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Series HK (Shoshonitic)

Pluton BARRU MASAMBA POLEWALI MAMASA


Sample DIO BR MST-13 MRF-4 MRF-7 MRF-1 MA-67C-1MA-67XE MA-67B POL-13 POL-ST2 POL-ST1 POL-19 POL-11 MA-41 MA-41B MA-43B MA-45B MA-46
Whole Rock (wt%)
SiO2 60.67 66.14 68.66 74.28 66.97 60.51 64.03 72.51 65.16 64.33 64.78 64.78 65.42 61.14 62.50 51.60 63.7 67.56
TiO2 0.52 0.54 0.51 0.13 0.56 0.66 0.69 0.21 0.52 0.68 0.63 0.56 0.4 0.71 0.65 0.98 0.61 0.66
Al2O3 15.52 14.54 14.41 13.57 15.07 15.54 14.41 13.63 15.18 14.28 14.19 14.68 14.2 14.62 14.40 13.84 13.21 12.65
FeOt 4.37 3.85 2.74 1.52 2.96 5.5 4.12 1.82 4.23 4.52 4.29 3.87 2.56 5.27 4.73 6.90 4.51 3.49
MnO 0.09 0.08 0.05 0.03 0.05 0.12 0.09 0.05 0.07 0.1 0.09 0.07 0.07 0.11 0.10 0.12 0.07 0.07
MgO 3.4 2.44 2.17 0.17 2.37 3.11 3.51 0.76 2.59 3.28 2.89 2.54 1.82 3.74 3.47 5.29 4.34 4.32
CaO 4.94 3.94 3.21 0.70 3.58 5.38 4.25 1.5 3.81 4.73 4.26 3.94 4.21 5.07 4.68 6.42 3.98 3.07
Na2O 2.92 2.49 2.37 3.30 2.39 3 2.77 3.99 2.61 2.33 2.39 2.42 1.15 3.21 3.11 2.34 2.88 2.05
K2O 4.06 4.59 4.85 5.82 4.31 4.38 4.65 4.96 3.93 4.39 4.31 4.98 4.43 4.03 4.35 6.62 4.52 4.52
P2O5 0.28 0.22 0.13 0.02 0.13 0.3 0.19 0.05 0.23 0.28 0.24 0.21 0.13 0.31 0.27 0.58 0.23 0.14
H2 O 2.88 0.89 0.71 0.40 1.44 0.8 1.01 0.41 1.34 0.82 1.6 1.6 5.4 0.78 0.82 2.37 1.2 0.79
Total 99.65 99.72 99.81 99.94 99.83 99.3 99.72 99.89 99.67 99.74 99.67 99.65 99.79 98.98 99.08 97.04 99.26 99.32
Trace element (ppm)
Cr 42 30 30 12 40 20 110 20 38 30 33 40 45 40 30 90 270 200
Ni 28 11 6 13 6 9 44 21 25 2 20 36 24 10 8 34 53 37
V 113 103 46 5 10 12 22 16 85 88 94 87 34 151 122 113 81 90
Rb 131.5 179.5 233 158 165 201 258 184 177.5 196 185.5 207 227 172 220 196 65.8 253
Ba 1130 1645 747 26.9 766 1310 956 244 1215 1175 1540 2230 1020 1180 1165 4180 496 484
Th 14.1 44.5 23 35.3 16.05 108.5 41.1 33.6 47 36.9 47.7 43.9 54.4 45.1 45.6 14.8 30.8 25.4
U 4.11 9.34 6.14 3.98 4.2 7.93 14.75 5.59 9.33 9.04 10.1 8.82 10.5 6.58 9.65 3.69 5.92 6.49
Nb 6.8 15.4 11.4 3.6 9.6 25.1 20.9 12.8 17.5 17.4 17.4 14.9 20.8 16 20.1 19.4 17.5 17.9
Ta 0.4 1.2 1 0.4 0.9 1.7 2.3 0.9 1.3 1.4 1.4 1.2 1.9 1.3 1.5 1.2 1.7 1.7
La 34.7 64.5 34.4 75.1 29.3 273 45.8 39 61 36 61 64 71.9 64.3 58.4 82.9 56.3 49.3
Ce 61.1 112 66.3 157 58.5 393 84.3 75.6 111 80.7 110 112 127.5 110 110.5 157.5 121 104.5
Pr 7.15 11.2 6.98 17.2 6.72 37.2 9.34 8.67 11.7 9.63 11.6 11.25 12.75 13.2 11.7 20.9 13.7 11.55
Sr 705 562 324 13.1 322 738 310 113.5 586 461 533 563 288 537 475 1335 217 203
Nd 28.5 40.3 25.3 53 23.6 106 34.1 32.5 42.6 37.7 41.7 39.2 42.9 36.5 42.1 61.5 39.6 40.9
Zr 145 191 169 302 158 261 213 214 204 214 200 178 213 212 220 326 246 250
Hf 3.8 6.1 5.3 9.3 4.8 7.7 6.1 6.5 6.3 6.8 6.2 5.5 6.7 6.4 5.8 8.7 7.9 7.1
Sm 5.69 7.38 4.37 7.18 4.42 11.05 6.42 6.45 7.8 7.69 7.81 6.8 7.25 7.12 7.06 12.05 8.42 8.53
Eu 1.59 1.56 1.1 0.18 1.21 1.88 1.08 0.53 1.64 1.56 1.6 1.48 1.2 1.61 1.55 2.95 1.21 1.09
Gd 5.15 6.45 3.72 5.98 4.01 5.93 4.96 5.07 6.92 6.91 7.02 5.99 6.42 5.5 4.81 7.42 6.64 6.09
Tb 0.68 0.98 0.55 0.57 0.55 0.73 0.68 0.72 1.05 1.08 1.07 0.86 0.92 0.88 0.81 1.07 1.18 1.17
Dy 3.86 5.04 2.79 2.23 2.84 3.93 3.97 4.04 5.47 5.79 5.57 4.42 4.87 4.6 4.94 5.02 6.47 6.84
Y 23.9 25.7 13.8 10 14.4 24.9 25.9 25.2 27.8 29.9 27.5 23 26.1 29.6 26.7 28.9 43.2 39.9
Ho 0.78 0.95 0.51 0.39 0.53 0.79 0.78 0.84 1.01 1.11 1.01 0.82 0.89 0.9 0.94 0.91 1.34 1.38
Er 2.15 2.76 1.44 1.22 1.52 2.12 2.14 2.21 2.96 3.2 2.98 2.41 2.64 2.36 2.79 2.03 3.56 3.89
Tm 0.32 0.4 0.19 0.16 0.21 0.31 0.32 0.31 0.43 0.47 0.44 0.34 0.37 0.41 0.37 0.34 0.63 0.57
Yb 2.08 2.69 1.35 1.04 1.33 2.07 2.09 1.94 2.93 3.22 2.87 2.41 2.61 2.45 2.42 1.88 3.66 3.76
Lu 0.35 0.41 0.2 0.17 0.2 0.35 0.34 0.33 0.42 0.49 0.44 0.37 0.38 0.41 0.37 0.3 0.6 0.53
A/NK 1.69 ### 1.60 1.58 1.16 1.14 1.78 1.65 1.57 2.12 1.52 1.46 1.37
(A/CNK) 0.85 0.90 0.96 1.04 0.93 0.98 0.87 0.89 0.99 0.78 0.79 0.78
(La/Yb)n 12.0 17.2 18.2 51.8 14.4 ### 14.9 15.2 19.0 19.8 ### 18.8 17.3 11.9
Ce* 3.88 4.17 4.28 4.37 4.11 4.15 4.14 4.17 4.21 3.78 4.23 3.92
Eu* 0.88 0.68 1.68 0.08 0.27 0.67 0.65 0.70 0.53 0.76 0.77 0.48

###

FeO ### 3.71


### 3.27 1.29 1.55
### 3.60 3.65 3.29 2.18
### 4.48 4.02
FeO ### 3.71
### 3.27 1.29 1.55
### 3.60 3.65 3.29 2.18
### 4.48 4.02
FeO ### 3.71
### 3.27 1.29 1.55
### 3.60 3.65 3.29 2.18
### 4.48 4.02
Fe2O3 ### 0.66
### 0.58 0.23 0.27
### 0.63 0.64 0.58 0.38
### 0.79 0.71

Fe2O3T ### 4.86


### 4.28 1.69 2.02
### 4.70 4.77 4.30 2.84
### 5.85 5.26
Series High-K calc alkaline (CAK)
MAMASA LALOS-TOLI SONY Location MASAMBA EMU-LAB LALOS-TOLI PARIGI
MA-47 MA-48 MA-49 LA-18C LA-18D SO-20 KF SO-20 SO-21 SO-24C Sample M-1 MST-6 MRF-6 EMU-10A EMU-13 EMU-14 LA-17AB LA-17B PA-27E
Whole Rock (wt%)
66.31 65.75 65.12 63.81 64.27 67.40 67.87 51.01 68.82 SiO2 63.89 64.33 57.57 60.59 65.05 62.85 64.50 65.31 62.21
0.61 0.65 0.62 0.44 0.46 0.52 0.50 0.95 0.47 TiO2 0.70 0.64 1.00 0.84 0.49 0.70 0.51 0.55 0.43
13.45 12.72 13.16 14.93 14.92 13.63 13.54 14.34 12.46 Al2O3 14.83 14.65 16.08 14.39 14.25 14.48 14.73 15.04 16.98
3.78 4.34 4.22 3.96 3.69 2.77 2.83 8.25 2.86 FeOt 4.53 4.59 6.04 6.16 3.55 4.56 4.06 3.93 3.26
0.07 0.07 0.07 0.08 0.06 0.09 0.11 0.19 0.06 MnO 0.11 0.09 0.10 0.11 0.05 0.08 0.08 0.08 0.04
4.11 4.65 4.55 2.62 2.35 2.21 2.28 4.66 2.61 MgO 3.15 2.99 5.46 4.01 2.73 3.68 2.75 2.67 2.62
3.18 3.57 3.30 3.57 3.72 1.74 1.87 7.30 2.35 CaO 5.03 4.58 6.84 4.58 3.24 4.76 4.31 4.34 4.44
2.23 2.42 2.68 3.13 3.21 3.26 2.88 3.29 3.61 Na2O 2.51 2.56 2.32 3.37 3.40 2.96 3.12 2.91 4.26
4.99 4.20 4.71 4.85 4.87 4.76 5.02 3.76 4.71 K2O 3.94 3.65 2.94 2.47 3.98 3.94 3.67 3.41 3.68
0.14 0.16 0.19 0.25 0.19 0.25 0.26 0.53 0.30 P2O5 0.24 0.24 0.27 0.18 0.27 0.26 0.20 0.18 0.15
0.90 0.83 0.66 1.03 0.84 1.65 1.60 3.97 0.82 H2 O 0.82 1.33 1.14 2.91 1.91 0.97 1.22 1.31 0.14
99.77 99.36 99.29 98.66 98.58 98.28 98.76 99.07 Total 99.75 99.65 99.76 99.60 98.92 99.23 99.14 99.73 98.21
Trace element (ppm)
210 200 240 30 30 50 50 16 70 Cr 30 40 120 40 80 120 50 50 30
48 38 59 16 14 35 31 14 41 Ni 12 16 33 13 21 17 19 21 24
77 72 76 111 89 75 77 166 67 V 111 103 144 205 88 100 88 81 69
210 230 236 199 214 185.5 201 337 186.5 Rb 178 184.5 161.5 104.5 186 173.5 196 145.5 155.5
727 551 632 1805 1965 917 2290 2630 1095 Ba 1125 1010 586 267 1255 839 970 961 2530
26.4 25.1 33.5 36.6 18.25 29.2 30.9 11.3 21.5 Th 40.7 58.5 26.5 11.55 35.3 18.25 39.2 26.5 32.9
5.38 4.76 7.6 6.73 4.32 6.84 7.12 1.7 4.68 U 8.53 11.1 6.98 2.29 10.25 7.47 4.73 5.03 8.26
15 16.8 15.5 14.3 9.5 16.5 15.6 10.3 13.5 Nb 18.3 17.7 16.5 7.7 16.1 17.1 10.9 12.3 12.6
1.4 1.3 1.7 1.3 1 1.3 1.2 0.5 0.9 Ta 1.5 1.4 1.5 0.6 1.7 2.1 0.9 0.9 0.8
47.2 49.6 52.5 49.8 29.1 69.4 53.6 45 39.3 La 74.6 108.5 53 20.4 43.6 20.9 70.1 43.2 47.1
101.5 103.5 115 96.9 59.7 91.5 86.9 80.3 78.2 Ce 133 181 102.5 47.1 89.2 49.3 119.5 83.7 87
11.45 11.4 13.1 10.35 6.56 14.5 10.95 8.79 8.94 Pr 14 18.05 11.2 5.71 9.83 6.51 12.85 8.83 9.31
212 222 223 728 603 778 859 963 410 Sr 504 542 493 256 747 437 519 537 1460
32.8 40 37.6 28.1 18.5 39.5 29.9 33.6 25.1 Nd 50.3 60.2 42 18.2 26.8 21.6 32.9 29.5 34.3
208 260 239 211 154 209 225 56 189 Zr 197 209 255 213 213 222 180 222 214
6.5 7 7.8 5.9 4.3 6.6 6.3 1.7 5.4 Hf 6.3 6.7 7.5 5.7 6.5 6.1 4.9 5.8 6.5
6.89 7.86 8.11 5.03 3.68 6.85 5.34 5.95 4.96 Sm 9.09 9.68 7.78 4.66 5.14 5.79 5.21 5.14 5.81
1.2 1.18 1.13 1.15 1.03 1.64 1.27 1.56 1.02 Eu 1.73 1.75 1.62 1.09 1.15 1.45 1.12 1.1 1.71
5.97 5.35 5.93 2.86 2.45 4.61 3.43 3.33 3.75 Gd 7.85 8.64 6.68 4.82 3.19 4.87 2.95 2.77 3.5
1.04 1.03 1.06 0.47 0.38 0.73 0.56 0.59 0.62 Tb 1.21 1.19 1.02 0.85 0.53 0.85 0.49 0.52 0.6
5.61 5.96 5.77 2.41 1.89 3.85 2.97 3.68 3.42 Dy 6.2 5.86 5.17 4.97 2.74 4.71 2.47 2.86 3.43
36.2 35.5 37 15.5 11.9 24.6 19.9 20.5 23.6 Y 31.1 29.5 25.8 33.7 18.3 31.9 16.7 16.7 18
1.17 1.19 1.15 0.46 0.36 0.77 0.6 0.7 0.69 Ho 1.13 1.1 0.95 1.06 0.53 0.97 0.49 0.54 0.64
3.02 3.49 3.01 1.21 0.92 2.02 1.58 2.01 1.89 Er 3.36 3.21 2.79 2.88 1.37 2.59 1.25 1.52 1.77
0.54 0.5 0.55 0.22 0.17 0.37 0.3 0.27 0.36 Tm 0.47 0.45 0.38 0.52 0.25 0.49 0.23 0.22 0.24
3.12 3.22 3.04 1.27 0.98 2.24 1.82 1.81 2.21 Yb 3.17 3.08 2.54 3.06 1.46 2.8 1.31 1.53 1.48
0.51 0.47 0.49 0.22 0.17 0.37 0.31 0.27 0.36 Lu 0.47 0.47 0.37 0.52 0.24 0.46 0.22 0.23 0.22
1.48 1.49 1.38 1.44 1.41 1.30 1.33 1.51 1.13 A/NK 1.77 1.80 2.30 1.75 1.44 1.59 1.62 1.77 1.54
0.91 0.85 0.85 0.88 0.86 1.00 1.00 0.63 0.81 (A/CNK) 0.85 0.89 0.83 0.87 0.90 0.82 0.87 0.92 0.89
10.9 11.0 12.4 28.1 21.3 22.2 21.1 17.8 12.8 (La/Yb)n 5.8 6.8 7.8 4.8 21.4 5.4 38.4 39.4 22.8
4.37 4.35 4.39 4.27 4.32 2.88 3.59 4.14 4.17 Ce* 4.12 4.09 4.21 4.36 4.31 4.23 3.98 4.29 4.15
0.5 0.48 0.85 0.85 0.99 0.84 0.85 1.07 0.70 Eu* 1.70 2.70 3.70 0.70 0.81 0.82 0.80 1.80 0.3792

3.21 3.69 3.59 3.36 3.13 2.35 2.41 2.43 FeO 5.24 3.02 3.88
### 3.45 3.34
### 2.77
3.21 3.69 3.59 3.36 3.13 2.35 2.41 2.43 FeO 5.24 3.02 3.88
### 3.45 3.34
### 2.77
3.21 3.69 3.59 3.36 3.13 2.35 2.41 2.43 FeO 5.24 3.02 3.88
### 3.45 3.34
### 2.77
0.57 0.65 0.63 0.59 0.55 0.42 0.42 0.43 Fe2O3 0.92 0.53 0.68
### 0.61 0.59
### 0.49

4.20 4.83 4.69 4.40 4.10 3.08 3.14 3.17 Fe2O3T 6.85 3.95 5.07
### 4.51 ### 3.62
4.37
igh-K calc alkaline (CAK) Series Low-K to tholeiitic
PARIGI WEST PALU LATUPPA Pluton MASAMBA MAMASA GORONTALO
PA-28 PA-28C PA-28ENC WP-29 B WP-32 A WP-32B LA-69B LA-71A LA-71B Sample MST-3A MST-3B MRF-4B MA-41BA MA-45 GR-2 GR-3 55 GTL 62 GTL
Whole Rock (wt%)
62.69 65.40 55.05 57.95 68.80 63.50 64.44 66.29 68.4 SiO2 76.59 71.67 71.40 66.356 63.86 78.38 70.79 76.31 72.37
0.70 0.69 0.97 0.93 0.43 0.58 0.63 0.55 0.43 TiO2 0.16 0.43 0.44 0.4 0.64 0.21 0.45 0.15 0.40
13.85 13.82 18.17 14.25 14.01 14.26 15.41 15.13 14.79 Al2O3 12.66 13.4 13.48 15.983 13.55 11.37 13.22 12.53 13.00
4.96 4.38 7.29 6.35 2.62 4.41 3.91 3.42 2.43 FeOt 1.45 3.25 3.57 2.857 4.7 2.00 3.57 1.45 3.33
0.03 0.02 0.07 0.13 0.04 0.07 0.07 0.06 0.04 MnO 0.05 0.14 0.11 0.035 0.15 0.03 0.12 0.05 0.09
3.78 3.48 4.43 5.46 2.13 3.91 3.24 2.72 2.21 MgO 0.73 1.58 1.42 2.438 4.79 0.59 1.31 0.54 1.33
4.47 4.43 3.85 6.14 2.68 4.37 4.66 4.42 3.37 CaO 1.87 2.95 3.65 4.031 3.18 2.28 3.21 2.08 3.31
3.50 3.32 4.70 2.63 3.53 2.95 3.17 3.13 3.09 Na2O 3.86 2.71 3.30 4.403 6.55 4.14 3.37 4.58 3.57
2.35 2.51 2.26 3.79 4.21 3.54 3.25 3.32 4.08 K2O 1.98 2.07 1.99 1.06 1.2 0.25 1.45 1.58 1.82
0.11 0.11 0.08 0.41 0.18 0.30 0.18 0.17 0.13 P2O5 0.04 0.09 0.10 0.118 0.16 0.04 0.10 0.03 0.09
3.14 1.45 2.53 0.99 0.64 1.30 0.83 0.56 0.82 H2 O 0.58 1.63 0.46 2.01 1.05 0.70 2.33 0.61 0.60
99.58 99.61 99.41 99.02 99.27 99.19 99.79 99.77 99.79 Total 99.97 99.92 99.92 99.691 99.83 99.99 99.92 99.91 99.91
Trace element (ppm)
90 60 160 140 30 110 70 40 50 Cr 8 7 10 20 240 10 8 7 10
22 21 87 19 11 19 10 12 10 Ni 4 3 6 0 5 5 6 5 8
170 153 270 123 54 108 88 75 58 V 13 45 50 51 81 45 42 9 50
126.5 124 153.5 167 217 173.5 165.5 158 193 Rb 31.3 36.4 45 41.6 51.4 16.2 32.6 24.1 40.2
376 278 571 1185 800 880 689 891 667 Ba 141.5 344 288 152 428 115 340 131 275
10.2 11.2 7.84 63.9 34 37.9 24.6 24.4 25.9 Th 2.59 4.41 7.36 0.49 29.5 3.6 5.15 1.79 6.05
1.83 2.53 1.65 2.97 8.16 10.45 6.22 5.54 7.02 U 0.93 0.54 1.66 0.61 5.63 0.72 1.21 0.64 1.11
5.5 5.7 8 17.1 14 16.5 12.1 11.3 12.4 Nb 1.4 5.5 5.3 3.8 18.7 3.3 7 1.4 5
0.5 0.5 0.7 1 1.5 1.7 1 1 1.2 Ta 0.2 0.4 0.4 0.3 1.6 0.2 0.5 0.2 0.3
16.3 13.3 16.6 173.5 50.7 49.6 45.8 44.7 44.7 La 7.6 6.2 15.4 3.5 59 9.5 19.8 8.1 10.2
38.4 31.3 35.4 316 102.5 97.7 81.8 78.9 77.2 Ce 16.6 12.7 31.1 7.5 111.5 20.1 40.4 17.9 19.2
4.71 3.92 4.07 32.8 10.85 10.4 8.9 8.5 8.39 Pr 2.11 1.62 3.99 0.94 12.7 2.69 4.81 2.51 2.42
194.5 163.5 303 520 524 521 515 540 462 Sr 88.8 150.5 160.5 443 231 149 178 92.4 153.5
15 12.9 12.6 102.5 29.3 28.7 32.7 31.4 29.8 Nd 8.9 7.2 16.1 3.1 47.3 10.9 20.2 11.4 10.9
179 163 212 255 204 211 216 188 204 Zr 102 146 152 127 289 120 150 109 159
5 4.6 5.7 6.9 5.6 5.9 5.9 5.1 5.7 Hf 3.9 4.6 4.8 2.9 8 3.6 4.7 3.5 4.3
3.93 3.67 2.84 14.55 5.3 5.61 5.54 5.36 4.88 Sm 2.3 1.85 4.12 0.96 9.06 3.12 5.05 3.05 2.91
0.99 0.9 1.15 1.94 0.95 1.32 1.24 1.27 1.09 Eu 0.46 0.82 0.92 0.69 1.33 0.91 1.29 0.8 0.85
3.93 3.7 2.45 5.79 2.73 4.13 4.23 3.94 3.72 Gd 2.41 1.92 4.54 1.02 7.57 3.41 5.39 3.78 3.45
0.7 0.69 0.45 1.1 0.48 0.68 0.56 0.51 0.48 Tb 0.5 0.4 0.86 0.18 1.15 0.61 1.08 0.67 0.59
4.04 4.02 2.69 5.68 2.52 3.64 3.07 2.68 2.62 Dy 3.31 2.64 5.88 1 6.82 4 6.94 4.48 3.94
27.4 28.3 20.4 29.6 17 24.6 19.7 16.7 17.9 Y 20.3 16.6 38.2 6.9 44.3 24.9 40.6 32.6 28.7
0.87 0.85 0.6 1.11 0.48 0.74 0.61 0.53 0.54 Ho 0.7 0.6 1.31 0.2 1.39 0.84 1.45 1 0.89
2.34 2.36 1.78 2.77 1.22 2.01 1.71 1.32 1.37 Er 2.23 1.87 4.21 0.54 3.7 2.66 4.52 3.02 2.65
0.43 0.42 0.33 0.4 0.23 0.38 0.23 0.19 0.19 Tm 0.38 0.31 0.71 0.11 0.56 0.35 0.7 0.48 0.43
2.46 2.47 2.22 2.39 1.37 2.29 1.54 1.23 1.2 Yb 2.93 2.38 4.62 0.54 3.57 2.54 4.84 3.36 2.95
0.39 0.4 0.38 0.35 0.23 0.38 0.25 0.2 0.21 Lu 0.48 0.37 0.77 0.09 0.58 0.4 0.77 0.6 0.52
1.67 1.69 1.79 1.69 1.35 1.64 1.77 1.73 1.56 A/NK 1.49 2.00 1.78 1.91 1.12 1.61 1.86 1.36 1.66
0.84 0.85 1.06 0.73 0.92 0.86 0.90 0.90 0.95 (A/CNK) 1.06 1.11 0.95 1.02 0.76 1.01 1.02 0.96 0.94
4.8 3.9 5.4 52.1 26.5 15.5 21.3 26.1 26.7 (La/Yb)n 1.9 2.9 3.9 4.9 5.9 2.7 2.9 1.7 2.5
4.38 4.33 4.31 4.19 4.37 4.30 4.05 4.05 3.99 Ce* 4.15 4.01 3.97 4.13 4.07 3.98 4.14 3.97 3.86
0.77 0.74 1.31 0.54 0.68 0.80 0.76 0.81 0.75 Eu* 0.60 1.60 2.60 3.60 4.60 0.96 0.72 0.63 0.82

4.22 3.72 6.20


### 5.40 2.23 3.75 3.32 2.91 2.07
### FeO 1.23 2.76 1.70 3.03 1.23 2.83
4.22 3.72 6.20
### 5.40 2.23 3.75 3.32 2.91 2.07
### FeO 1.23 2.76 1.70 3.03 1.23 2.83
4.22 3.72 6.20
### 5.40 2.23 3.75 3.32 2.91 2.07
### FeO 1.23 2.76 1.70 3.03 1.23 2.83
0.74 0.66 1.09
### 0.95 0.39 0.66 0.59 0.51 0.36
### Fe2O3 0.22 0.49 0.30 0.54 0.22 0.50

5.51 4.87 8.11


### 7.06 2.91 4.90 4.35 3.80 2.70
### Fe2O3T 1.61 3.61 2.22 3.97 1.61 3.70
Series
Pluton BARRU MASAMBA POLEWALI
Sample DIO BR MST-13 MRF-4 MRF-7 MA-67B POL-13 POL-ST1 POL-19
Whole Rock (wt%)
SiO2 60.67 66.14 68.66 74.28 72.51 65.16 64.78 64.78
TiO2 0.52 0.54 0.51 0.13 0.21 0.52 0.63 0.56
Al2O3 15.52 14.54 14.41 13.57 13.63 15.18 14.19 14.68
FeOt 4.37 3.85 2.74 1.52 1.82 4.23 4.29 3.87
MnO 0.09 0.08 0.05 0.03 0.05 0.07 0.09 0.07
MgO 3.4 2.44 2.17 0.17 0.76 2.59 2.89 2.54
CaO 4.94 3.94 3.21 0.70 1.5 3.81 4.26 3.94
Na2O 2.92 2.49 2.37 3.30 3.99 2.61 2.39 2.42
K2O 4.06 4.59 4.85 5.82 4.96 3.93 4.31 4.98
P2O5 0.28 0.22 0.13 0.02 0.05 0.23 0.24 0.21
H2 O 2.88 0.89 0.71 0.40 0.41 1.34 1.6 1.6
Total 99.65 99.72 99.81 99.94 99.89 99.67 99.67 99.65
Trace element (ppm)
Cr 42 30 30 12 20 38 33 40
Ni 28 11 6 13 21 25 20 36
V 113 103 46 5 16 85 94 87
Rb 131.5 179.5 233 158 184 177.5 185.5 207
Ba 1130 1645 747 26.9 244 1215 1540 2230
Th 14.1 44.5 23 35.3 33.6 47 47.7 43.9
U 4.11 9.34 6.14 3.98 5.59 9.33 10.1 8.82
Nb 6.8 15.4 11.4 3.6 12.8 17.5 17.4 14.9
Ta 0.4 1.2 1 0.4 0.9 1.3 1.4 1.2
La 34.7 64.5 34.4 75.1 39 61 61 64
Ce 61.1 112 66.3 157 75.6 111 110 112
Pr 7.15 11.2 6.98 17.2 8.67 11.7 11.6 11.25
Sr 705 562 324 13.1 113.5 586 533 563
Nd 28.5 40.3 25.3 53 32.5 42.6 41.7 39.2
Zr 145 191 169 302 214 204 200 178
Hf 3.8 6.1 5.3 9.3 6.5 6.3 6.2 5.5
Sm 5.69 7.38 4.37 7.18 6.45 7.8 7.81 6.8
Eu 1.59 1.56 1.1 0.18 0.53 1.64 1.6 1.48
Gd 5.15 6.45 3.72 5.98 5.07 6.92 7.02 5.99
Tb 0.68 0.98 0.55 0.57 0.72 1.05 1.07 0.86
Dy 3.86 5.04 2.79 2.23 4.04 5.47 5.57 4.42
Y 23.9 25.7 13.8 10 25.2 27.8 27.5 23
Ho 0.78 0.95 0.51 0.39 0.84 1.01 1.01 0.82
Er 2.15 2.76 1.44 1.22 2.21 2.96 2.98 2.41
Tm 0.32 0.4 0.19 0.16 0.31 0.43 0.44 0.34
Yb 2.08 2.69 1.35 1.04 1.94 2.93 2.87 2.41
Lu 0.35 0.41 0.2 0.17 0.33 0.42 0.44 0.37
A/NK 1.69 ### 1.60 1.58 1.16 1.14 1.78 1.65 1.57
(A/CNK) 0.85 0.90 0.96 1.04 0.93 0.98 0.87 0.89
(La/Yb)n 12.0 17.2 18.2 51.8 14.4 ### 14.9 15.2 19.0
Ce* 3.88 4.17 4.28 4.37 4.11 4.15 4.14 4.17
Eu* 0.88 0.68 1.68 0.08 0.27 0.67 0.65 0.70
HK (Shoshonitic)
EWALI MAMASA LALOS-TOLI
POL-11 MA-41 MA-41B MA-45B MA-47 MA-48 MA-49 LA-18C LA-18D

65.42 61.14 62.50 63.7 66.31 65.75 65.12 63.81 64.27


0.4 0.71 0.65 0.61 0.61 0.65 0.62 0.44 0.46
14.2 14.62 14.40 13.21 13.45 12.72 13.16 14.93 14.92
2.56 5.27 4.73 4.51 3.78 4.34 4.22 3.96 3.69
0.07 0.11 0.10 0.07 0.07 0.07 0.07 0.08 0.06
1.82 3.74 3.47 4.34 4.11 4.65 4.55 2.62 2.35
4.21 5.07 4.68 3.98 3.18 3.57 3.30 3.57 3.72
1.15 3.21 3.11 2.88 2.23 2.42 2.68 3.13 3.21
4.43 4.03 4.35 4.52 4.99 4.20 4.71 4.85 4.87
0.13 0.31 0.27 0.23 0.14 0.16 0.19 0.25 0.19
5.4 0.78 0.82 1.2 0.90 0.83 0.66 1.03 0.84
99.79 98.98 99.08 99.26 99.77 99.36 99.29 98.66 98.58

45 40 30 270 210 200 240 30 30


24 10 8 53 48 38 59 16 14
34 151 122 81 77 72 76 111 89
227 172 220 65.8 210 230 236 199 214
1020 1180 1165 496 727 551 632 1805 1965
54.4 45.1 45.6 30.8 26.4 25.1 33.5 36.6 18.25
10.5 6.58 9.65 5.92 5.38 4.76 7.6 6.73 4.32
20.8 16 20.1 17.5 15 16.8 15.5 14.3 9.5
1.9 1.3 1.5 1.7 1.4 1.3 1.7 1.3 1
71.9 64.3 58.4 56.3 47.2 49.6 52.5 49.8 29.1
127.5 110 110.5 121 101.5 103.5 115 96.9 59.7
12.75 13.2 11.7 13.7 11.45 11.4 13.1 10.35 6.56
288 537 475 217 212 222 223 728 603
42.9 36.5 42.1 39.6 32.8 40 37.6 28.1 18.5
213 212 220 246 208 260 239 211 154
6.7 6.4 5.8 7.9 6.5 7 7.8 5.9 4.3
7.25 7.12 7.06 8.42 6.89 7.86 8.11 5.03 3.68
1.2 1.61 1.55 1.21 1.2 1.18 1.13 1.15 1.03
6.42 5.5 4.81 6.64 5.97 5.35 5.93 2.86 2.45
0.92 0.88 0.81 1.18 1.04 1.03 1.06 0.47 0.38
4.87 4.6 4.94 6.47 5.61 5.96 5.77 2.41 1.89
26.1 29.6 26.7 43.2 36.2 35.5 37 15.5 11.9
0.89 0.9 0.94 1.34 1.17 1.19 1.15 0.46 0.36
2.64 2.36 2.79 3.56 3.02 3.49 3.01 1.21 0.92
0.37 0.41 0.37 0.63 0.54 0.5 0.55 0.22 0.17
2.61 2.45 2.42 3.66 3.12 3.22 3.04 1.27 0.98
0.38 0.41 0.37 0.6 0.51 0.47 0.49 0.22 0.17
2.12 1.52 1.46 1.37 1.48 1.49 1.38 1.44 1.41
0.99 0.78 0.79 0.78 0.91 0.85 0.85 0.88 0.86
19.8 ### 18.8 17.3 11.9 10.9 11.0 12.4 28.1 21.3
4.21 3.78 4.23 3.92 4.37 4.35 4.39 4.27 4.32
0.53 0.76 0.77 0.48 0.5 0.48 0.85 0.85 0.99
Series
SONY Location MASAMBA EMU-LAB
SO-20 KF SO-20 SO-24C Sample M-1 MST-6 MRF-6 EMU-10A
Whole Rock (wt%)
67.40 67.87 68.82 SiO2 63.89 64.33 57.57 60.59
0.52 0.50 0.47 TiO2 0.70 0.64 1.00 0.84
13.63 13.54 12.46 Al2O3 14.83 14.65 16.08 14.39
2.77 2.83 2.86 FeOt 4.53 4.59 6.04 6.16
0.09 0.11 0.06 MnO 0.11 0.09 0.10 0.11
2.21 2.28 2.61 MgO 3.15 2.99 5.46 4.01
1.74 1.87 2.35 CaO 5.03 4.58 6.84 4.58
3.26 2.88 3.61 Na2O 2.51 2.56 2.32 3.37
4.76 5.02 4.71 K2O 3.94 3.65 2.94 2.47
0.25 0.26 0.30 P2O5 0.24 0.24 0.27 0.18
1.65 1.60 0.82 H2 O 0.82 1.33 1.14 2.91
98.28 98.76 99.07 Total 99.75 99.65 99.76 99.60
Trace element (ppm)
50 50 70 Cr 30 40 120 40
35 31 41 12 16 33 13
75 77 67 111 103 144 205
185.5 201 186.5 Rb 178 184.5 161.5 104.5
917 2290 1095 Ba 1125 1010 586 267
29.2 30.9 21.5 Th 40.7 58.5 26.5 11.55
6.84 7.12 4.68 U 8.53 11.1 6.98 2.29
16.5 15.6 13.5 Nb 18.3 17.7 16.5 7.7
1.3 1.2 0.9 Ta 1.5 1.4 1.5 0.6
69.4 53.6 39.3 La 74.6 108.5 53 20.4
91.5 86.9 78.2 Ce 133 181 102.5 47.1
14.5 10.95 8.94 Pr 14 18.05 11.2 5.71
778 859 410 Sr 504 542 493 256
39.5 29.9 25.1 Nd 50.3 60.2 42 18.2
209 225 189 Zr 197 209 255 213
6.6 6.3 5.4 Hf 6.3 6.7 7.5 5.7
6.85 5.34 4.96 Sm 9.09 9.68 7.78 4.66
1.64 1.27 1.02 Eu 1.73 1.75 1.62 1.09
4.61 3.43 3.75 Gd 7.85 8.64 6.68 4.82
0.73 0.56 0.62 Tb 1.21 1.19 1.02 0.85
3.85 2.97 3.42 Dy 6.2 5.86 5.17 4.97
24.6 19.9 23.6 Y 31.1 29.5 25.8 33.7
0.77 0.6 0.69 Ho 1.13 1.1 0.95 1.06
2.02 1.58 1.89 Er 3.36 3.21 2.79 2.88
0.37 0.3 0.36 Tm 0.47 0.45 0.38 0.52
2.24 1.82 2.21 Yb 3.17 3.08 2.54 3.06
0.37 0.31 0.36 Lu 0.47 0.47 0.37 0.52
1.30 1.33 1.13 A/NK 1.77 1.80 2.30 1.75
1.00 1.00 0.81 (A/CNK) 0.85 0.89 0.83 0.87
22.2 21.1 12.8 (La/Yb)n 5.8 6.8 7.8 4.8
2.88 3.59 4.17 Ce* 4.12 4.09 4.21 4.36
0.84 0.85 0.70 Eu* 1.70 2.70 3.70 0.70
High-K calc alkaline (CAK)
EMU-LAB LALOS-TOLI PARIGI
EMU-13 EMU-14 LA-17AB LA-17B 24 D PA-27E PA-28 PA-28C

65.05 62.85 64.50 65.31 69.30 62.21 62.69 65.40


0.49 0.70 0.51 0.55 0.45 0.43 0.70 0.69
14.25 14.48 14.73 15.04 12.34 16.98 13.85 13.82
3.55 4.56 4.06 3.93 2.77 3.26 4.96 4.38
0.05 0.08 0.08 0.08 0.07 0.04 0.03 0.02
2.73 3.68 2.75 2.67 2.56 2.62 3.78 3.48
3.24 4.76 4.31 4.34 2.52 4.44 4.47 4.43
3.40 2.96 3.12 2.91 3.62 4.26 3.50 3.32
3.98 3.94 3.67 3.41 4.68 3.68 2.35 2.51
0.27 0.26 0.20 0.18 0.29 0.15 0.11 0.11
1.91 0.97 1.22 1.31 0.55 0.14 3.14 1.45
98.92 99.23 99.14 99.73 99.13 98.21 99.58 99.61

80 120 50 50 70 30 90 60
21 17 19 21 24 22 21
88 100 88 81 69 170 153
186 173.5 196 145.5 212 155.5 126.5 124
1255 839 970 961 1055 2530 376 278
35.3 18.25 39.2 26.5 17.9 32.9 10.2 11.2
10.25 7.47 4.73 5.03 3.55 8.26 1.83 2.53
16.1 17.1 10.9 12.3 10.7 12.6 5.5 5.7
1.7 2.1 0.9 0.9 0.7 0.8 0.5 0.5
43.6 20.9 70.1 43.2 39 47.1 16.3 13.3
89.2 49.3 119.5 83.7 79.7 87 38.4 31.3
9.83 6.51 12.85 8.83 8.78 9.31 4.71 3.92
747 437 519 537 408 1460 194.5 163.5
26.8 21.6 32.9 29.5 24.8 34.3 15 12.9
213 222 180 222 187 214 179 163
6.5 6.1 4.9 5.8 5 6.5 5 4.6
5.14 5.79 5.21 5.14 4.82 5.81 3.93 3.67
1.15 1.45 1.12 1.1 0.96 1.71 0.99 0.9
3.19 4.87 2.95 2.77 3.14 3.5 3.93 3.7
0.53 0.85 0.49 0.52 0.57 0.6 0.7 0.69
2.74 4.71 2.47 2.86 3.05 3.43 4.04 4.02
18.3 31.9 16.7 16.7 21.5 18 27.4 28.3
0.53 0.97 0.49 0.54 0.64 0.64 0.87 0.85
1.37 2.59 1.25 1.52 1.66 1.77 2.34 2.36
0.25 0.49 0.23 0.22 0.32 0.24 0.43 0.42
1.46 2.8 1.31 1.53 1.91 1.48 2.46 2.47
0.24 0.46 0.22 0.23 0.33 0.22 0.39 0.4
1.44 1.59 1.62 1.77 1.12 1.54 1.67 1.69
0.90 0.82 0.87 0.92 0.79 0.89 0.84 0.85
21.4 5.4 38.4 39.4 12.4 22.8 4.8 3.9
4.31 4.23 3.98 4.29 4.31 4.15 4.38 4.33
0.81 0.82 0.80 1.80 0.71 0.37920497 0.77 0.74
ARIGI WEST PALU LATUPPA
PA-28ENC WP-29 B WP-31 C WP-32 A WP-32B LA-69B LA-71A LA-71B

55.05 57.95 71.42 68.80 63.50 64.44 66.29 68.4


0.97 0.93 0.26 0.43 0.58 0.63 0.55 0.43
18.17 14.25 14.18 14.01 14.26 15.41 15.13 14.79
7.29 6.35 1.78 2.62 4.41 3.91 3.42 2.43
0.07 0.13 0.03 0.04 0.07 0.07 0.06 0.04
4.43 5.46 1.13 2.13 3.91 3.24 2.72 2.21
3.85 6.14 1.67 2.68 4.37 4.66 4.42 3.37
4.70 2.63 3.24 3.53 2.95 3.17 3.13 3.09
2.26 3.79 4.60 4.21 3.54 3.25 3.32 4.08
0.08 0.41 0.08 0.18 0.30 0.18 0.17 0.13
2.53 0.99 1.25 0.64 1.30 0.83 0.56 0.82
99.41 99.02 99.64 99.27 99.19 99.79 99.77 99.79

160 140 20 30 110 70 40 50


87 19 11 19 10 12 10
270 123 54 108 88 75 58
153.5 167 200 217 173.5 165.5 158 193
571 1185 1585 800 880 689 891 667
7.84 63.9 41.5 34 37.9 24.6 24.4 25.9
1.65 2.97 10.75 8.16 10.45 6.22 5.54 7.02
8 17.1 15.8 14 16.5 12.1 11.3 12.4
0.7 1 1.2 1.5 1.7 1 1 1.2
16.6 173.5 39.1 50.7 49.6 45.8 44.7 44.7
35.4 316 74.6 102.5 97.7 81.8 78.9 77.2
4.07 32.8 8.12 10.85 10.4 8.9 8.5 8.39
303 520 890 524 521 515 540 462
12.6 102.5 21.9 29.3 28.7 32.7 31.4 29.8
212 255 198 204 211 216 188 204
5.7 6.9 6.2 5.6 5.9 5.9 5.1 5.7
2.84 14.55 4.06 5.3 5.61 5.54 5.36 4.88
1.15 1.94 0.87 0.95 1.32 1.24 1.27 1.09
2.45 5.79 2.46 2.73 4.13 4.23 3.94 3.72
0.45 1.1 0.42 0.48 0.68 0.56 0.51 0.48
2.69 5.68 2.31 2.52 3.64 3.07 2.68 2.62
20.4 29.6 15.6 17 24.6 19.7 16.7 17.9
0.6 1.11 0.45 0.48 0.74 0.61 0.53 0.54
1.78 2.77 1.15 1.22 2.01 1.71 1.32 1.37
0.33 0.4 0.22 0.23 0.38 0.23 0.19 0.19
2.22 2.39 1.25 1.37 2.29 1.54 1.23 1.2
0.38 0.35 0.22 0.23 0.38 0.25 0.2 0.21
1.79 1.69 1.38 1.35 1.64 1.77 1.73 1.56
1.06 0.73 1.06 0.92 0.86 0.90 0.90 0.95
5.4 52.1 19.0 26.5 15.5 21.3 26.1 26.7
4.31 4.19 4.19 4.37 4.30 4.05 4.05 3.99
1.31 0.54 0.73 0.68 0.80 0.76 0.81 0.75
Low-K to tholeiitic
MASAMBA MAMASA GORONTALO
MST-3A MST-3B MRF-4B MA-41BA MA-45 GR-2 GR-1

76.59 71.67 71.40 66.356 63.86 78.38 71.12


0.16 0.43 0.44 0.4 0.64 0.21 0.40
12.66 13.4 13.48 15.983 13.55 11.37 12.75
1.45 3.25 3.57 2.857 4.7 2.00 3.50
0.05 0.14 0.11 0.035 0.15 0.03 0.11
0.73 1.58 1.42 2.438 4.79 0.59 1.65
1.87 2.95 3.65 4.031 3.18 2.28 3.84
3.86 2.71 3.30 4.403 6.55 4.14 3.56
1.98 2.07 1.99 1.06 1.2 0.25 0.80
0.04 0.09 0.10 0.118 0.16 0.04 0.09
0.58 1.63 0.46 2.01 1.05 0.70 2.14
99.97 99.92 99.92 99.691 99.83 99.99 99.96

8 7 10 20 240 10 <10
4 3 6 0 5 5
13 45 50 51 81 45
31.3 36.4 45 41.6 51.4 16.2 2.1
141.5 344 288 152 428 115 37.8
2.59 4.41 7.36 0.49 29.5 3.6 0.59
0.93 0.54 1.66 0.61 5.63 0.72 0.19
1.4 5.5 5.3 3.8 18.7 3.3 0.5
0.2 0.4 0.4 0.3 1.6 0.2 0.3
7.6 6.2 15.4 3.5 59 9.5 3
16.6 12.7 31.1 7.5 111.5 20.1 9.2
2.11 1.62 3.99 0.94 12.7 2.69 1.64
88.8 150.5 160.5 443 231 149 96.8
8.9 7.2 16.1 3.1 47.3 10.9 8.4
102 146 152 127 289 120 66
3.9 4.6 4.8 2.9 8 3.6 2.8
2.3 1.85 4.12 0.96 9.06 3.12 3.26
0.46 0.82 0.92 0.69 1.33 0.91 1.11
2.41 1.92 4.54 1.02 7.57 3.41 3.86
0.5 0.4 0.86 0.18 1.15 0.61 0.8
3.31 2.64 5.88 1 6.82 4 5.69
20.3 16.6 38.2 6.9 44.3 24.9 37.2
0.7 0.6 1.31 0.2 1.39 0.84 1.23
2.23 1.87 4.21 0.54 3.7 2.66 4
0.38 0.31 0.71 0.11 0.56 0.35 0.59
2.93 2.38 4.62 0.54 3.57 2.54 3.99
0.48 0.37 0.77 0.09 0.58 0.4 0.62
1.49 2.00 1.78 1.91 1.12 1.61 1.90
1.06 1.11 0.95 1.02 0.76 1.01 0.93
1.9 2.9 3.9 4.9 5.9 2.7 2.5
4.15 4.01 3.97 4.13 4.07 3.98 4.15
0.60 1.60 2.60 3.60 4.60 0.96 0.75
GORONTALO
GR-3 55 GTL 62 GTL

70.79 76.31 72.37


0.45 0.15 0.40
13.22 12.53 13.00
3.57 1.45 3.33
0.12 0.05 0.09
1.31 0.54 1.33
3.21 2.08 3.31
3.37 4.58 3.57
1.45 1.58 1.82
0.10 0.03 0.09
2.33 0.61 0.60
99.92 99.91 99.91

8 7 10
6 5 8
42 9 50
32.6 24.1 40.2
340 131 275
5.15 1.79 6.05
1.21 0.64 1.11
7 1.4 5
0.5 0.2 0.3
19.8 8.1 10.2
40.4 17.9 19.2
4.81 2.51 2.42
178 92.4 153.5
20.2 11.4 10.9
150 109 159
4.7 3.5 4.3
5.05 3.05 2.91
1.29 0.8 0.85
5.39 3.78 3.45
1.08 0.67 0.59
6.94 4.48 3.94
40.6 32.6 28.7
1.45 1 0.89
4.52 3.02 2.65
0.7 0.48 0.43
4.84 3.36 2.95
0.77 0.6 0.52
1.86 1.36 1.66
1.02 0.96 0.94
2.9 1.7 2.5
4.14 3.97 3.86
0.72 0.63 0.82

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