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10.

1 a,b P xy
P x1 y1 P1 sat P2 sat A
74.182329612 0 0 180.0498 74.18233 benzene 13.8594
85.8277517 0.11 0.2307584389 180.0498 74.18233 toluene 14.0098
97.4731734 0.22 0.4063780281 180.0498 74.18233
109.1185951 0.33 0.544512454 180.0498 74.18233 200
120.7640168 0.44 0.656005937 180.0498 74.18233 180
132.4094385 0.55 0.7478876968 180.0498 74.18233
160
144.0548602 0.66 0.8249139795 180.0498 74.18233
155.7002819 0.77 0.8904180796 180.0498 74.18233 140

167.3457036 0.88 0.9468054488 180.0498 74.18233 120


178.9911253 0.99 0.9958555303 180.0498 74.18233 100
180.0498 1 1 180.0498 74.18233
80

60

40

20

0
0 0.1 0.2 0.3 0.4 0.5 0.6

10.1 c,d T xy
A
benzene 13.8594
toluene 14.0098
x1 x2 a0 P2sat T a1 P1sat y1
0 1 2.3046835965 120 116.6778 2.304684 276.562 0
0.11 0.89 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.22 0.78 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.33 0.67 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.44 0.56 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.55 0.45 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.66 0.34 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.77 0.23 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.88 0.12 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.99 0.01 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
1 0 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522

10.2
a. Benzene, ethyl benzene P xy Diagram
A B C Diket
benzene 13.8594 2773.78 220.07 T= 90
Ethylbenzene 14.0045 3279.47 213.2
160

140

120
P X1 Y1 P1 sat P2 sat 160
24.2473193402 0 0 136.148 24.24732
140
36.5563948 0.11 0.4096760658 136.148 24.24732
48.8654696 0.22 0.6129596266 136.148 24.24732 120
61.1745444 0.33 0.7344368551 136.148 24.24732
100
73.4836192 0.44 0.8152173321 136.148 24.24732
85.792694 0.55 0.8728179115 136.148 24.24732 80
98.1017688 0.66 0.9159639128 136.148 24.24732
110.4108436 0.77 0.9494897112 136.148 24.24732 60
122.7199184 0.88 0.9762900885 136.148 24.24732
40
135.0289932 0.99 0.9982042879 136.148 24.24732
136.148 1 1 136.148 24.24732 20

0
0 0.1 0.2 0.3 0.4 0.5

a. Benzene, ethyl benzene T xy Diagram


x1 x2 a0 P2 sat T a1 P1 sat y1
0 1 4.3817640652 90 131.837 4.381764 394.3588 0
0.11 0.89 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.22 0.78 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.33 0.67 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.44 0.56 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.55 0.45 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.66 0.34 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.77 0.23 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.88 0.12 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.99 0.01 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
1 0 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522

b. 1-Chlorobutane, Chlorobenzene P xy Diagram


A B C Diket
1-Chlorobutane 13.96 2826.26 224.1 T 90
Chlorobenzene 13.9926 3295.12 217.55
160
P X1 Y1 P1 sat P2 sat
140
26.5360644638 0 0 142.8846 26.53606
39.3343994 0.11 0.3995816954 142.8846 26.53606 120
52.1327388 0.22 0.6029725797 142.8846 26.53606
64.9310782 0.33 0.7261841218 142.8846 26.53606 100

77.7294176 0.44 0.8088214982 142.8846 26.53606 80


90.527757 0.55 0.8680931971 142.8846 26.53606
103.3260964 0.66 0.9126816873 142.8846 26.53606 60
116.1244358 0.77 0.9474417787 142.8846 26.53606
40
128.9227752 0.88 0.9753005069 142.8846 26.53606
141.7211146 0.99 0.998127586 142.8846 26.53606 20
142.8846 1 1 142.8846 26.53606
0
0 0.1 0.2 0.3 0.4 0.5
20

0
0 0.1 0.2 0.3 0.4 0.5

b. 1-Chlorobutane, Chlorobenzene T xy Diagram


x1 x2 a0 P2 sat T a1 P1 sat y1
0 1 4.3445152859 90 129.5682 4.344515 391.0064 0
0.11 0.89 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.22 0.78 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.33 0.67 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.44 0.56 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.55 0.45 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.66 0.34 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.77 0.23 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.88 0.12 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
0.99 0.01 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
1 0 Err:522 Err:522 Err:522 Err:522 Err:522 Err:522
B C Diket:
2773.78 220.07 T 100
3103.01 219.79

.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Asumsi: Diket:
B C ao 2.4009321612 P 120
2773.78 220.07 P2sat 82.062077033
3103.01 219.79 P1sat 197.02547996
P T 103.36197855
120 a1 2.4008898377
120 a1-a0 -4.232349E-05
120
120 140
120
120 120

120
100
120
120 80
120
120 60

40

20

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

P Asumsi: Diket
90 a0 4.381764 P 90
90 P2 sat 90
90 P 1 sat 394.3588 140
90 T 131.837
90 a1 4.381764 120
90 a1-a0 0
100
90
90 80
90
90 60
90
40

20

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1


0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

P Asumsi:
90 a0 4.344515
90 P2 sat 90
90 P 1 sat 391.0064
90 T 129.5682
90 a1 4.344515
90 a1-a0 0
90
140
90
90 120
90
90 100

80

60

40

20

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.7 0.8 0.9 1

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