 × 0.05
136.0343
𝑛 = 3.97𝑥10−3 𝑚𝑜𝑙𝐶𝐻3𝐶𝑂𝑂𝑁𝑎 ×
82.034 𝑚𝑜𝑙

0.5399 𝑔
Compuesto pH teórico pH experimental
CH3COOH 2.87 4
NH4OH 11.13 10
H2SO4 0.92 1
H2SO4 4.31 4