CH t07 . 1 hes Novemb. wuwern Will NOT be corr only unin a PEN Qualitatively sketeh the bonding and nntibonding, MOw Gvith sigan) of at adlatoml formed by a} nation of w dey and. pry orbital ndde(s) AP we overlap Integral (8) aa function of lnternuelewr divta : For Hat an fon, derive the expression f yy) of the antibonding MO, in terns of hydrogenie wceleetron ener wera, Conley tal potential energy for an electron in a 20 orbital, 5 ) ving, Your may use the standard integral, (alt refully draw the contour plot ( hybridized AO the expression for which ta [2py~ 24]. Cle Hin o(s)/surrfacets) If any plain why commion candle wax (u hydrocarbon, C; litative, twith at Teast ly slat 200K? Hea) Photoelectron spectroscopy of A, B ch provided the following data: ‘Two elements A and B have # and p orbitals in the valence shel nd their binary compound AB is performed with 20 eV photo Spec ce " Intensity A % “5 an 3 71 lars 4 * | 7 3 2 26 4 : Note that this is a hypothetical molecule. Assume the MOs and their energies for AB, AB* and AB" are the same. Label dingrams/sketches appropriately for full credit. Fat | Carefully (quantitatively) sketch the molecular orbital (MO) energy level diagram for AB in | (27 she graph paper provided. The energies must be drawn to scale. o) of the lowest energy MO of AB? What is the p-characte tion. Determine the bond order of AB with proper justifi | et a Is AB* paramagnetic or diamagnetic? Explain, € Qualitatively sketch the HOMO of AB-. 1Q ‘nt in a solution of chloroform and methanol? CA [ar] What are the intermolecular forces pre: Lt Which molecular property is essential for_a diatomic molecule to be microwave and infrared active (i.e., absorb microwave and infrared radiation)? 7 jectra of a diatomic molecule at two | [2T sketch the microwave r, >> T, #0 Kelvin), clearly showing the changes in various spectral tule to be stable at both temperatures. different temperatures (1 [parameters (features), assuming, the mole i [27] In the same graph, qualitativel yet Considering an anharmonic oscillator model where the lowed vibrational levels are given | (27 v4 4) ox, ent’ evaluate the zero-point energy of 4N-°O, if the TR by c=(v+h)a, spectrum of the molecule exhibits cm, — n intense peak at 1876.06 em”, and a much less intense peak at 3724. - =