2.16.WATER, DEAERATION
- i ‘ipping ope!
Avery widely Be na erie ante
that obeys Henry's Law. Dissolved alt BT.
shit guacmesettsaee yr contains no oxygen
‘The pure steam stripping VaP> ‘i
driving force for mass transfer is ae tit
yuently vacuum deaeration is ut
it will in to etc a part of the feed into en Pils
drops until its vapor pressure plus those ofthe dissolved EEC yg
the vapor pressure of water overwhelms the vapor PFOSSLTy AX te
therefore, the latter can be neglected for practical purposes. ;
‘i it will flash and be cooled to a
a column under pressure of 2000 Pa. abs., it wi 1 oe
this lower temperature Henry's Law constant for DO is reduce y only dae
294K. That is flashing will sustain considerable deaeration inspite of cooling.
Forasmuch as the water flashed to the lower temperature in one equilibri
very little stripping vapor available in the lower partof the column. The amount of«
so small that there is practically no upward movement of vapor phase from col
together with high liquid flow used in these deaerators drags the small vapor ph
column where the oxygen is reabsorbed quickly.
Hence a double-stage vacuum deaeration is opted. This 2nd-stage column is
with the first column, but at a lower absolute pressure. This generates addit
vapor for stripping the DO to a lower concentration. Thus if the foregoing dea
with another deaerator operating at 1333 Pa. abs., the feedwater will flash
generated vapor will scavenge the stripped oxygen out of the packed bed while
down to 284K.
Asmall amount of inert gas introduced to the bottom of the vacuum column
reduction of oxygen concentration in the effluent water. For instance, 0.4 Nm3.h 0
23 m*.h” of feedwater can reduce the effluent oxygen content by an additional 66'
more effective in reducing oxygen content compared to straight vacuum deaeration. H
of steam accentuates its stripping potential.
sration is
DESIGN
‘The usual design procedure is a trial-and-error approach based on successive
-and-error approi
‘ ich based o1
‘The vacuum deaerator dia is so select
m®.h~ per m? of column cross-sectional area,
In erstwhile design, the vacuum deaerators used ceramic packing and operated
rate. However, most modern column u: ii
sa se plastic packing (50mm or larger) with a p
ed as to give rise to a liquid irrigati
‘The operation is 80 overwhelmin,
i
design purposes, ee
im. film
can be dropped. Therefore, the number of uae soe ne eae
‘umber of transfer units
NTUp, = In|nol’) from an oil by
per 100 kmol of oil s1
Determine the ni
to 0.05 mol
No steam is condes
lution =
Since the steam does me
OL equation is