APPENDIX A Thermochemical Data ‘The data in this appendix have teen compiled fiom a numbor of sources. Nealy all of the ccitial property dats are taken from Appendix Af The Properties of Gases and Liauids, Second Edition, by RC. Reid and T. K. Sherwood, copyrigit © 1966, McGraw-Hill Book Com: ppany. They are used with the permission of McGraw-Hill Book Company. Mest of the thermochemical éate (G9, A/T2, and S°) were ‘obtained from the following sources 1, Zwollnski, B.J., et al, “Seecied Values of Peopertios of Hydrocarbons and. Related Compounds,” American Petroleum Tastitute Research Project 44, Thermodynamics Re- search Center, Texas A&M Universi Cobege Station, Texas (Loose-leafdata sheet sxtant, 1977). 2, Zwolineki, B,J, et al, “Selected Values of Properties of Chemical Compounds” Ther- modynamics Research Center Data Project, ‘Thermodynamics Research Center, Texas A&M University, College Station, Texas (Loose-Leaf data sheets, extant, 1977), ‘They are used with permission of the Thermo- dynamics Research Center. Other sourves used include the Handbook of Chemistry and Phys, Sth edition, edited by RC. Weast, CRC Pros, Cleveland, 1973; and Lange's Handbook of Chemisry, Lith edition, edited by J. A. Dean, McGraw-Hill Book Company, New York, 1973 Sire soite Suite of Moleailar AG sc entropy TO Comoovnd fngrezation —weithtkealgmole eal/emole caligmokK °K Aim Flementary gases Hydecgen Gee 2016 0 ° gia 83 1280 Owaen Ges 200 0 ° 80031348501 Nizogen Ges reas ° 49767 1262335 Fluorine Ges 3800 0 0 ao 5s Chlerne Ges 031 ° ° sua 41276 Bromine Ligwid 15083 ° ° wa Steam Tedine Crist 25242 ° ° m9 1S 16 Paralfine Methne Gs leod 21M WB SOIT as Ethane Gs MOOT 780 = 29235 SUS BOSH AR Propane Gas HO sold — aD GSE kes 20 Butane Ges s2 0 aun ns TH? 282 MS cute Ga se Sm sO 60 mPeniane Ge Ris = 2m = 300 BaD 469S 3S 2-Metisltutane Gs mis = As 3a92 ID oud BD Neopentane Ge wis Sol 0) SAB SL rllonane Gos 097 96928 SOT 259 2Metnylpentane Gas se7 = 1m = aioe 9954963 300 SMeylpentine Gas SorT asi = 402 977 S047 308 70Appendix A. Thermochemical Dats st Se Absolite Sueof Moleilar AGhase — MMfjage—_ envopy e Compound sggrigation weight Lealgmole kealigmele calig-nole °K Ai lens raslene Gs asco waaay nas ANSE ss Propors Ga i290 S651 aS4 Butene Ga 561020) = 3 TOL 196 397 cle 2-Butene Ga: Sol) 86? T8046 tas trans--Butene Gas Sel 1505267 RRS ALS Isebuptere os Soi 88 kok eT 995 Penton Gx WIS 9% SOD BS GA 300 ie2-Fentene Ga mos mat = gt S176 4756 ana trans--Pentene Gm 701s 67% TDS TSG a 3MeliyLL-butens Gas wis ST = 592 THI ads 339) DMewiyt2buces Gas yon M36 aaa? IHerene Gas Sai 9988 393 SOHO BA Loctene Ge 12M 98D DSS STE Cyelopentene Gas silat 7 8235061 472" Dione Propadiene Gas 400 8374592 SBD 883 |eBuadene Gas shy Jess TS ww ST Aectyenes ‘Acetyene Gas root Shige ai9p7 3095 616 Propyne Ga ‘ose 4p 5530 tO S38 Eihyloetslene Gas seo gas gest awa Dimethyleetslens Gas su9 MoT GT a8RT TS Cyclparatos ‘Cyelopentane Gas 7013 92 Balu SLS at Matbyleyelopentane Gas B06 8335590824327 Etiyleyelopentane Gas Seis os SST 2 335 Cyelotoxene Gas 86 76 AT 3240. Mathyleyclobssane Gas 98 6 = 599 806 S721 M3 Arosaton Benzene Gas Jl 9! AD GBM aR Teluere Gas 9213 ng 14a als Xylene Gas 106.16 as §31 357 mexylene Gas 066 sim 8549 7 pixie Ga 1066 fa eu23 no Etiyltenzene Gas 16.16, nim Bhs 369 Alcott Methyl alto! Gos S20 3881 OSS iguid <8 ST aa Ethyl aochol Gs 4007 4018 = 5803 nse Ste 00 iguia Sas 6203volute Suateof Molar AGP avy AMPs emeopy TP Compound tegration weuht kcal ginole ealgemole calmokKk °K atm mPrepylaieono) Gas ow sky STUB Lauid 4058 os ato opraps alcohol Gs on aes 08 Mi 5082 0 Lauid Sahin 7598s ‘Bug alcohol Gas MIQ —36il G6 HHT SOS quis S30 ms sscRaylaleohol Gas mio 253 tno SR HHO auld er rert-Buty alcohol Gas, m2 ads aos T5062 HD Tspbutylateahol Gas M12 Sa — mS as agus Sen = tos Phen Ga oun = Ta = 98 6943 6s quid Sn = wa Ethers Dimethylether Gas 4607-2696 GH aL Diethyleher Lud 412 HD HH DHE Isopropybether G02? 283 63k SOOL Lauia = ww = 400 ma Ketones ‘Aceon Gas soe 3680 = S sora. avid -2 - 97 Aldehydes Formaldehyde Gas oo = = 8 226 Actaldeyde Gas 405 sl BB go, SH Draanic Acids ‘Acetic aid Liquid 6005. 938 = 1164 B20 se SLL Gas 9128 S10 Acctisambyetide Gas 1020911939 LR $02 162 quit Spns=15816 Proponis acid Gas Taos = 8827 = 10875 62.7 0 guid Sos eT Esters ‘Methyl formate wos 137 87 » 4812, 92 Sass = me Baby) acetate seo 7493 anne sms m8 Swi 1102 Enhy) propicnats bis 7a 116 541 BO Sle 1216 Nitogen compounds ‘Ammon, Gas ros = 3m 597 a6 LDS Cyanogen Ge 5202 Taal «TPM AOD. DO Hydrogen cyanide Cae pio. 8T 32 BX 467-89 Methyl amize Gas 3108 + 66 = 6? 3B 492 TRL sn