ALBERT MESSIAH
QUANTUM
MECHANICSNo part of this book may be reproduced in any form by
print, photoprint, microfilm or any other means without
written permission from the publisher
ORIGINAL TITLE: MECANIQUE QUANTIQUE, VOL. IT
TRANSLATED FROM THE FRENCH
BY
J. POTTER
Orsay (S.-et-0.), France
MECANIQUE QUANTIQUE I AND II WERE PUBLISHED BY
DUNOD, PARIS
SIXTH PRINTING, SEPTEMBER, 1966
PUBLISHERS:
NORTH-HOLLAND PUBLISHING COMPANY, AMSTERDAM
JOHN WILEY & SONS, INC. — New York * London + Sydney
Printed in the United States of AmericaCHAPTER XX
THE DIRAC EQUATION
I. GENERAL INTRODUCTION
1. Relativistic Quantum Mechanics ')
All of the applications made up to the present have been based
on the Schridinger equation. This equation, deduced by the corre-
spondence principle from the Hamiltonian formalism of non-relativistic
Classical Mechanics, has all the invariance properties of the Hamil-
tonian from which it derives. In particular, if the system is isolated,
it is invariant under spatial rotations and translations. It can also
be shown that it is invariant under Galilean transformations (cf.
Problem XV.7). Therefore, the physical properties predicted by the
Schrédinger theory are invariant in a Galilean change of referential,
but they do not have the invariance under a Lorentz change of
referential required by the principle of relativity. Since the Galilean
transformation approximates to the Lorentz transformation only in
the limit of small velocities, one expects — and experiment verifies —
that this theory will correctly describe phenomena only when the
velocities of the particles involved are negligible beside the velocity
of light: v
Fundamental Problems in Statistical Mechanics, VIII: Proceedings of the Eighth International Summer School on Fundamental Problems in Statistical Mechanics, Altenberg, Germany, 28 June - 10 July, 1993