1.

- Cd → Cd+2 +2e-

Datos

E°=0.403V

[Cd+2] =1mol/L
0.0592V
𝐸 = 𝐸0 − 𝑙𝑜𝑔𝑄
𝑛
0.0592𝑉
𝐸 = 𝐸0 − log[𝐶𝑑+2 ]
1
𝐸 = 0.403𝑉 − 0.592𝑉𝑙𝑜𝑔[𝐶𝑑+2 ]
𝐸 = 0.403𝑉 − 0.592𝑉𝑙𝑜𝑔[1]

𝑬 = 𝟎. 𝟒𝟎𝟑𝑽

Chart Title
0.45
0.4
0.35
0.3
0.25
0.2
0.15
0.1
0.05
0
1 2 3 4 5 6 7 8 9 10 11 12 13 14

Series2

2.- 4Cd + 4H+ +O2 → 4Cd2 +2H2O+ 4e-

E0 = 2.036V
0.0592V
𝐸 = 𝐸0 − 𝑙𝑜𝑔𝑄
𝑛
0.0592𝑉
𝐸 = 1.230𝑉 − 𝑥𝑙𝑜𝑔𝑄
4
0.0592𝑉 [𝐶𝑑+2 ]4
𝐸 = 2.036𝑉 − 𝑙𝑜𝑔
4 [𝐻 + ]4
0.0592𝑉
𝐸 = 2.036𝑉 − log[𝑙𝑜𝑔1 − 𝑙𝑜𝑔𝐻 +4 ]
4
 𝑬 = 𝟐. 𝟎𝟑𝟔𝑽 − 𝟎. 𝟎𝟓𝟗𝟐𝒑𝑯

2.5

1.5
E(V)

0.5

0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15

3. Cd+2 + 2H2O → Cd(OH)2 + 2H+

Datos

[Cd+2] = 1mol/L

K = 1.67x10-14

log k = -13.78

[𝐻 + ]2 [Cd(OH)2 ]
𝐾=
[𝐶𝑑2+ ][𝐻2 𝑂]2
𝑙𝑜𝑔𝐾 = 2𝑙𝑜𝑔[𝐻 + ]
−13.78 = −2 log[𝐻 + ]
𝒑𝑯 = 𝟔. 𝟖𝟗

4.5

3.5

2.5

1.5

0.5

0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
Para el agua

O2 + 4H+ + 4e- → 2H2O

2H+ + 2e- → H2
0.0591
E𝑎 = 𝐸𝑎0 + log[𝑝𝑜2 (𝐻 + )4 ]
4
0.0591 (𝐻 + )2
E𝑏 = 𝐸𝑏0 + log[ ]
4 𝑝𝐻2

E𝑎 = 1.228 − 0.0591 𝑝𝐻
E𝑏 = 0.000 − 0.0591 𝑝𝐻

Eh (Volts) Cd - H2O - System at 25.00 C

2.0

1.5

1.0 Cd(OH)2

Cd(+2a)
0.5

0.0

-0.5

-1.0
Cd
-1.5

-2.0
0 2 4 6 8 10 12 14

C:\HSC6\EpH\Cd25.iep pH

ELEMENTS Molality Pressure

Cd 1.000E+00 1.000E+00