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Journal of Materials Processing Technology 179 (2006) 239–243

Porosity variation along multipass underwater wet welds and


its influence on mechanical properties
Ezequiel Caires Pereira Pessoa a,∗ , Alexandre Queiroz Bracarense a ,
Eduardo Maluf Zica a , Stephen Liu b , Faustino Perez-Guerrero b
a Federal University of Minas Gerais – UFMG, Laboratory of Robotics, Welding and Simulation, Mechanical Engineering Department,
Av. Antônio Carlos, 6627 – Pampulha, 31270-901 – Belo Horizonte – MG, Brazil
b Colorado School of Mines – CSM, Center for Welding, Joining and Coatings Research, Golden, CO 80401, USA

Abstract
The objective of this work is to evaluate the influence of porosity variation on multipass V-groove weld metal properties. Commercial covered
electrodes (E6013 and E7024) and three different steels (A-36, A-572 and API 5L grade B) were used to perform the wet welds at 50 and 100 m
depth. A pressurized chamber with 20 atmospheres capacity was used to simulate the depth with fresh water. A gravity feeding system was used
to perform the welds. The porosity in transverse cross-sections, Charpy V-notch tests, side bending tests and tensile tests were determined for
correlation. Samples for porosity measurement removed in four different points along the weld length showed decreasing porosity. Mechanical
tests showed better properties in the samples extracted from the end of the welds.
© 2006 Published by Elsevier B.V.

Keywords: Underwater wet welding; Covered electrode; Joule effect and porosity

1. Introduction welds is probably, the increase in the droplet size, due to elec-
trode heating by Joule effect. Ibarra et al. [3] explained that
In a way similar to the changes in weld metal chemical com- wet welds present inferior mechanical properties compared to
position along the length of a weld bead during surface welding surface welds because of the chemical reactions of oxygen,
as observed by Bracarense [1], Pessoa et al. [2] reported that hydrogen and carbon with important alloying elements in the
weld metal porosity reduced along the length of underwater wet weld pool. Christensen [4] mentioned that variations of man-
welds. In surface welds, the significant changes in microstruc- ganese and carbon contents affected weld metal hardenability,
ture and mechanical properties along the weld length were while oxygen content variation modified weld metal toughness.
because of variations in oxygen, manganese and silicon con- Porosity is another factor responsible for mechanical proper-
tent. It was also observed that the variation is bigger for higher ties reduction. Liu et al. [5] stated that the influence of porosity in
values of current. Manganese and silicon contents increased 7.1 the weld metal is similar to that in sintered steels, where poros-
and 10.7% for the E6013 welds and 6.3 and 14.5% for the E7018 ity caused reduction of toughness, ductility, yield and ultimate
welds electrode at current of 100 and 150 A, respectively. This strength limits. These authors also reported depth (pressure),
phenomenon was related to electrode heating, i.e. Joule effect, electrode coating and arc stability as the main factors that con-
which allowed for the growth of the pendant liquid metal droplet, trolled weld metal porosity.
decreasing oxygen pickup as welding time increases. As it was evidenced by the non-uniform distribution of poros-
In the wet welds, the amount of oxygen present in the weld ity in underwater wet welds, a study of the influence of porosity
pool is higher due to water dissociation in the electric arc. distribution on the mechanical properties became necessary. The
The controlling factor for the variations along the length of objective of this work is to describe and to discuss the variations
observed in porosity and micro-structural distribution.

∗ Corresponding author. Tel.: +31 3499 5245; fax: +31 3443 3783. 2. Materials and methods
E-mail addresses: epessoa@mines.edu (E.C.P. Pessoa),
bracarense@ufmg.br (A.Q. Bracarense), e.maluf@ig.com.br (E.M. Zica), Three different steel plates, 12.7 mm thick ASTM A-36 steel with 220 MPa
sliu@mines.edu (S. Liu), fperezgu@mines.edu (F. Perez-Guerrero). specified minimum yield strength (SMYS) and 400 MPa specified minimum ten-

0924-0136/$ – see front matter © 2006 Published by Elsevier B.V.


doi:10.1016/j.jmatprotec.2006.03.071
240 E.C.P. Pessoa et al. / Journal of Materials Processing Technology 179 (2006) 239–243

Fig. 1. V-groove coupons used to made wet welds.

Table 1
Current values used for electrodes and depths
E6013 E7024

Depth (m) 50 100 50 100


Current (A) 260 280 310 310 Fig. 4. Dimensions (mm) of “sub size” Charpy V-notch test samples.

Fig. 5. Dimensions (mm) of tensile test samples.

DCEP current polarity was used in all V-groove welds with travel speed
changing from 3.0 to 5.0 mm/s depending on electrode type, current and water
depth.
To fill the groove, an average of 10 passes was made. All beads began at the
same side of the groove. One weld was made for each condition, i.e. current,
travel speed, etc.
Fig. 2. Position of sample extraction for tests. Samples for porosity and macro- and micro-structural studies, Charpy V-
notch tests, side bending tests and tensile tests were extracted as shown in Fig. 2.
Four side bend specimens, three Charpy V-notch specimens and two tensile
sile strength (SMTS), 12.7 mm thick A-572 grade 50 steel with 345 MPA SMYS test samples were extracted along the V-groove welds.
and 450 MPA SMTS and 18.0 mm thick API L grade B steel with 250 MPa Quantitative porosity analysis was performed by optical metallographic mea-
SMYS and 400 SMTS were used in the experiments. surements in the short transverse face of the side bend samples. Qualitative
Two commercial covered electrodes E6013 and E7024 with 5.0 mm electrode analysis was done by examining the radiographic image. Since four side bend
diameter and length of 250.0 and 350.0 mm, respectively, were waterproofed samples were removed from each plate (two in the beginning and two in the end
with varnish for the experiments. of each weld as shown in Fig. 2) it was possible to study the porosity variation
V-grooves with 45◦ were prepared on 160 mm × 250 mm plates. Backing along the length of the weld.
bars were used for the 6.0 mm root opening. The weld joint is shown in Fig. 1. All specimens for the mechanical tests were produced following the 1988
The welds were made at depth of 50 and 100 m using a gravity feeding ASME Section IX Boiler and Pressure vessel Code [6] as shown in Figs. 3–5.
system inside of a pressurized chamber filled with fresh water. Bend tests were made with 85.7 mm plunger radius and Charpy tests conducted
The current values applied are showed in Table 1. made at 0 ◦ C.

Fig. 3. Dimensions (mm) of side bend test samples.


E.C.P. Pessoa et al. / Journal of Materials Processing Technology 179 (2006) 239–243 241

Fig. 6. Weld bead photo and radiograph – E6013 electrode, A-36 steel at 50 m depth.

Fig. 7. Weld bead photo and radiograph – E6013 electrode, A-36 steel at 100 m depth.

3. Results and discussion joint in these conditions. This low overall ductility, as strongly
cited in the literature, is probably due to the high cooling rate that
Visual analysis of radiographic image clearly showed poros- promotes the formation of martensite, which is of low toughness,
ity reduction along weld length as shown in Figs. 6 and 7. and high porosity. Accepting the fact that wet welds possess low
Photographs and porosity measurements on transverse cross- ductility, the maximum load supported by the samples until crack
sections and top surfaces of the Charpy and bend specimens opening was observed to increase from the beginning to the end
confirmed the trend observed in the radiographs, as showed in of the weld bead. The load difference clearly demonstrates the
Figs. 8 and 9. effect of porosity reduction along the length of the weld.
None of the specimens successfully qualified in the side bend Considering the depth, the loads supported by welds made
tests, i.e. wrapping around the plunger to form a U-shape without at 50 m were higher than those made at 100 m, indicating the
crack formation on the transverse and top surfaces. All cracked relation between porosity increase and water depth, as well as
before bending to 180◦ showing the low ductility of welded the loss of alloying elements and the deterioration of mechani-

Fig. 8. Photographs of longitudinal sections (top view) of Charpy and bend test samples made with E7024 electrode, A-572 steel at 50 m depth.

Fig. 9. Photographs of cross-sections porosity of weld bead made with E6013 electrode, A-36 steel at 100 m depth.
242 E.C.P. Pessoa et al. / Journal of Materials Processing Technology 179 (2006) 239–243

Fig. 10. Results of side bend tests and porosity measurements of welds made with E6013 electrode at 50 and 100 m depth.

Fig. 11. Results of side bend tests and porosity measurements of welds made with E7024 electrode at 50 and 100 m depth.

cal properties with increasing water depth. The maximum load et al. [10], the welds made at 50 m reached values close to the
supported by the side bend test samples and porosity values mea- absorbed energy values found for oxidizing electrodes without
sured on their transverse sections are shown in Figs. 10 and 11, nickel addition, made at 1.1 m depth. Others researchers [8,11]
where D1, D2, D3 and D4 are samples extracted as showed in also presented results around 28 J at 0 ◦ C for welds made at 50 m
Fig. 2. and 20 J at 0 ◦ C at 100 m, in agreement with the results obtained
The weld metal porosity content produced by E6013 elec- in this work. The fact that the Charpy results did not show clear
trode satisfied the macroetch test acceptance criteria from AWS relationship with porosity (or position along the weld bead) is not
D3.6M Standard [7] for class B welds, while, for E7024 elec- surprising since at low temperatures, crack propagation depends
trode, only welds made at 50 m depth, had porosity inferior to far more on the microstructure and less on defects (e.g. porosity)
5%, as demanded in the standard. and cleanliness (e.g. inclusions) as in higher temperature impact
Tensile tests results confirmed the trend observed in bend testing.
tests. Samples extracted from the end of weld bead presented
higher strength than samples extracted from the beginning of the Table 2
weld bead, as shown in Table 2, where T1 and T2 are samples Tensile tests results for underwater wet welds
extracted as showed in Fig. 2. The lower amount of porosity at Plate Specimen Ultimate strength (MPa)
the end of the weld contributed to the improvement in tensile
E6013 E7024
properties.
The values obtained in this program are close to the values A-36, 50 m T1a 450.9 461.2
reported by Rowe and Liu [8] for welds made at 50 m depth T2b 425.5 403.5
(between 400 and 500 MPa) but a little below the welds made A-36, 100 m T1 393.9 263.3
at 100 m (about 400 MPa). None of specimens extracted from T2 425.5 326.5
E6013 welds produced results in the range specified by elec- A-572, 50 m T1 456.8 430.4
trodes manufacturer [9] (US 480–520 MPa). The same occurring T2 467.8 473.9
for welds made with E7024 electrodes (US 550–600 MPa), indi- A-572, 100 m T1 381.8 292.1
cating the effect of porosity and high cooling rate on weld metal. T2 409.0 363.5
Note, however, that those ranges were determined for surface dry API, 50 m T1 429.5 412.4
welds. T2 455.1 457.5
Charpy tests did not reveal any relationship between the API, 100 m T1 393.6 295.9
absorbed energy and porosity reduction along weld bead. T2 419.0 311.1
Figs. 12 and 13 show Charpy results (each point corresponds a The specimen T1 (E6013) slid during the test and, due to mechanical hard-
to the average of three tests). However, the absorbed energy ening, presented an US value higher than that of specimen T2.
decreased with depth increase and this trend occurred for all b The specimen T2 (E7024) had a machining defect that influenced negatively

electrodes and steels. Comparing with the data reported by Pope in US value.
E.C.P. Pessoa et al. / Journal of Materials Processing Technology 179 (2006) 239–243 243

2. Tensile strength and ductility of multipass wet welds were


influenced by the porosity variation. Samples extracted from
the end of the welds showed higher strength and ductility.
3. The use of gravity feeding system produced E6013 welds
that met the macroetch test acceptance criteria as described
in AWS D3.6M class B standard (regarding porosity) for both
50 and 100 m depth.
4. The use of gravity feeding system produced E7024 welds
that met the macroetch test acceptance criteria according to
AWS D3.6M class B standard, in the porosity aspect only at
50 m depth.
5. The welds met the impact test acceptance criteria from AWS
D3.6M class B standard at 0 ◦ C temperature.
Fig. 12. Absorbed energy – E6013 electrode at 50 and 100 m depth.

Acknowledgments

The authors acknowledge the support of the U.S. DOI


– Minerals Management Service, the Instituto Mexicano del
Petroleo, Conselho Nacional de Desenvolvimento Cientı́fico
e Tecnológico – CNPq, Brazil and USIMINAS – Usinas
Siderúrgicas de Minas Gerais S/A, Brazil.

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