LAMPIRAN PERHITUNGAN

1. Penentuan Angka Peroksida

Diketahui : N Na2S2O4 = 0,1212 N
m aquades = 5,017 g
m sampel 1 = 5,020 g
m sampel 2 = 5,071 g
m sampel 3 = 5,035 g
V Na2S2O4 blanko = 0,2 + 0,1 Ml = 0,3 mL
V Na2S2O4 sampel 1= 1 + 1,6 mL = 2,6 mL
V Na2S2O4 sampel 2 = 1,2 + 1,4 Ml = 2,6 mL
V Na2S2O4 sampel 3 = 1,1 + 1,2 Ml = 2,3 mL
Ditanya : Angka peroksida?
Jawab :
𝑽 𝑵𝒂𝟐 𝑺𝟐 𝑶𝟑− 𝑽 𝑩𝒍𝒂𝒏𝒌𝒐 × 𝑵 𝑵𝒂𝟐 𝑺𝟐 𝑶𝟑 × 𝟏𝟎𝟎𝟎
Angka peroksida =
𝒎 𝒔𝒂𝒎𝒑𝒆𝒍 (𝒈)
0,3 𝑚𝐿 ×0,1212 𝑁 × 1000
a. Angka peroksida blanko =
5,017g
= 7,24 meq/kg
(2,6−0,3) 𝑚𝐿 ×0,1212 𝑁 × 1000
b. Angka peroksida sampel 1 =
5,020 g
= 55, 52 meq/kg
(2,6−0,3)𝑚𝐿 ×0,1212 𝑁 × 1000
c. Angka peroksida sampel 2 =
5,071 g
= 54, 97 meq/kg
(2,3−0,3) 𝑚𝐿 ×0,1212 𝑁 × 1000
d. Angka peroksida sampel 3 =
5,035 g
= 48,14 meq/kg
(55,52+54,97+48,14 ) meq/kg
Rata rata Angka peroksida sampel =
3
= 52,87 meq/kg
2. Penentuan asam lemak bebas
Diketahui : N NaOH = 0,1008 N
m blanko = 6,034 g
m sampel 1 = 6,017 g
m sampel 2 = 6,030 g
m sampel 3 = 6,034 g
V NaOH blanko = 0,1 mL
V NaOH sampel 1 = 0,4 mL
V NaOH sampel 2 = 0,3 mL
V NaOH sampel 3 = 0,2 mL
BM asam lemak minyak curah (asam palmitat) = 256 g/mol
Ditanya : % FFA?
Jawab :
% FFA =
𝑽 𝑵𝒂𝑶𝑯−𝑽 𝒃𝒍𝒂𝒏𝒌𝒐 × 𝑵 𝑵𝒂𝑶𝑯 × 𝑩𝑴 𝑨𝒔𝒂𝒎 𝑳𝒆𝒎𝒂𝒌
𝒙 𝟏𝟎𝟎%
𝒎 𝒔𝒂𝒎𝒑𝒆𝒍 (𝒈) × 𝟏𝟎𝟎𝟎
0,1 𝑚𝐿 ×0,1008 𝑁 × 256 𝑔/𝑚𝑜𝑙
a. % FFA blanko = 𝑥100%
6,034 g × 1000
= 0,043 %
(0,4−0,1) 𝑚𝐿 ×0,1008 𝑁 × 256 𝑔/𝑚𝑜𝑙
b. % FFA sampel 1 = 𝑥100%
6,017 g × 1000
= 0,128 %
(0,3−0,1)𝑚𝐿 ×0,1008 𝑁 × 256 𝑔/𝑚𝑜𝑙
c. % FFA sampel 2 = 𝑥100%
6,030 g × 1000
= 0,085 %
(0,2−0,1) 𝑚𝐿 ×0,1008 𝑁 × 256 𝑔/𝑚𝑜𝑙
d. % FFA sampel 3 = 𝑥100%
6,034 g × 1000
= 0,042 %
(0,128 + 0,085 + 0,042) %
Rata-rata % FFA sampel =
3
= 0,085 %