1.

Count the percentage of yield for iron(II) oxalate and potassium trisoxalatoferrate(III)
trihydrate.

Fe(NH4)2(SO4)2·6H2O + H2C2O4·2H2O FeC2O4·2H2O + (NH4)2SO4 + H2SO4 + 6H2O

15𝑔
Mol of (NH4)2Fe(SO4)2·6H2O =
392𝑔/𝑚𝑜𝑙

= 0.04 mol
Mol of H2C2O4·2H2O = 0.1 M x 0.075 L
= 0.0075 mol

Based on the chemical equation above;

1 mol of (NH4)2Fe(SO4)2.6H2O = 1 mol of FeC2O4.2H2O
0.0075 mol = 0.0075 mol
Theoretical mass of FeC2O4.2H2O = 0.0075 mol x 179 g/mol
= 1.3425 g
Percentage yield of Iron (II) Oxalate, FeC2O4.
𝐴𝑐𝑡𝑢𝑎𝑙
× 100%
𝑇ℎ𝑒𝑜𝑟𝑒𝑡𝑖𝑐𝑎𝑙

1.1553𝑔
= × 100% = 86.06%
1.3425 𝑔

2Fe(OH)3 + 3 K2C2O4 + 3H2C2O4 2K3[Fe(C2O4)3].3H2O + 3H2O

1.1553𝑔
1 mol of FeC2O4·2H2O =
179𝑔/𝑚𝑜𝑙

= 6.45 x 10-3 mol

2.3𝑔
Mol of K2C2O4 =
166𝑔/𝑚𝑜𝑙

= 0.014 mol
Mol of H2C2O4 = 0.1 M x 0.01 L
= 0.001 mol
From the overall equation:
2 mol of Fe(OH)3 = 2 mol of K3[Fe(C2O4)3].3H2O
2
= 6.45 x 10-3 mol x
2
= 0.00645 mol
3 mol of K2C2O4 = 2 mol of K3[Fe(C2O4)3].3H2O
3
= 0.014 mol x
2
= 0.021 mol
3 mol of H2C2O4 = 2 mol of K3[Fe(C2O4)3].3H2O
3
= 0.001 mol x
2
= 0.0015 mol

Theoretical mass of K3[Fe(C2O4)3].3H2O = 0.0015 mol x 491g/mol

= 0.7365 g
Percentage yield of. Potassium Trisoxalatoferrate(III) Trihydrate K3[Fe(C2O4)3].3H2O
𝐴𝑐𝑡𝑢𝑎𝑙
× 100%
𝑇ℎ𝑒𝑜𝑟𝑒𝑡𝑖𝑐𝑎𝑙
0.6017𝑔
= × 100% = 81.70%
0.7365 𝑔