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Journal of Building Engineering 5 (2016) 260–266

Contents lists available at ScienceDirect

Journal of Building Engineering


journal homepage: www.elsevier.com/locate/jobe

Eco-friendly insulation material production with waste olive seeds,


ground PVC and wood chips
Hanifi Binici a,n, Orhan Aksogan b
a
Kahramanmaraş Sutcu Imam University Department of Civil Engineering, Kahramanmaraş 46100, Turkey
b
Toros University Department of Civil Engineering, Mersin 33140, Turkey

art ic l e i nf o a b s t r a c t

Article history: The waste of the olive oil production process has been a notably important pollution source in Medi-
Received 14 November 2015 terranean countries, such as Italy, Spain, Greece, and Turkey. In recent years, the environmental impact of
Received in revised form this type of waste created a rich source, and researchers have been focusing on the treatment of olive oil
16 January 2016
mill waste. Furthermore, olive seed, waste PVC and wood chips are wastes that cause significant detri-
Accepted 26 January 2016
mental effects on the environment, following the production stage.
Available online 28 January 2016
In this study, insulation materials containing waste olive seeds, ground PVC, wood chips, plaster and
Keywords: epoxy were produced, and their properties were investigated. The unit weight, water absorption rate,
Olive seeds ultrasonic penetration velocity, thermal conductivity coefficient, compressive and flexure strengths
Unit weight
properties of the samples were determined. It can be seen from the results that most properties have
Insulation materials
improved with the addition of the additives,
Thermal conductivity coefficient
The unit weights of the samples and their thermal conductivity coefficients decreased, thanks to olive
seeds, PVC and wood chips. However, the decrease in the unit weight was accompanied by an increase in
the water absorption and a decrease in the flexural and compressive strengths of the samples, luckily
remaining at acceptable levels for the additive rates in the samples.
& 2016 Elsevier Ltd. All rights reserved.

1. Introduction Petrochemicals (mainly polystyrene) and other materials obtained


from natural sources are processed with high energy consump-
Heating of buildings is a real energy cost problem of economy tions (glass and rock wools) for the insulation of buildings. These
both worldwide and in Turkey. Hence, research on the conserva- materials cause significant pollution on the environment, parti-
tion of energy in this respect is of utmost importance. Due to the cularly, during the production when nonrenewable materials are
foregoing reason, the thermal insulation of buildings and new used and fossil energy is consumed. Also, during the disposal of
insulation materials of construction rendered research on [1]. some materials, there are problems in reusing or recycling them at
Energy consumption in Turkey in the last 15 years increased by the end of their original use. The researchers aiming at developing
100% and dependence on foreign sources increased from 51% to thermal and acoustic insulating materials using natural or recycled
74%. Hence, efficient use of energy is becoming a more important materials were encouraged to introduce the concept of “sustain-
issue every day. In this respect, in the Energy Efficiency Technol- ability” in building design. For example, hemp or wood fiber are
ogy Roadmap of the Turkish government, the development of already being used commercially but they must be further im-
technologies for producing new generation materials and ele- proved for being widely used, because their performance is similar
ments of construction to support the energy efficiency in buildings to the synthetic ones. Some others are only at an early stage of
and industry has been set as a target [2]. being developed and are currently being studied [4].
As many authors have shown in their studies, nowadays, waste Like other organic materials, sunflower stalk fibers have also
is of great importance. Making use of alternative wastes is in- been used to produce insulation materials. There is a significant
evitable due to the rapid depletion of natural resources [3]. amout of sunflower production in Turkey. After the production the
sunflower stem poses a serious pollution problem. Sunflower
stems are cleaned, burned or used for simple heating purposes,
n
Correspondence to: Department of Civil Engineering, Kahramanmaraş Sutcu causing serious environmental problems. To prevent this problem,
Imam University, Kahramanmaraş 46100, Turkey. Tel.: þ 90 344 2801660;
fax: þ90 344 2801602.
the present study proposes a useful way of using those waste
E-mail addresses: hbinici@ksu.edu.tr (H. Binici), materials for the insulation of buildings [1].
aksogan@cu.edu.tr (O. Aksogan). The insulation materials sector in Turkey constitutes more than

http://dx.doi.org/10.1016/j.jobe.2016.01.008
2352-7102/& 2016 Elsevier Ltd. All rights reserved.
H. Binici, O. Aksogan / Journal of Building Engineering 5 (2016) 260–266 261

50% share of the petroleum-derived products. Widely used ones 2. Materials and methods
are the extruded polystyrene foam (XPS) and expanded poly-
styrene foam (EPS). These products are not produced in Turkey 2.1. Materials
and are supplied by importing, causing an economic loss for the
country. Development of new generation materials will render 2.1.1. Olive seeds
alternatives to the current domestic products and it is expected The prominent oil production countries in the world are Spain,
that they do not cause the inconvenience observed in the in- Italy, Greece, Turkey, Tunisia, Portugal, Morocco, Algeria, Argenti-
organic structures and existing products and, yet, are easily na, Syria and Jordan (Fig. 1). Turkey ranks first in the world in
applicable. edible-olive production and consumption, followed by Spain,
95% of the total worldwide olive and olive oil production occurs Greece and Italy. In addition, the olive oil production and con-
in the Mediterranean countries, i.e., Greece, Italy, Spain, Syria, sumption per person ranks fourth. In Turkey, there are 83 million
Tunisia, and Turkey. During the production process of olive oil, a olive trees on 8 million acres, and this figure increases yearly. In
significant number of olive seeds remain [5,6]. Olive seeds from the past two decades, the number of olive trees has tripled. The
olive oil production and the solid waste, which consists of pulp olive pulp is 10–25% oil, and the seed is 25–50% oil. Olive seeds
parts, compose 3–6% oil and 40–65% humidity in the process. Al- were collected as waste from the olive mills in the City of Kahra-
though olive seeds were only used as a natural method of pre- manmaras, in the Southeastern Region of Turkey.
venting weed growth in old Roman times, it has many applications
today. Olive seeds are used as an additive and mixed with bitumen 2.1.2. Wood chips
for use in road construction. Although the calorific value of the Wood chips are waste material from wood cutting in various
seed varies depending on the type of olive trees, soil structure, timber production facilities and factories (Fig. 1). World timber
feeders in the climate and soil, and oil production technology, production has decreased between the years of 2005 and 2009.
olive seeds provide great advantages as fuel [7–9]. This type of The production capacity decreased from 437 million cubic meters
waste can be used as a solid fuel and an additive for animal feed. In in 2005 to 362 million cubic meters in 2009 [26]. The world's
addition, it is used in the preparation of composite fertilizers. largest timber manufacturer is the United States. In 2009, the
Previous studies have suggested that the seed, which is non- United States produced 61.9 million cubic meters of timber, fol-
phytotoxic and has organic material content, can be used in the lowed by Canada, China, Brazil and Germany [27]. Turkey, with its
fields where the soil needs to be strengthened. Additionally, che- 5.8 million cubic meters production, is the thirteenth largest
micals such as lipase can be produced by fermentation [10,11]. producer among 166 countries in the world timber production and
Activated carbon, methanol, acetic acid and carbon have been has 1.6% share of the world production [28]. Wood chips used in
successfully obtained by distilling using the hydrolysis process. this study were obtained from the carpenters in the city.
The process of obtaining active carbons from bagasse has been
used widely in recent years. Environmentalists claim that this ef- 2.1.3. Ground PVC
ficient approach can render the benefit of waste from olive oil Plastic can be turned into fibers and used in the textile industry.
mills for cogeneration applications possible. PVC material is used as an alternative to wood in window frames.
A 16 MW plant built in Spain uses 105 thousand tons of seeds Thus, PVC usage reduces tree cutting and protects forests. Ad-
per year for fuel and satisfies the electricity demand of approxi- ditionally, PVC profiles do not require painting, whereas, wood
mately 50 thousand homes [12]. In this facility, 0.8 kg seed is re- requires it several times, and PVC is much lighter than wood. In
quired as fuel to produce 1 kWh of electricity. this study, waste PVC was obtained from waste collection sites
Since, the heating costs in winter and cooling costs in summer (Fig. 1).
are too high in Turkey, buildings are insulated to reduce these
costs. Approximately 40% of the energy in Turkey is consumed in 2.1.4. Plaster
residences, 80% of which is for heating purposes. Therefore, var- Gypsum is a mineral whose chemical composition is calcium
ious insulation materials are used in existing buildings in Turkey sulfate. The type of calcium sulfate with two crystal-water mole-
[13,14]. cules is called gypsum (CaSO4 þ 2 H2O). Plaster crystals are found
The quantity of natural resources is decreasing because of the in clay, marl, salt and spaces of plaster Mountains. It is found in
increase of the world population. Natural resources can be pro- Anatolia, particularly the upper side of the Red River with rock salt
tected by recycling. Additionally, material consumption can be as large rocks. Two different plaster stone species can be obtained
reduced and natural resources can be efficiently used when waste using two processing methods. In this study, dehydrated gypsum
is recycled. Therefore, recycling is important for the protection and used in plaster works is used.
efficient use of natural resources [15]. In recent years, many waste
materials are widely used for various purposes in constructional 2.1.5. Epoxy
engineering [16–18]. Epoxy is an adhesive chemical resin from the thermoset group.
Energy conservation has recently gained importance for many It is notably resistant against water, acid and alkali, and it does not
economic and strategic reasons. For example, 40% of the total lose its strength properties over time. Epoxy adhesive that is used
consumed energy in the EU is consumed in the buildings, and half to fill cracks converts the discontinuous environment created by
of this energy is lost through the walls [19]. Recently, new building the crack into continuity by smoothly connecting both sides of the
materials and construction systems have provided many benefits opening along the crack, preventing stress concentration.
in terms of building characteristics and comfort. In this context,
the insulation of building walls is a new popular research subject 2.2. Method
because proper insulation saves energy [20–25].
Previous studies have shown that the reuse of wastes is of 2.2.1. Production of insulation material
worldwide significant importance. This study intends to produce Waste PVC is ground up in the cement size in the grinding
an insulation material using olive seeds, ground PVC, and wood machine and mixed with plaster and epoxy as binders. The sam-
shavings. With the method in this study, wastes can be reused, ples produced are described by the volume mixing ratios and by
which will help to create employment in mass production and the weights of the samples in Table 1. Using the foregoing raw
contribute to the national economy. materials, various samples were produced with different rates.
262 H. Binici, O. Aksogan / Journal of Building Engineering 5 (2016) 260–266

Fig. 1. Materials used.

Table 1 the samples was 10  10x2 cm. Then, mortar was poured into
Mix proportion (g). moulds, and 5 bars compressive force was applied for 2 min to
compact the mortar in the mould. After one day the samples were
Samples no Plaster Olive seeds Epoxy Wood chips Ground PVC Water
taken out of the molds. Then, after being cured for 2 days, the
NI 400 0 0 0 0 125 samples were dried in an oven at 110 °C. The production process is
N2 300 100 0 0 0 100 shown in Fig. 2. Eight different groups of samples were produced.
N3 200 200 0 0 0 75 Three samples were tested for each group and the average of the
N4 100 300 0 0 0 50
N5 0 50 175 100 200 0
three results was used for each property.
N6 0 100 150 100 150 0
N7 0 150 125 100 100 0 2.2.2. Experimental
N8 0 200 100 100 50 0 2.2.2.1. Unit weights and water absorption rates. The unit weights
and water absorption rates of the produced samples were de-
termined according to TS 2823 and ASTM C 67–03, respectively
Wood chips, being organic, are susceptible to corruptive bacteria [29].
that could evolve in the mixture. To overcome this problem, an
anti-bacterial agent was used. 2.2.2.2. Ultrasonic transmission velocity. The wave velocity was
For mixing the samples, ground olive seeds, PVC, and wood calculated after measuring the surface ultrasonic wavelength of
chips were placed in a mixer together with plaster or epoxy as the rays transmitted through the thickness of the sample (see
binder and mixed for 5 min. For the homogeneity of the mixes, Fig. 3).
while the mixer was turning the correct amount of water (Samples
made with plaster) was then sprayed on the mixes using an air 2.2.2.3. Thermal conductivity coefficient. The thermal conductivity
pump. Moisture content of the samples was 1,5% and the size of coefficient was found in accordance with ASTM C 1113- 90 [30]
H. Binici, O. Aksogan / Journal of Building Engineering 5 (2016) 260–266 263

Fig. 2. Production scheme for the insulation materials.

200 °C, measuring time is standard 60 s, sensor is standard 60 s,


ambient condition is temperature: 5–35 °C, humidity: below 85%
RH, power source is AC 100–240 V, 50/60 Hz and power con-
sumption is 60 W. The calibration of the machine is done at reg-
ular intervals.

2.2.2.4. Compressive and flexure strengths. The compressive


strengths of the samples of 16  16  4 cm dimensions and the
flexure strengths of the samples of 3  3  4 cm dimensions were
found using a Diwick Roell Z010 Universal tester.

Fig. 3. Ultrasonic transmission velocity meter. 3. Results and discussion

3.1. Unit weights and water absorption rates

The unit weights and water absorption rates of the samples are
given in Figs. 5 and 6, respectively. When the contribution rate of
the olive seeds increased, the unit weight of the sample decreased.
The PVC doped sample had the lowest unit weight. When the
amount of wood chips was fixed, the unit weights of the samples
decreased with an increase in the amount of olive seeds, probably
Fig. 4. Termal conductivity meter.
due to the interfacial gaps between the seeds and the paste. As
expected, the samples with lower unit weights had significantly
using the Hot-Wire Method (see Fig. 4). higher water absorption rates.
The testing system follows similar principles to the thermal
needle probe. However, the sensor sits on the surface of the spe- 3.2. Ultrasonic penetration velocities
cimen, and the line-source heat is propagated in only one direc-
tion. This method can be readily applied in situ, although a flat and The ultrasonic penetration velocities of the samples are given
polished contact surface is required for sound coupling. The in Fig. 7. The olive seed and PVC doped samples with lower unit
measuring range of the data logger is 0.023–12 W/mK, accuracy is weights had lower ultrasonic penetration velocities. Likewise, the
75% reading value per reference plate, reproducibility is 10 to samples that were doped with olive seeds with a porous structure
264 H. Binici, O. Aksogan / Journal of Building Engineering 5 (2016) 260–266

1,5

Unite weight of samples (g/cm )


3
1,33 1,28
1,23
1,15 1,11 1,09 1,05
0,97
1

0,5

0
N1 N2 N3 N4 N5 N6 N7 N8
Samples

Fig. 5. Unit weights of the samples.

30
Water absorbtion of samples(%)

25
25 23
21
20 18
17
15
15 13
10
10

0
N1 N2 N3 N4 N5 N6 N7 N8
Samples

Fig. 6. Water absorption ratios of the samples.

0,05
Ultrasonic penetration speed of

0,04
0,035
samples (km/s)

0,031
0,03 0,027
0,022 0,023
0,019
0,02 0,017
0,015

0,01

0
N1 N2 N3 N4 N5 N6 N7 N8
Samples

Fig. 7. Ultrasonic penetration velocities of the samples.


Thermal conductivity cofficient of

0,15 0,145
samples.(w/mK)

0,0992 0,0981 0,0965


0,1
0,0866 0,0841
0,0742 0,0789

0,05

0
N1 N2 N3 N4 N5 N6 N7 N8
Samples

Fig. 8. Thermal conductivity coefficients of the samples.


H. Binici, O. Aksogan / Journal of Building Engineering 5 (2016) 260–266 265

had lower ultrasonic penetration velocities. In these samples the 3.4. Compressive and flexure strengths
sound waves were damped due to the voids. There is a direct re-
lationship between the thermal conductivity coefficient and ul- The compressive and flexure strengths of the composites are
trasonic transmission properties of the samples. When one given in Figs. 9 and 10, respectively. The compressive strength
quantity increases, the other also increases because these two increased with an increase in the olive seed and PVC and wood
characteristics are both directly related to the void structure of the chips doping ratios because the PVC and wood chips formed the
material. When the amount of wood chips was fixed, the ultra- main phase of the composite and the olive seeds stiffened it. The
sonic transmission velocity of the olive seed and PVC doped compressive strengths of the samples with additives were about
samples decreased, i.e., the sound was fading in the material be- 2.48 times that of the reference sample. Generally, the olive-seed
cause of the porosity of the material. Similarly, the thermal con- and PVC and wood chips doped samples had higher flexure
ductivity coefficients of these samples decreased. strengths than the reference samples. This can be explained by the
The ultrasonic sound penetration velocity coefficient test was olive seeds and wood chips acting as fibers. The flexure strengths
conducted in accordance with ASTM C 597. The sound penetration of the doped samples were 44% higher than that of the reference
velocity has no direct relationship with the material strength [31]. sample. These results can be explained by the contribution of the
The P-wave velocity of the material decreases with increasing fibers in the composites to the flexural strength.
amount of voids. The ultrasonic sound velocity of the insulation In fact, the samples with low unit weights and thermal con-
material made with ground PVC, wood chips and epoxy was found ductivity coefficients were expected to have low compressive
to be 0.023–0.035 km/s. These values are quite low compared to strength. In addition, the samples with only plaster had higher
other building materials [32]. flexure strengths than those with only epoxy. Despite some
strength wise relative weaknesses, the strength values obtained
3.3. Thermal conductivity coefficients are sufficient for an insulation material.

The thermal conductivity coefficients of the samples are given


in Fig. 8. To identify a material as a thermal insulation material 4. Conclusion
according to Turkish and international standards, the thermal
conductivity coefficient (λ) must be less than 0.1 W/mK. Fig. 8 The following results were obtained from this study.
shows that all olive seed, PVC, wood chips and plaster doped
samples are acceptable as insulation materials. The microstructure 1. With the increase in olive seed ratio, the thermal conductivity
of these samples had many related or unrelated voids, as con- coefficients of the samples decreased. Some low thermal con-
firmed by their ultrasonic transmission with low ultrasonic pe- ductivity coefficients were obtained in sample group N5. The
netration velocities, which is a result of the sound waves being reason for this is the presence of more air gaps in the samples.
absorbed while passing through the material. However, the sam- TS 805 EN 60155 requires a thermal conductivity coefficient of
ples that were produced with only plaster had higher ultrasonic lower than 0.1. Hence, all samples except the references are
penetration velocities and thermal conductivity coefficients than appropriate to be used as insulation materials. As obtained in
the other samples. Moreover, olive seeds, PVC grains, and plaster the findings, the research materials, olive seeds, waste PVC, and
are strongly related to one another. Hence, the thermal con- wood chips, are suitable as additives to be used together with
ductivity coefficients were lower because of the air cavities be- epoxy to produce insulation materials.
tween these materials and the ground PVC pulp. In general, the 2. The olive seeds, waste PVC and wood chips doped samples had
thermal conductivity coefficients of the material increased with an lower unit weights, higher water absorption rates and lower
increase in its unit weight. ultrasonic transmission velocities than the other samples.
The low density of the samples led to lower heat transfer 3. The flexure and compressive strengths of all samples were
coefficients. A high proportion of the materials used contain above the values required by the standards.
empty space. At the same time, the material can absorb water due 4. Olive seeds, waste PVC and wood chips doping made with
to the materials used to retain water, and thus the water absorp- binder led to better thermal insulation than the references.
tion value is expected to be higher. While the unit weight and the
thermal conductivity of sample N8 were lower than the others, its Finally, this study proves that an appropriate insulating mate-
water absorption rate was higher than them. rial can be produced using olive seeds, PVC, and wood chips. This

0,7

0,57
Compressive strength of samples

0,6
0,53
0,49
0,5
0,42
0,4 0,35
0,33
(MPa)

0,3 0,25
0,23
0,2

0,1

0
N1 N2 N3 N4 N5 N6 N7 N8
Samples
Fig. 9. Compressive strengths of the samples.
266 H. Binici, O. Aksogan / Journal of Building Engineering 5 (2016) 260–266

0,1 0,097
0,091
0,083

Flexure strength of samples (MPa)


0,08
0,074
0,067
0,061
0,055

0,05

0
N1 N2 N3 N4 N5 N6 N7 M8

Samples
Fig. 10. Flexure strengths of the samples.

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