HITUNG KONVERSI

TEMPERATUR 340 C 613.15

TEKANAN 0.6415 ATM
C4H8 + 0.5 O2 --> C4H6 + H2O

ENTALPI 298 ENERGI GIBS 298 TC TR PC PR f/p

C4H8 -2.67 15.05 419.6 1.4612726406 39.7 0.0161586902 1
O2 0 0 154.58 3.9665545349 50.1 0.0128043912 1
C4H6 26.75 36.43 425.67 1.4404350788 42.7 0.0150234192 1
H2O -57.7979 -54.6351 647.13 0.9474912305 218.3 0.0029386166 1
-28.3779 -33.2551 kkal/mol

DELTA H = PRODUK- REAKTAN -28377.9 kal/mol

ENERGI GIBS =PRODUK - REAKTAN -15068.2051 kal/mol

Go
298
= - RT ln Ka,298
k298 12.7239114801

Ho 1 1 
lnK a 2  lnK a1    
R T
 1 T2 
ln ka2/ka1 -0.5887142506
ln ka2/ka1 0.5550404691
ka2 7.0622857968

s t
 f   f 
s t    
y y  P S P  (s  t  b  c)
K  S
b
T
c b
T
c
P
y B y C  f   f 
   
 P  B  P  C
ka f/p P
7.0622857968 1 0.8009369513

0.8282078678 82.8207867781

Awal reaksi kesetimbangan

C4H8 1 0.1717921322 0.0793825701 0.079383
O2 0.75 0.3358960661 0.1552125389 0.39397
C4H6 0 0.8282078678 0.3827024455 0.382702
H2O 0 0.8282078678 0.3827024455 0.382702
total 1.75 2.1641039339 1 4.683105
0.531113
x=0 -0.4688869661

Konversi 1-butene 85.82%

Konversi cis-butene 83.86%
Konversi trans-buten 82.82%