Professional Documents
Culture Documents
= 4166.667 kg/jam
Konversi : Sulfonasi = 99 %
Netralisasi = 95 %
Basis Perhitungan
LAB : C12H25C6H5
Dialkil tetralin : C6H5C10H21
Parafin : C6H5C14H29
Sehingga :
F1 LAB = 0.986 x F1
= 0.986 x 100 kg/jam
= 98.600 kg/jam
F1 parafin = 0.004 x F1
= 0.004 x 100 kg/jam
= 0.400 kg/jam
Komponen LAB
Laju alir [F] (kg/jam) 98.6
Berat molekul (kg/mol) 246
Laju molar [N] (kmol/jam) 0.4008
LAB bertindak sebagai pereaksi pembatas, sehingga perhitungan konversi 99% sebagai berikut :
N3 LABSA = N2 LABSA + 1r
= 0 + 0.3968
= 0.3968 kmol/jam (N out)
Maka,
Masuk Keluar
Komponen Aliran 1 Aliran 2 Aliran 3
x F x F x F
LAB 0.986 98.600 0.003 0.986
Parafin 0.004 0.400 0.001 0.400
Dialkiltetralin 0.010 1.000 0.003 1.000
SO3 0.200 40.081 0.028 8.337
H2SO4 0.784 157.119 0.523 157.119
H2O 0.016 3.207 0.011 3.207
LABSA 0.431 129.358
Sub total 1.000 100.000 1.000 200.407 1.000 300.407
Total 300.407 300.407
2) Tangki Pengenceran
Komponen SO3
Laju alir [F] (kg/jam) 8.337
Berat molekul(kg/mol) 80
Laju molar [N] (kmol/jam) 0.1042
Pelarutan SO3 sisa dengan konversi sebesar 100% mengikuti reaksi sebagai berikut :
F3 LAB = F4 LAB
= 0.986 kg/jam
F3 LABSA = F4 LABSA
= 129.3584 kg/jam
F3 Dialkiltetralin = F4 Dialkiltetralin
= 1.0 kg/jam
F3 Paraffin = F4 paraffin
= 0.4 kg/jam
Masuk Keluar
Komponen Aliran 3 Aliran 14 Aliran 4
x F x F x F
LAB 0.003 0.986 0.003 0.986
Parafin 0.001 0.400 0.001 0.400
Dialkiltetralin 0.003 1.000 0.003 1.000
SO3 0.028 8.337
H2SO4 0.523 157.119 0.483 167.331
H2O 0.011 3.207 1.000 45.865 0.136 47.196
LABSA 0.431 129.358 0.374 129.358
Sub total 1.000 300.407 1.000 45.865 1.000 346.272
Total 346.272 346.272
3) Decanter
F5 = 131.7444
0.940
= 140.1536 kg/jam
Masuk Keluar
Komponen Aliran 4 Aliran 7 Aliran 5
x F x F x F
LAB 0.003 0.986 0.007 0.986
Parafin 0.001 0.400 0.003 0.400
Dialkiltetralin 0.003 1.000 0.007 1.000
H2SO4 0.483 167.331 0.780 160.772 0.047 6.559
H2O 0.136 47.196 0.220 45.346 0.013 1.850
LABSA 0.374 129.358 0.923 129.358
Sub total 1.000 346.272 1.000 206.118 1.000 140.154
Total 346.272 346.272
4) Tangki Netralisasi
Reaksi 1 :
Reaksi 2 :
H2SO4 bertindak sebagai pereaksi pembatas, sehingga konversi 100% sebagai berikut :
F5 H2SO4 6.5592 kg/jam
N5 H2SO4 = = = 0.0669 kmol/jam
BM H2SO4 98 kg/kmol
N8 H2SO4 = N6 H2SO4 - (X H2SO4 x N5 H2SO4)
= 0.0669 - ( 1 x 0.0669 ) kmol/jam
= 0.0 kmol/jam
Kebutuhan NaOH (F6 NaOH) = (N6 NaOH 1 - sisa N6 NaOH 1 + N6 NaOH 2) x BM NaOH
= ( 0.3968 - 0.0198 + 0.1339 ) kmol/jam x 40 kg/mol
= 20.433 kg/jam
F6 NaOH 20.4330
F6 = = = 102.1651 kg/jam
0.2 0.20
F6 H2O = 0.8 x F6
= 0.8 x 102.1651
= 81.7321 kg/jam
Masuk Keluar
Komponen Aliran 5 Aliran 6 Aliran 8
x F x F x F
LAB 0.007 0.986 0.004 0.986
Parafin 0.003 0.400 0.002 0.400
Dialkiltetralin 0.007 1.000 0.004 1.000
H2SO4 0.047 6.559
H2O 0.013 1.850 0.800 81.732 0.383 92.777
LABSA 0.923 129.358 0.027 6.468
NaOH 0.200 20.433
Na2SO4 0.039 9.504
LASNa 0.541 131.184
Sub total 1.000 140.154 1.000 102.165 1.000 242.319
Total 242.319 242.319
5) Tangki Spray Dryer
Masuk Keluar
Komponen Aliran 8 Aliran 9 Aliran 10
x F x F x F
LAB 0.004 0.986 0.006 0.986
Parafin 0.002 0.400 0.003 0.400
Dialkiltetralin 0.004 1.000 0.006 1.000
H2O 0.383 92.777 0.040 6.231
LABSA 0.027 6.468 0.042 6.468
Na2SO4 0.039 9.504 0.061 9.504
LASNa 0.541 131.184 0.842 131.184
Uap air 1.000 86.546
Sub total 1.000 242.319 1.000 155.773 1.000 86.546
Total 242.319 242.319
6) Kondensor
Masuk
Komponen Aliran 10 Aliran 11
x F x F
H2O 1.000 86.546
Uap air 1.000 86.546
Sub total 1.000 86.546 1.000 86.546
Total 86.546 86.546
7) Penampung
Masuk Keluar
Komponen Aliran 11 Aliran 12 Aliran 13 Aliran 14
x F x F x F x F
H2O 1.000 86.546 1.000 40.634 1.000 81.315 1.000 45.865
Sub total 1.000 86.546 1.000 40.634 1.000 81.315 1.000 45.865
Total 127.180 127.180
Dimana,
F15 NaOH = F6 NaOH = 20.433
Masuk Keluar
Komponen Aliran 15 Aliran 13 Aliran 6
x F x F x F
H2O 0.020 0.417 1.000 81.315 0.800 81.732
NaOH 0.980 20.433 0.200 20.433
Sub total 1.000 20.850 1.000 81.315 1.000 102.165
Total 102.165 102.165
NaOH H2O
Dialkiltetralin
Parafin
LAB LAS Na
Masuk = Keluar
F1 + F2 + F15 + F13 + F14 = F7 + F10 + F12
100.00 + 200.407 + 20.850 + 81.315 + 45.865 = 206.118 + 86.546 + 155.773
448.437 = 448.437
Masuk Keluar
Komponen
x F x F
LAB 0.220 98.600
Parafin 0.001 0.400
Dialkiltetralin 0.002 1.000
SO3 0.089 40.081
H2SO4 0.350 157.119 0.460 206.118
NaOH 0.046 20.850
H2O 0.291 130.387
LAS Na 0.347 155.773
Uap air 0.193 86.546
Sub total 1.000 448.437 1.000 448.437
Total 448.437 448.437
kmol/jam
kg/jam
NERACA MASSA AKTUAL
= 4166.667 kg/jam
Produk Keluar = 155.773 kg/jam
Faktor Pengali = 4166.667 kg/jam
155.773 kg/jam
= 26.748
1) Tangki Sulfonasi
Masuk Keluar
Komponen Aliran 1 Aliran 2 Aliran 3
x F x F x F
LAB 0.986 2637.385 0.003 26.374
Parafin 0.004 10.699 0.001 10.699
Dialkiltetralin 0.010 26.748 0.003 26.748
SO3 0.200 1072.100 0.028 223.001
H2SO4 0.784 4202.670 0.523 4202.670
H2O 0.016 85.782 0.011 85.782
LABSA 0.431 3460.110
Sub total 1.000 2674.832 1.000 5360.551 1.000 8035.384
Total 8035.384 8035.384
2) Tangki Pengenceran
Masuk Keluar
Komponen Aliran 3 Aliran 14 Aliran 4
x F x F x F
LAB 0.003 26.374 0.003 26.374
Parafin 0.001 10.699 0.001 10.699
Dialkiltetralin 0.003 26.748 0.003 26.748
SO3 0.028 223.001
H2SO4 0.523 4202.670 0.483 4475.851
H2O 0.011 85.782 1.000 1226.812 0.136 1262.414
LABSA 0.431 3460.110 0.374 3460.110
Sub total 1.000 8035.384 1.000 1226.812 1.000 9262.196
Total 9262.196 9262.196
3) Dekanter
Masuk Keluar
Komponen Aliran 4 Aliran 7 Aliran 5
x F x F x F
LAB 0.003 26.374 0.007 26.374
Parafin 0.001 10.699 0.003 10.699
Dialkiltetralin 0.003 26.748 0.007 26.748
H2SO4 0.483 4475.851 0.780 4300.408 0.047 175.442
H2O 0.136 1262.414 0.220 1212.929 0.013 49.484
LABSA 0.374 3460.110 0.923 3460.110
Sub total 1.000 9262.196 1.000 5513.338 1.000 3748.858
Total 9262.196 9262.196
4) Tangki Netralisasi
Masuk Keluar
Komponen Aliran 5 Aliran 6 Aliran 8
x F x F x F
LAB 0.007 26.374 0.004 26.374
Parafin 0.003 10.699 0.002 10.699
Dialkiltetralin 0.007 26.748 0.004 26.748
H2SO4 0.047 175.442
H2O 0.013 49.484 0.800 2186.194 0.383 2481.629
LABSA 0.923 3460.110 0.027 173.008
NaOH 0.200 546.549
Na2SO4 0.039 254.216
LASNa 0.541 3508.925
Sub total 1.000 3748.858 1.000 2732.743 1.000 6481.600
Total 6481.600 6481.600
Masuk Keluar
Komponen Aliran 8 Aliran 9 Aliran 10
x F x F x F
LAB 0.004 26.374 0.006 26.374
Parafin 0.002 10.699 0.003 10.699
Dialkiltetralin 0.004 26.748 0.006 26.748
H2O 0.383 2481.629 0.040 166.669
LABSA 0.027 173.008 0.042 173.008
Na2SO4 0.039 254.216 0.061 254.216
LASNa 0.541 3508.925 0.842 3508.925
Uap air 1.000 2314.960
Sub total 1.000 6481.600 1.000 4166.640 1.000 2314.960
Total 6481.600 6481.600
6) Kondensor
Masuk
Komponen Aliran 10 Aliran 11
x F x F
H2O 1.000 2314.960
Uap air 1.000 2314.960
Sub total 1.000 2314.960 1.000 2314.960
Total 2314.960 2314.960
7) Penampung
Masuk Keluar
Komponen Aliran 11 Aliran 12 Aliran 13 Aliran 14
x F x F x F x F
H2O 1.000 2314.960 1.000 1086.891 1.000 2175.040 1.000 1226.812
Sub total 1.000 2314.960 1.000 1086.891 1.000 2175.040 1.000 1226.812
Total 3401.852 3401.852
8) Mixer NaOH
Masuk Keluar
Komponen Aliran 15 Aliran 13 Aliran 6
x F x F x F
H2O 0.020 11.154 1.000 2175.040 0.800 2186.194
NaOH 0.980 546.549 0.200 546.549
Sub total 1.000 557.703 1.000 2175.040 1.000 2732.743
Total 2732.743 2732.743
Masuk Keluar
Komponen
x F x F
LAB 0.220 2637.385
Parafin 0.001 10.699
Dialkiltetralin 0.002 26.748
SO3 0.089 1072.100
H2SO4 0.350 4202.670 0.460 5513.338
NaOH 0.046 557.703
H2O 0.291 3487.634
LAS Na 0.347 4166.640
Uap air 0.193 2314.960
Sub total 1.000 11994.938 1.000 11994.938
Total 11994.938 11994.938
Aliran
Komponen
1 2 3 4 5 6 7
LAB 2637.385 26.374 26.374 26.374
Parafin 10.699 10.699 10.699 10.699
Dialkiltetralin 26.748 26.748 26.748 26.748
SO3 1072.100 223.001
H2SO4 4202.670 4202.670 4475.851 175.442 4300.408
H2O 85.782 85.782 1262.414 49.484 2186.194 1212.929
LABSA 3460.110 3460.110 3460.110
NaOH 546.549
Na2SO4
LAS Na
Uap air
Sub total 2674.832 5360.551 8035.384 9262.196 3748.858 2732.743 5513.338
Aliran
8 9 10 11 12 13 14 15
26.374 26.374
10.699 10.699
26.748 26.748