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Ground Improvement (2003) 7, No.

1, 9–23 9

Stabilising effects of different binders in some


Swedish soils
H. ÅHNBERG, S.-E. JOHANSSON,y H. PIHL{ and T. CARLSSON§
 Swedish Geotechnical Institute, Linköping, Sweden; y Cementa AB, Sweden; {Partek
Nordkalk Oy Ab, Finland; § SSAB Merox AB, Sweden

In Sweden, lime and lime–cement have been used for En Suède, la chaux et une combinaison chaux-ciment ont
several decades as stabilising agents in deep stabilisation été utilisés depuis plusieurs décennies comme agents
of soft soils. More recently, other types of binder have stabilisants pour la stabilisation de sols mous. Plus récem-
come into use, but so far only to a limited extent. In order ment, d’autres types de liants ont été utilisé, mais de façon
to gather experience about the effect of various binders, limitée. Dans le but d’acquérir de l’expérience concernant
laboratory tests have been performed on different types of l’effet de différents liants, un certain nombre d’essais en
soil stabilised with a range of binders. Lime, cement, fly laboratoire ont été exécutés sur différents types de sols
ash and blast furnace slag in different combinations stabilisés avec différents liants. La chaux, le ciment, les
together with different admixtures, such as gypsum, silica cendres, et les scories de haut fourneaux combinés dans
fume and calcium chloride, have been used in the différents mélanges avec du gypse, de la silice et du
investigations. The variation in strength with type of chloride de calcium ont éte utilisés dans ces essais. La
binder has been studied, and comparisons have also been variation de la résistance avec le type de liants a été étudié
made with results from some previous investigations using et des comparaisons ont été faites avec des essais prove-
different binders. The tests showed that there is no nant d’études antérieures de différents liants. Les essais
optimal, universal binder for stabilisation of the soils. n’ont pas résulté en un liant optimal universel, mais ils
Whereas some binders are robust, yielding good results in ont démontré que certains liants affichent de bons résultats
most types of soil, there are also binders that produce very dans la plupart des types de sols étudiés alors que certains
good results in certain soils but poor results in others. autres liants montrent de bons résultats dans certains sols
Both similarities and differences in effects were found for et des mauvais résultats dans d’autres. Des similitudes
different binders. ainsi que des différences se rapportant à l’effet de
différents liants ont été enregistées au cours des essais.

Introduction This programme has been set up and funded by different


actors in the market involved with deep stabilisation in
Since the first application of deep-mix columns in 1975, two Sweden. There is also interest in this subject in other parts of
types of binder have mainly been used for deep stabilisation Europe. Some experience of the effect of different binders
of soft soils in Sweden. During the first 10 years quicklime has recently been gained in an EC-funded (Brite EuRam)
alone was used in the process, but since the mid-1980s, project, EuroSoilStab, involving tests on organic soils stabi-
combinations of lime and cement have been increasingly lised with different types of binder (den Haan, 1998;
used. Today, only a few per cent of the production of deep- Åhnberg and Holm, 1999; Cortellazzo and Cola, 1999; Hebib
mix columns in Sweden is performed with binders other and Farrell, 1999; Lahtinen et al., 1999).
than the lime–cement combination. However, there is a In this paper, the results obtained from one of the projects
potential for other binders to be used. Other types of binder within the SD research programme are presented. In the
are increasingly being used internationally, mainly in con- project, different binders have been tested to a varying
nection with shallow stabilisation of capping layers and sub- extent in three types of soil. The main purpose has been to
bases, but also for deep soil stabilisation. Apart from the study the effect of different binders on the strength of
possible environmental benefit of reusing industrial by- stabilised soil, but other properties were also determined in
products, there could be economic as well as technical order to demonstrate similarities and differences between
reasons for incorporating a larger number of binders. the various materials. The paper describes the measured
In order to study the effects of different binders in the increase in unconfined compressive strength, and changes in
stabilisation of soft soils, various projects in this area have water content and consistency limits. Some comparisons are
been initiated within a comprehensive research programme also made with experience from the tests conducted in
run by the Swedish Deep Stabilisation Research Centre (SD). Sweden within the EuroSoilStab project. The aim is not to
pick out any specific binder from the others, but to illustrate
(GI 140) Paper received 19 November 2001; last revised 2 August differences and similarities in strength increase between
2002; accepted 10 October 2002 various combinations of binder and soil. Studies of the more
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H. Åhnberg et al.

general mechanical behaviour of different stabilised soils Organic soils are often considered more difficult to stabilise
and studies of influencing soil parameters and chemical than clays. They usually demand larger quantities of binder
reactions of the binders have commenced in other projects in order to achieve satisfactory results. The organic soil was
and will be reported at a later date. a gyttja from Holma Mosse in the eastern part of Sweden.
This soil had previously been investigated in the EuroSoil-
Stab project.
The Holma gyttja, gyttja 1, is a clayey gyttja with a water
Tests performed content of 220% and a liquid limit of 170%. The organic
content is 10%. The properties of the gyttja are shown in
Choice of soils Table 1.
The type of soil can greatly influence the results of Investigations of the chemical properties and other soil
stabilisation. Soils that could be expected to give varying parameters that may be of importance for the stabilisation
results with the different binders were therefore sought in results are being performed in a related project within the
order to obtain a large variation in stabilisation effects. Three same research programme. The results from these investiga-
types of soft soil were chosen for the investigations. tions will be published at a later stage.
Two of the soils in the investigations were soft clays, clay
1 and clay 2. They have fairly similar geotechnical properties
according to the routine investigations, but originated from Choice of binder
two different parts of Sweden. Experiences from different There are many binder materials that possess hardening
applications of deep stabilisation have shown that in some properties and which could potentially be used for the
areas, for example west of Stockholm and on the eastern stabilisation of soils. In this project the traditional binders
coast, there are layers of clay in which pure lime gives very cement and quicklime, which are most commonly used in
poor stabilising results. However, deep stabilisation of the Sweden, were chosen. In addition binders based on ground
soft clays along the west coast of Sweden most often granulated blast furnace slag or fly ash, which are more widely
produces good results, including relatively high strengths used for soil stabilisation in other countries, were included.
with both lime–cement and pure lime. Investigations on Apart from these, several other materials were used at
clays from different areas, stabilised in the laboratory with percentages of 2–33% of the total binder content, together
the same type and amount of lime, have shown that there with different combinations of the main binders. Among
can be more than a tenfold difference in strength 28–91 days these were mineral additions and admixtures commonly
after stabilisation (Åhnberg and Pihl, 1998). Clay 1 was taken used to improve the hardening or setting properties of
at Linköping in the eastern part of Sweden. This is a post- concrete. These were silica fume, alumina cement, calcium
glacial clay deposited during periods of sedimentation in chloride and gypsum. Certain tests were also performed with
alternating lake and brackish sea water. Clay 2 was taken at the addition of a secondary product from lime production,
Löftabro on the Swedish west coast; it is a marine post- kiln dust, mixed with lime. Also included in the investiga-
glacial clay containing occasional shells. tions were tests with water-glass—that is, sodium silicate—as
The geotechnical properties of the two clays are similar, admixture. Water-glass was tested mainly as an activator for
although the Löftabro clay has a somewhat higher water the cement reactions, but is also expected to affect the
content and lower shear strength than the Linköping clay. mixing ability of the soils since it is commonly used also as
Both clays are high-plastic, with liquid limits around 70% a peptising agent.
and organic contents around 1%. The bulk densities are just The different composite binders together with mineral
above 1:5 t=m3 . The properties of the clays are shown in additions or admixtures are shown in Table 2. A total binder
Table 1. quantity corresponding to 100 kg=m3 was used in most of
The third soil chosen for the tests was an organic soil. the tests, but some tests were also performed with a higher
quantity of 150 kg=m3 .
The main type of cement used was the currently dominant
standard cement in Sweden, a Portland-limestone cement
Table 1. Properties of the test soils designated CEM II/A-LL 42·5 R (CEN, 2000). The limestone
Holma exchange is approximately 15%. Only a year before the start
Linköping Löftabro Mosse of the investigations, the main Swedish cement producer
clay 1 clay 2 gyttja 1 changed the composition of the standard cement for con-
Depth: m 3–6 2–5 3–5 struction purposes in Sweden from ordinary cement to
Density: t/m3 1·55 1·52 1·23 limestone cement. Because of this, certain comparative tests
Specific gravity: t/m3 2·72 2·73 2·36 were performed with ordinary Portland cement, CEM I 42·5 R,
Plastic limit: % 24 23 64 which had earlier been used in numerous stabilisation
Water content: % 78 89 220 projects. Another cement used was SH Portland cement, CEM
Liquid limit: % 70 66 170 I 52·5 R, which is more fine-grained and hardens more
Undrained shear 15 8 5
rapidly than standard cement. An even more fine-grained
strength} : kPa cement or microcement, ultra-fine Portland cement, CEM I
Sensitivity 20 25 10 52·5 R LA SR, was also included in the investigations. The
Organic content: % 1·0 1·0 10·3 mean particle size of this cement is 0·005 mm compared with
Chloride content: % 0·01 0·38 ,0·01
0·01 and 0·03 mm for the SH cement and the standard
cement respectively. The compositions of the different ce-
Carbonate content: % 1·1=1·0 (CaCO3 =MgCO3 ) 8·4=,0·5 0·6
Sulphide content: % 0·05 0·18 0·2
ments are shown in Table 3.
The main type of lime used was the quicklime normally
pH 7·6 8·7 8·5
used in deep stabilisation, CL90-Q (CEN, 1998). This
Clay content: % 63 72 80
‘standard’ quicklime is relatively highly burnt and because
}
Determined by fall-cone tests. of this is also labelled lime HB. To study the relevance of the
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Stabilising effects of binders in Swedish soils

Table 2. Types of binder


Additional Binder ratio : %
Binder 1 Binder 2 binder/admixture by weight Abbreviation
Lime HB (std) l
Lime LB llb
Cement (std) c
Cement SH c2
Cement ordinary c3
Cement ultra-fine c0:005
Cement (std) Lime (std) 50 : 50, 75 : 25 cl
Cement (std) Slag 50 : 50, 25 : 75 cs
Cement SH Slag 50 : 50 c2 s
Cement (std) Fly ash 50 : 50, 75 : 25 cf
Cement (std) PFBC ash 50 : 50 cpf
Slag Lime (std) 50 : 50, 75 : 25 sl
Slag Lime (std) Fly ash 33 : 33 : 33 slf
Lime (std) Kiln dust 70 : 80, 80 : 20 lk
Cement (std) Lime (std) Kiln dust 33 : 33 : 33 clk
Cement (std) Alumina cement 95 : 5 cal
Lime (std) Silica fume 90 : 10 lsi
Cement (std) Silica fume 90 : 10 csi
Cement (std) Lime (std) Silica fume 45 : 45 : 10 clsi
Cement (std) Slag Silica fume 45 : 45 : 10 cssi
Lime (std) CaCl2 (salt) 98 : 2, 95 : 5 lsa
Cement (std) CaCl2 98 : 2, 95 : 5 csa
Cement (std) Slag CaCl2 42·5 : 42·5 : 5 cssa
Cement (std) Fly ash CaCl2 42·5 : 42·5 : 5 cfsa
Cement (std) Lime (std) Water-glass 42·5 : 42·5 : 5 clwa
Cement (std) Slag Water-glass 42·5 : 42·5 : 5 cswa
Lime (std) Gypsum 80 : 20 lg
Cement (std) Gypsum 80 : 20 cg
Cement (std) Slag Gypsum 40 : 40 : 20 csg
Cement (std) Fly ash Gypsum 40 : 40 : 20 cfg
Slag Lime slaked Gypsum 33 : 33 : 33 sl2 g

Table 3. Chemical composition and specific surfaces of binders and admixtures


Specific
surface:
CaO:% SiO2 : % Al2 O3 : % Fe2 O3 :% MgO:% K2 O:% Na2 O: % SO3 : % m2 =kg Blaine
Lime (std) 93·0 1·4 0·6 0·3 1·0 ,0·1 ,0·1 ,0·1 661
Lime slaked 72·7 1·4 0·6 0·3 1·1 ,0·1 ,0·1 ,0·1 –
Lime LB 92·5 1·8 1·0 0·4 1·5 0·2 ,0·1 0·2 –
Cement (std) 61·4 19·9 3·6 2·6 2·8 1·0 0·2 3·3 466
Cement SH 62·3 20·4 4·2 2·4 3·3 1·3 0·3 3·4 534
Cement ordinary 61·8 19·7 4·2 2·6 3·4 1·3 0·3 3·4 358
Cement ultra–fine 64·2 22·5 3·4 4·4 0·8 0·6 0·1 2·5 330
Slag 32·1 35·2 13·6 0·2 16·8 0·6 0·6 1·8 476
Fly ash 5·9 54·4 30·5 5·5 1·8 1·2 0·5 0·5 465
PFBC ash 21·8 32·4 18·2 6·7 11·8 1·7 0·8 7·8 470
Alumina cement 38·3 2·5 43·5 13·11 0·7 0·1 ,0·1 0·1 301
Silica fume 0·6 90·3 1·6 3·9 1·2 1·6 0·5 0·2 –
Gypsum 26·2 1·5 1·2 13·5 0·5 0·2 0·1 18·9 698
Kiln dust 56·1 3·7 2·3 1·4 1·4 1·6 0·7 3·1 480
Water-glass ,0·01 53·7 ,0·01 ,0·01 ,0·01 0·1 28·6 ,0·1 –
Salt 23·6 ,0·01 ,0·01 ,0·01 1·2 ,0·01 7·1 4·0 –

requirement for hard-burned lime, which is normally in- slaked lime, CL70-S, was used when the effect of gypsum was
cluded in the specifications for limes to be used in deep investigated. In order to study the influence of particle size
stabilisation, a soft-burned lime, lime LB, was also used. on the stabilisation effect, two types of more coarsely ground
Since problems with inhomogeneous mixing normally arise standard lime were also used. The maximum particle sizes of
when using quicklime together with dihydrate gypsum, a these two types were 2 mm and 4 mm, compared with
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H. Åhnberg et al.

0·1 mm for the standard lime. The compositions of the of clearly dubious results, any spare samples were used for
different types of lime are shown in Table 3. a control test.
The slag used was a ground granulated blast furnace slag The unconfined compression tests were performed with a
with a glass content of 99%. This binder has been used only rate of 1·5%/min on specimens with a height-to-diameter
to a very limited extent for deep stabilisation of soils in ratio of 2. Before strength testing, the specimens were cut
Sweden (Jelisic and Leppänen, 1999). Its composition is and smoothed to form parallel end surfaces. The end plates
shown in Table 3. were lubricated with grease in order to minimise friction at
The ashes used were a pure coal fly ash from pulverised the end surfaces.
coal combustion and a combined cyclone/bed ash from the The densities and water contents of the samples were
combustion of coal and dolomite in a pulverised fluid bed determined in connection with the unconfined compression
combustion (PFBC) plant. The fly ash was of Class F (ASTM, tests. This was done mainly in order to check the homo-
1994), thus having pozzolanic properties. Fly ash has not yet geneity and uniformity of samples prepared in the same
been used for deep stabilisation purposes in Sweden, but a way, but also to investigate the changes and differences in
number of lime–fly ash test columns have been installed in water content and density when using different binders.
a research project (Holm and Åhnberg, 1987). The composi-
tion of the ashes is shown in Table 3.
The other materials, which were used in smaller quanti-
ties, were of varying compositions. The kiln dust was a fine- Test results and discussion
grained material collected in a filter from the flue gases of
the lime kiln. It contained mainly calcium carbonate dust, Change in density and water content
fuel ash and some calcium oxide. The alumina cement was a When adding a stabilising agent to a soft soil, a certain
ciment fondu: that is, a cement produced from limestone and increase in density and decrease in water content can be
bauxite. High-alumina cements of this type are highly reac- expected. The extent of this change depends on the amount
tive cements based on calcium aluminates instead of calcium and type of binder used. Neglecting the effects of certain
silicates, which are the basis of Portland cements. The structural changes caused by the initial chemical reactions,
constituents are mainly CA (monocalcium aluminate) to- the change in density can roughly be estimated from the
gether with secondary phases of C12 A7 , C2 S and different specific densities of the added binders. In the gyttja, adding
ferrites. The silica fume was a by-product from the manufac- a binder quantity of 100 kg=m3 would change the density
ture of ferro-silicon alloys. The silica fume contains very fine from 1:23 t=m3 of the original undisturbed soil to a maxi-
spherical grains of amorphous silicate. The mean particle mum density of about 1:28 t=m3 when using the different
size was less than 0·0002 mm and the silicate content 90%. composite binders and to a slightly higher density when
The gypsum used in the investigations was a ferrous using pure cement. However, when preparing the specimens
dihydrate gypsum derived as a secondary product from the by layer-wise compaction, a certain amount of air-filled
manufacture of titanium dioxide. Apart from dihydrate pores and larger pockets of air will be entrapped. Adding
gypsum, it contained iron hydroxides and titanium hydro- binders corresponding to 100 kg=m3 changed the density to
xides. The contents of SO3 and CaO were therefore relatively 1:27 t=m3 as a mean. This indicates a low quantity of air
low. The water-glass was a hydrous sodium silicate contain- pockets in the mixed gyttja samples, which was also estab-
ing 54% SiO2 and 29% Na2 O. The salt used contained 70% of lished by visual inspection of the samples (Fig. 1(a)). The
CaCl2 . See Table 3. corresponding mean measured densities in the stabilised
clay 1 and clay 2 were 1:55 t=m3 and 1:52 t=m3 respectively,
compared with the calculated densities of 1:58–1:60 t=m3
Preparation of samples and 1:55–1:57 t=m3 . The measured mean densities are the
Combinations of binders were mixed prior to being mixed same as those of the original undisturbed clays, indicating a
with the soil. They were then mixed with soil for 5 min. larger volume of air pockets in the stabilised clay samples.
Directly afterwards, the mixtures were gradually filled into Later on, the procedure for filling tubes with stabilised clay
50 mm dia. plastic tubes using a compaction pressure of was slightly modified, in order to produce more homoge-
100 kPa on approximately every 30 mm layer of mixture, in neous samples. However, in order to allow for comparisons
accordance with the common procedure used in Sweden between all the different types of stabilised sample, the
(Carlsten and Ekström, 1995). The gyttja mixture developed
a sticky consistency, preventing the use of the standard
compaction device. The mixtures were therefore filled into
the sample tubes using light hand pressure. The mixtures in
the tubes were given a height of about 0·15 m. Each batch of
mixed soil contained a volume large enough to prepare six
to eight samples. The tubes were sealed with rubber lids and
stored in a climate room at a temperature of 88C. This
corresponds to the mean ground temperature in Sweden.
The samples were stored in the same compartment seven
days to one year after mixing.

Testing
To investigate the strength increase of the samples,
unconfined compression tests were performed 7, 28, 91 and
364 days after mixing. Duplicate tests were performed 28
and 91 days after mixing, whereas only single tests were
performed after one week and one year. However, in cases Fig. 1. Samples of stabilised soil: (a) stabilised gyttja; (b) stabilised clay
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Stabilising effects of binders in Swedish soils

mode of preparation was not changed until all the test series wN is the natural water content of the unstabilised soil (as a
had been completed. An example of the distribution of air decimal number); x is the amount of dry binder added to
pockets in a stabilised clay sample is shown in Fig. 1(b). the soil (t=m3 ); and a is the content of non-evaporable water
In both clays, the measured densities of the lime-stabilised of the hydration product with respect to dry binder weight
samples were somewhat higher than the mean densities of (as a decimal).
all samples, whereas the densities of the cement-stabilised The non-evaporable water content, a, of the main binders
samples were somewhat lower. The lime-stabilised soils are can be assumed to be approximately 0·23 in a hydrated
affected by a higher degree of structural change caused by cement and somewhat lower in a hydrated slag (Cesareni
flocculation of the clay particles as ion exchange processes and Frigione, 1968; Taylor, 1997). A non-evaporable water
take place during and shortly after mixing. Mixing and content of approximately 0·20 for hydrated slag was used in
compaction were more easily performed than in the cement- the calculations. In the lime- and fly-ash-stabilised soils,
stabilised soils, which exhibited a stickier, less easily com- where pozzolanic reactions take place, the water bound by
pacted behaviour. No significant differences in density were the hydrated CaO can be calculated as approximately 0·30
measured for the different composite binders in the stabi- and 0·02 respectively of the dry binder weight. The water
lised clay or gyttja samples. contents estimated in this way agree fairly well with those
The densities achieved in the preparation of the samples measured in the stabilised soil samples 28 days after mixing
can be expected to affect the results of the strength tests. A (Fig. 2).
higher density will normally give a higher strength when As a rule, the strength of a soil stabilised with a specific
using a certain type of binder. However, if unevenly dis- binder increases with decreasing water content. However,
tributed, the air pockets will lead to non-representative low- there is no unique correlation between the water content
strength measurements and a larger scatter. and strength of stabilised soils, as this varies with the soil as
The water content decreases when dry binders are added well as with the type of binder used. Just as in natural soils,
to the soil. The water content after stabilisation depends on the behaviour of the stabilised soil is affected not only by its
the amount and type of binder used. The decrease in water water content but also by its liquidity or consistency index.
content is caused both by the larger quantity of solid The water content after stabilisation can be calculated from
particles introduced in the soil and by the amount of water the quantity of binder used, but the liquid limit and
bound by the hydration products as the binders react with plasticity limit will change to varying degrees depending on
water. The measured water content is to some extent also the effect of the binder. The plasticity limit normally in-
affected by the drying out/evaporation of water during creases after stabilisation. The liquid limit of Swedish soft
mixing. The larger part of the decrease in water content clays most often increases after stabilisation. In some high
occurs during the first week after stabilisation, but a plastic and organic soils, such as the gyttja and peat from
continued decrease is normally noticeable for up to at least the test site at Dömle in the EuroSoilStab project, the liquid
one month after mixing. The water content of the stabilised limit decreases after stabilisation. The measured changes in
soil could roughly be calculated as water content and consistency limits in the stabilised
  Linköping clay and Holma gyttja are shown in Fig. 3. The
wN
rsoil  ax measured changes in the Löftabro clay were principally the
wN þ 1 same as in the Linköping clay, but the scatter in measured
wstab ¼   (1)
1 wL and wP was considerably less.
rsoil þ (1 þ a)x
wN þ 1 As in natural soils, a decrease in water content from
around the liquid limit towards the plasticity limit is accom-
where rsoil is the bulk density of the unstabilised soil (t=m3 ); panied by an increase in strength. Different investigations

200
l – 100 kg/m3 1:1
c
cl
180 cs
cf
sl
160 l – 150 kg/m3
c
cl Holma gyttja
140 cs
cf
Measured water content: %

sl
1:1
120

100

80
Löftabro clay
60
Linköping clay
40

20

0
0 20 40 60 80 100 120 140 160 180 200
Estimated water content: %

Fig. 2. Estimated plotted against measured water contents 28 days after mixing. For abbreviations see Table 2, column 5
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H. Åhnberg et al.

250 Gyttia: Holma

wL

200
wP

w
150
w: %

Clay 1: Linköping
100
wL

w
50 wP

wP wL w
0
0 50 100 150 200 250 300 350 400
Time: days

Fig. 3. Range of measured w, wL and wP in Linköping clay and Holma gyttja before and after mixing with different binders

have shown the remoulded shear strength in natural clays to samples. The remoulded strength of stabilised soils is
be about 200 kPa at a water content equal to the plastic limit, normally not determined. The sensitivity of stabilised soil is
decreasing to about 2 kPa at the liquid limit (Wood, 1990). most often low, but these strengths would lie somewhat
By definition, the fall cone shear strength is 1·6 kPa when below the line of remoulded natural soils. However, the
the liquidity index (IL ) is 1 (Karlsson, 1981). Measured shear results show that the approach used in describing the
strength, evaluated from the unconfined compression tests consistency of natural soils can also in principle be applied
as quc =2, is shown as a function of IL of the three stabilised to unconsolidated stabilised soils.
soils in Fig. 4. For comparison, the approximate linear The relation between the consistency limits and the
relation for the remoulded strength of a soil, strength is to a large part governed by the relation between
cu ¼ 2 3 100(1 IL ) , suggested by Wood (1990) on the basis of w and wP . In Fig. 5, the measured shear strength is shown as
data collected by Mitchell (1976), is also shown in the a function of w=wP . There is a large scatter, especially at
diagram. The scatter in results is considerable, but the trend ratios lower than 1, but at water contents well above the
for the stabilised soils agrees quite well with that reported plastic limit the scatter is smaller. A similar increase in
for natural remoulded soils. The tests on stabilised soils strength with decreasing w=wP ratio was measured, regard-
were performed on unconsolidated but not remoulded less of the type of binder and the type of soil. Measurement

Plastic limit Liquid limit


1000

100

Natural remoulded clays


(Wood, 1990)
quc /2: kPa

10 l-100-Clay 1 14-100
llb-100 lsa95/5-100
c-100 c2l50/50-100
c2s50/50-100 skf-100
l-150 lg80/20-100
c3-100 cfg-100
c005-100
cl50/50-100
c2-100
c2kel-100
Remoulded clay 1,
cf50/50-100
cs50/50-100
cpf50/50-100
sl50/50-100
clay 2 and gyttja 1
sk2g-100 cg80/20-100
csg80/20-100
1 c-100-Clay 2 cf50/50-100
cs50/50-100 sl50/50-100
lsa98/2-100 lg80/20-100
l-100
c-100-Gyttja 1 c2-100
c3-100 ck50/50-100
cs50/50-100 sk50/50-100
cksi-100 cal95/5-100
cg80/20-100 sk2g-100
csa98/2-100 cf50/50-100
skf-100
0.1
⫺1.0 0.0 1.0 2.0
lL

Fig. 4. Strength plotted against liquidity index of the different stabilised soils and the corresponding remoulded soils. Approximate relation for natural
remoulded clays from Wood (1990). Abbreviations represent binder type: (see Table 2, columns 4 and 5; quantity kg=m3 )
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Stabilising effects of binders in Swedish soils

1000
l-100-Clay 1 14-100
llb-100 lsa95/5-100
900 c-100 c2l50/50-100
c2s50/50-100 slf33/33/33-100
l-150 lg80/20-100
c3-100 cfg40/40/20-100
800 lg80/20-100 cg80/20-150
c005-100 c2-100
cl50/50-100 c2lel33/33/33-100
cf50/50-100 cpf50/50-100
700 cs50/50-100 sl50/50-100
sl2g33/33/33-100 cg80/20-100
csg80/20-100
c-100-Clay 2 cf50/50-100
cs50/50-100 sl50/50-100
600 lsa98/2-100 lg80/20-100
l-100
quc : kPa

c2-100-Gyttja 1 c-100
c3-100 ck50/50-100
500 cs50/50-100 sk50/50-100
cksi45/45/10-100 cal95/5-100
cg80/20-100 sk2g33/33/33-100
csa98/2-100 cf50/50-100
400 skf33/33/33-100

300

200

100

0
0.8 1.0 1.2 1.4 1.6 1.8 2.0
w/wP

Fig. 5. Measured shear strength plotted against w=w P of the different types of stabilised soil. Abbreviations represent binder type: (see Table 2, columns 4
and 5; quantity kg=m3 )

of the plastic limit becomes more laborious and difficult to Results from unconfined compression tests on samples
perform when the strength increases. A relatively large with the six main binders or binder combinations of cement
scatter can therefore be expected when the plastic limit (c), cement–slag (cs), cement–fly ash (cf), cement–lime (cl),
becomes higher than the water content. slag–lime (sl) and lime (l) respectively are shown in Fig. 6.
Comparisons between different compositions of binders
within each category of main binder or binder combination
Unconfined compressive strength show that their effectiveness largely follows the same
The unconfined compression tests were performed in pattern in the different soils. However, there are a number
order to study differences in strength level and rate of of exceptions.
strength increase between different types of binder, rather The ‘new’ limestone cement, c, was somewhat more effec-
than to find the optimal binder composition for the three tive than the previous standard cement, c3, in the Linköping
soils. The optimal binder composition found for one soil clay but not in the gyttja. The limestone interground with
would not be directly applicable to another soil as it varies the cement clinker is softer and becomes finer after grinding
considerably with the soil type. than ordinary cement. The specific surface is also higher
As a certain scatter in results can be expected, the tests at than that of ordinary cement: see Table 3. This makes the
28 days and 91 days were duplicated. Triple tests or double cement more reactive, which can be expected to produce an
tests were in some cases performed at 364 days when earlier strength increase through accelerated hydration of
abnormal stress–deformation curves or otherwise unexpect- the alite and aluminate phases. As the limestone is finer, it
edly low strengths were registered. The calculated coefficient can to some extent also act as a filler between clinker grains.
of variation of the measured strengths of samples containing Apart from these effects, the limestone is also known to have
binder quantities corresponding to 100 and 150 kg=m3 was certain chemical effects on the hydration process. Different
6–9% and 3–9% respectively, with the lowest scatter for investigators have shown that monocarbonate is formed and
results from tests on gyttja 1 and the highest for tests on clay that there are indications that the persistence of ettringite on
1. About 5% of the measured values 28 days after mixing behalf of monosulphates is sustained (Klemm and Adams,
exceeded scatters of 14%, 11% and 7% of the mean 1990; Taylor, 1997). In the organic soil, on the other hand,
strengths of the stabilised clay 1, clay 2 and gyttja 1 the exchange of part of the ordinary cement (15%) was not
respectively. A large part of the most deviating results could compensated by these effects.
be discovered early in the unconfined tests, when a jagged The rapid cement, c2 , is a more finely ground cement with
stress–deformation curve was registered, indicating severe a specific surface larger than that of the limestone cement, c,
inhomogeneities caused by the air pockets in the samples. and can thus be expected to be more reactive. In construc-
Outliers of this type were not included in calculating the tion works, it is normally used where there are demands on
mean values presented in the different figures in the paper. faster hardening. In the marine Löftabro clay, clay 2, as well
as in the gyttja, the strength increase with this binder was
Main binders somewhat larger than with the limestone cement. However,
The binders can be expected to act somewhat differently the opposite effect was observed in the Linköping clay, clay
depending on the type of binder reactions that take place in 1. The rapid cement did not exhibit the same behaviour in
the soil. Processes such as ion exchange, cement reactions the stabilised soils as is normal for hydrated cements, where
and pozzolanic reactions proceed to varying extents and at there is a more rapid increase in strength during the initial
different rates depending on the type of binder used. These period after mixing.
processes are also affected by the chemical constituents of With time, the strengths normally converge towards the
the soil and by the temperature. same level. However, the differences in strengths in the
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H. Åhnberg et al.

2000
7 days Clay 1, 28–91 days 100 kg/m3
28 days
Clay 2, 28–91 days cl sl
91 days l
365 days Gyttja 1, 28–91 days
1500

c cs cf
quc /2: kPa

1000

500

0
cs 0

cl 0

sl 5
c

05

l
llb

l2

l4

4
0

cf 5
cp /50

cf 0
5

cl 5
c 50

c 25

sl 0
f3 /25

3
2

cs c3
c

/5

2
/7

llb
/5

/2

/5

/3
0/

5/
c0

0/

5/

/
50
50

25

50

75

50

75

50

75

33
2 l5

2 l7
f5

f7
2s

3/
cp
c

sl
Stabilising agent

Fig. 6. Measured mean unconfined compressive strength in clay 1, clay 2 and gyttja 1 stabilised with different binders. Abbreviations represent binder type:
see Table 2, columns 4 and 5

stabilised soils found after 28 days were the same or even increase from pozzolanic reactions when used in equal
larger after 3 months. This observation that a finer, normally proportions, but quite considerably when used in the
more reactive cement does not always exhibit a higher short- proportion 75 : 25. When replacing 50% of the cement by fly
term strength when used for stabilisation of soils also ash, a reduced amount of Ca(OH)2 is produced. After ion
applied to the ultra-fine cement, c0:005 . This cement did not exchange and absorption in the clay, this leaves only a
produce any better effect than the c2 cement in the clay, and limited amount for pozzolanic reactions with minerals in the
showed a considerably slower strength increase up to 28 fly ash competing with those of the clay particles.
days in the stabilised gyttja. The ultra-fine cement was In the combinations of cement–lime, the rapid cement, c2 l,
intended to act more effectively by mixing in a larger gave about the same or higher strength than the limestone
number of cement grains in the soil. However, this cement is cement, cl, when used in equal proportions to the lime. At
based on a somewhat less reactive type of clinker, and the the higher proportion of cement to lime of 75 : 25, c2 in
increased number of grains with a high specific surface did exchange for c had the opposite effect. A higher proportion
not compensate for the lower reactivity. of cement had no positive effect in the gyttja, but a clearly
In the various composite binders, the use of c2 instead of c positive effect in the Linköping clay. The relatively low
in cement–slag in equal proportions resulted in a lower strength obtained when using the higher proportion of lime
strength in the Linköping clay and about the same or a is not surprising in view of the very limited effect of pure
somewhat higher strength in the gyttja. Increased replace- lime in this clay: see the right-hand side of Fig. 6.
ment of cement by slag in the proportion 25 : 75 proved to The effect in Linköping clay was also somewhat different
give considerably lower strength, especially in the short from that in the other soils when using slag–lime, sl, as
term. This is in accordance with the normally slow hydra- binder. A higher ratio of slag to lime yielded significantly
tion properties of slag. In concrete, since hydrated slag higher strength 28 days after stabilisation in the Löftabro
cement is a denser product, which consists of a larger clay and the gyttja, but about the same strength after 91
amount of Si in relation to Ca compared with ordinary days. The opposite behaviour was observed in the Linköp-
cement, the hydration reactions are slower but may even- ing clay. The lime is obviously effective in both the Löftabro
tually lead to higher final strengths. clay and gyttja, and here it contributes considerably to the
The tests with different combinations of cement–fly ash as long-term strength increase. The replacement of part of the
binders showed that the combinations with PFBC ash, cpf, slag and lime by fly ash, slf, had a small positive effect on
were more effective than those containing ordinary coal fly the short-term strength in the gyttja, but the increase with
ash, cf. Increasing the proportion of cement to 75 : 25 instead time was more pronounced for the pure slag–lime mixtures.
of 50 : 50 yielded higher strengths and strength increases, The tests on samples with different types of pure lime as
which continued for a longer period of time. The same binders were performed only for the two clays, as pure lime
pattern could be observed for all three soils. Fly ash is a is not normally used in organic soils. The hard-burned lime,
pozzolanic material that together with water and CaO, from l, gave about the same or somewhat higher strength than the
cement for example, acts as a hydraulic cement. The soft-burned lime, llb . This was found for both the standard,
addition of fly ash to cement normally increases the work- finely ground lime and the coarser limes, l4 and llb4 . The
ability of concrete. A lower water=soil ratio can be used, result was somewhat unexpected as soft-burned lime, being
which means that strengths in the same order as with pure less dense and having a higher specific surface, is normally
cement are obtained. However, in stabilisation of soils, the classified as being more reactive than hard-burned lime. The
same water content is used. Apart from having a drying-out larger grains of up to 2 mm and 4 mm in the coarser limes,
effect, the fly ash contributed very little to the strength l2 and l4 respectively, could be clearly observed in the
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Stabilising effects of binders in Swedish soils

stabilised samples, indicating that they had not been broken the setting and the hardening of hydrated cement. On the
down in the mixing process to any larger extent. The other hand, the effect of the salt normally decreases with
coarseness of these binders had a positive effect on the time, and the final strength can in some cases be reduced
short-term strength of the stabilised compound. This indi- (Taylor, 1997). In the stabilised soils, it turned out that the
cated a benefit from a changed structure with coarser grains salt had a positive effect only in the Linköping clay and then
in the samples. As the short-term strength of lime-stabilised only in combination with cement or lime, but not together
clay is less dependent on the amount of binder used, the with cement–slag or cement–fly ash: see Fig. 7. In the latter
uneven distribution of lime did not reduce the strength to cases the strength was reduced instead. The effect of the salt
any large degree. However, the diffusion of CaO and the improved with time.
pozzolanic reactions with time became more effective for the The addition of alumina cement (al) to the standard cement
finely ground, more evenly distributed lime in the Löftabro had a certain positive effect on the strength of the two
clay. In the Linköping clay the lime reactions were generally stabilised clays. The alumina cement contains large amounts
retarded, and the strength of the samples stabilised with the of highly reactive CA (monocalcium aluminate). However, a
coarser lime was higher at all times. significant impact on the strength of the stabilised clays was
When comparing the different binder groups, it can be not observed before 91 days had passed. As the hydration
seen that the strength levels of the three soils are fairly products of alumina cements sometimes lose strength with
similar for the binders containing cement, fly ash and, to a time, depending on temperature and moisture conditions
certain extent, slag. For lime as a binder, alone or in (Robson, 1962), the long-term strength increase of this
combination with slag, the achieved strength varies consid- additive should normally also be checked.
erably between the different soils. Most noticeable is the Silica fume (si) showed both negative and positive effects,
poor effect of lime in Linköping clay. Lime is the one binder depending on the type of main binder. A mostly positive
that acts mainly by pozzolanic reactions with minerals in the effect was measured in cement–lime-stabilised clays and in
soil, or in other binders, to build up strength. One or more cement-stabilised gyttja. Silica fume is a pozzolanic material,
constituents in the Linköping clay obviously hinder or just like fly ash, consisting of very fine silica grains. It acts
severely retard these reactions. Also the other binders by being distributed in between larger cement grains, where
ideally generate pozzolanic reactions with the soil, but to a it can normally speed up the reactions and improve the
much lower extent. The different cement reactions are long-term strength by forming a denser product. The silica
instead to a large degree dependent on the composition of fume had a mostly negative effect when used together with
the pore water. cement–slag.
It should also be noted that the different binders often Water-glass (wa), or sodium silicate, has been considered
interact, yielding somewhat higher strengths with mixed for use as a peptising agent to improve the mixability of the
binders than the expected strengths from interpolating soil in situ and in this way increase the homogeneity and
between the corresponding measured strengths using the strength of stabilised soils. The water-glass should be mixed
separate binder ingredients respectively. with the soil before the binder is added. It is important that
Cement–fly ash in equal proportions gave a relatively this admixture in itself does not have a negative effect on
high strength after only one week, but subsequently showed the hydration processes. Sodium silicate is sometimes used
a slow increase with time. The strength increase is here in applications where a reduction in the bulk density is
largely governed by the relatively fast cement reactions, and desired, and may thereby have a certain negative effect on
the pozzolanic reactions can involve silicates and aluminates strength. Different investigations have shown that sodium
in fly ash itself instead of the less easily accessible compo- silicates can increase the strength and durability of sandy
nents in the soil. The increase in strength was in general and silty soils, but they only increase the short-term strength
relatively slow in the lime-, slag–lime- and cement–lime- of clays stabilised with cement, lime or lime-fly ash (Hurley
stabilised soils, but much faster in the cement- and cement– and Thornburn, 1972). The water-glass proved to have only
slag-stabilised soils. A relatively slow strength increase can a small, though mostly negative, effect on the cement–lime-
be expected with binder combinations using a large part of stabilised soils. Sodium silicate is often used in alkali-
lime, as the strength is then governed mainly by the activated slag cements to obtain rapid hardening and high
relatively slow pozzolanic reactions that take place in the strength properties in concrete. However, it proved to have
soil. The fastest strength increase and highest strength after a clearly negative impact on the cement–slag-stabilised soils.
28 and 91 days were obtained with the binder combination The gypsum (g) had the widest range of effects, varying
cement–slag. The measured one-year strength, however, from large decreases to large increases in strength, depend-
was only slightly higher and in several cases even lower ing on the soil and main binder. Very large strength
than the 91-day strength, and seemed more affected by increases compared with those for binders without admix-
scatter than the other types of stabilised sample. After one tures were measured in lime- and slag–lime-stabilised
year, regardless of the short-term strength, the strength level Linköping clay, but the effect of lime in this clay was
was about the same for the most effective binders in each extremely poor. The stabilising effect of gypsum mostly
group. The exception was slag–lime in equal proportions, decreased with time in the other two soils, and small to very
which had yielded still higher strengths. The one-year large negative effects were measured after 91 days. When
strength, however, is not to be regarded as a final strength. high contents of gypsum are added the gypsum dissolves,
A continued increase in strength at various rates, depending and after saturation of the pore water a precipitation of
on the binder used, can be expected. secondary gypsum can occur in the soil. Interlocking of
these gypsum crystals has a stabilising effect on the soil.
Admixtures Different investigations have also shown that the addition of
The admixtures CaCl2 (sa), water-glass (wa), gypsum (g) gypsum increases the rate of hydration of alite in cement
and kiln dust (k), as well as the supplementary cementing (Taylor, 1997). However, the addition of gypsum leads to
materials alumina cement (al) and silica fume (si), were the formation of ettringite and consequently a certain
tested to a varying extent together with the main binders. expansion of the stabilised materials. Delays in the formation
The admixture CaCl2 (sa) is well-known to accelerate both of ettringite may occur if the alumina available for early
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H. Åhnberg et al.

reactions is limited. If the formation of ettringite has been lime–cement in a lacustrine Linköping-type clay. However,
delayed, part of the formed cementing structure may be neither gypsum nor kiln dust would probably be considered
broken down. In order to maintain the high strengths, it is in the investigated types of soil, as the increased strength
further important that the formed ettringite remains stable levels with the admixtures are markedly lower than those
without large decreases in pH of the stabilised soil. obtained with the other main binders. In all three soils the
Although the kiln dust (k) from lime production has different admixtures tested had a significant negative impact
certain cementing properties, it was expected to serve on strength when mixed in together with cement–slag and
mainly as a filler that could be conveniently added to lime. cement–fly ash.
The results showed that at least about the same strength was In general, the stabilising effects of the different admix-
obtained when kiln dust was added to lime compared with tures increased with time except for gypsum, which showed
using lime alone. The kiln dust had almost no effect when a decreasing effect with time for most of the binders.
used together with lime–cement, except in the Linköping This was not in accordance with expectations based on
clay after 28 days or more. The good effect in lime is in experience of cement hydration. However, several of the
accordance with the observation that the effect of lime is accelerators yield an increased short-term strength by
usually rather insensitive to the range of quantities used. increasing the heat evolution at early stages and thus
Most often a larger quantity of lime is used than is needed accelerating the alite and aluminate hydration reactions. In
for starting the immediate reactions and the initial strength the laboratory, a large part of the generated heat vanishes
increase. However, an effect of the larger quantity can as a during the mixing procedure or relatively soon after the
rule be observed with time after mixing. samples have been put into the temperature-controlled
When considering the different admixtures intended for storage compartment (88C). This will not be the case in the
acceleration of the hydration reactions, the cost of the field, where the surrounding soil has an insulating effect
material and of handling and mixing the extra material and increased temperatures prevail for a long period of time
should be included. Taking into account also the scatter in (Åhnberg et al., 1989).
results, an improvement of about 20% could in most cases
be regarded as a minimum effect from a cost–benefit aspect. Order of strength
This limit is marked in Fig. 7. For the kiln dust, which is An attempt to place the main binders, without admix-
mainly a low-cost filler, an equal effect could be regarded as tures, in an approximate ranking order relating to strength
sufficiently good. Disregarding the results from pure lime or after 28 days is shown in Fig. 8. There is a large scatter in
slag–lime in the Linköping clay, as these two main binders the figure, depending on the difference in effects in the
yielded insufficient strength to be considered in this type of different types of soil, but it nevertheless provides a general
soil, this limits the number of admixtures of interest. None idea of the relative short-term stabilising effects of different
of the admixtures appeared to have a generally positive types of binder. The left side of the diagram, showing the
effect on the measured strength. Admixtures of possible highest measured strengths, is dominated by binder combi-
interest are CaCl2 together with cement in soils of the nations containing cement, and the right side is clearly
lacustrine Linköping clay type, or silica fume together with dominated by binders containing lime in different combina-
cement–lime in a marine Löftabro clay type. Gypsum might tions.
give an increase in short-term strength together with cement The relative stabilising effects vary with time, and the
or slag–lime in a Holma gyttja-type soil, or together with ranking order consequently also changes with time in favour
lime in a Löftabro-type clay. The kiln dust could be of binder combinations containing lime or pozzolanic mate-
economical to use together with lime in clay or together with rials. For comparisons of the relative stabilising effects at

4
c
cs
Clay 1 ⫺g
cf
cl
Clay 2
c2 l Gyttja 1
sl ⫺k
l
quc(binder ⫹ admixture)/quc(binder)

3
⫺sa (2%) ⫺sa (5%) ⫺al ⫺si ⫺wa

0
d
d
% 1d
a 5d
2% 7d

sa %- d
2% 91d

5 5d
5% 7d

sa %- d
5% 91d

5% d
5% -7d

d
d
10 5d

5 -7d

w 5% d
d
g -33 5d
g -33 -7d

20 % d

- d

% d
d

k % d
% 1d

d
10 -7
10 28
2 8

5 8

al 365

al -28

5% 1

8
5% -91

g -33 -28

3% 1

30 -7
k 365

30 -28

65
10 -9
w -36
sa %-
sa -2

sa -36
sa %-
sa -2

al %-9

si -36

w %-2

20 -36

-3 -9

30 -9
si %

w 5%

20 %

k 0%
si %-

-3
si %

20 %
-
2

3
sa

al

a
a
a

k
g

Admixture

Fig. 7. Measured effects of admixtures on strength of stabilised soils at different times after mixing. Total binder quantity corresponding to 100 kg=m3 . For
abbreviations see Table 2, columns 4 and 5. sa ¼ salt; al ¼ alumina cement; si ¼ silica fume; wa ¼ water-glass; g ¼ gypsum; k ¼ kiln dust.
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Stabilising effects of binders in Swedish soils

1000
100 kg/m3 28 days Clay 1
Clay 2

800 Gyttja 1

600
quc: kPa

400

200

0
0

25

c
0

25

50
25

l4

llb
0

25

50

50

3
2
c
/5
/5

/2

/5

/7

/5

/3
5/

0/
5/

c0

5/

5/

0/

0/
50
50

75

50

25

50

33
2 l7

2 l5
7

5
2s
cs

cl

sl

cl

cs

sl

3/
f

cf

cf
cp

cp
c

f3
c

sl
Stabilising agent

Fig. 8. Main binders arranged in approximate order of measured strengths after 28 days for the three soils. For abbreviations see Table 2, columns 4 and 5

different ages of the samples, the ranges of measured binder in Swedish organic soils within the EuroSoilStab
strengths at different times after mixing are shown in Fig. 9 project (Åhnberg et al., 2000). Fig. 10 shows the results from
with the binders arranged in the same order as in Fig. 8. The tests on stabilised Dömle peat and Dömle gyttja 28 days
binders yielding higher initial strengths show relatively after stabilisation with a binder quantity corresponding to
narrow ranges of measured strength at the different times 200 kg/m3 and the binders in the same order as in Figs 8
after mixing, whereas those with the lowest short-term and 9. A cement–lime combination of 80 : 20 in the EuroSoil-
strength in many cases show increased ranges with time, Stab project has here been approximated to the 75 : 25
depending on the type of soil. In the one-year tests, a combination in the present project. The effects of the binders
number of results show lower values than after 91 days, tested in the EuroSoilStab project generally coincide with the
indicating irregularities in the samples, which appear to pattern in the present project. However, the level of strength
become more important as strength and also brittleness obtained with a certain binder depends on the type of soil.
increase. To achieve about the same level of strength in the Dömle
The results in the present investigation can be compared organic soils as in the present soils, twice as large a quantity
with the results from tests performed with the same types of of binder was required. The maximum strength obtained

2000 Clay 1-7d


Clay 1-28d 100 kg/m3
Clay 1-91d
Clay 1-365d
Clay 2-7 days
Clay 2-28 days
Clay 2-91 days
1500 Clay 2-365 days
Gy-7 days
Gy-28 days
Gy-91 days
Gy-365 days
quc: kPa

1000
1 year

91 days

500
28 days

7 days

0
0

25

l4

l
llb
0

cf 5
5

05

50
cp /25
50

cl 5

cf 0

cs 0

sl 5
0

33
2
c
/5
/5

/2

/2

/5

/5

/7

/5
5/

5/

c0

0/
0/

/
50
50

75

75

75

50

50

25

50

33
2 l7

2 l5
f7

f5
2s
cs

cl

sl

3/
cp
c

f3
c

sl

Stabilising agent

Fig. 9. Approximate range of measured strength at different times after mixing with the main binders. For abbreviations see Table 2, columns 4 and 5
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H. Åhnberg et al.

1500
Present investigation 28 days
Dömle peat-200 kg/m3 - EuroSoilStab
Dömle peat-200 kg/m3 (series II)- EuroSoilStab
3
Dömle gyttja-200 kg/m - EuroSoilStab

1000

Clay 1, clay 2 and gyttja 1 - 100 kg/m2


quc: kPa

500

0
25
25
0

c
0

25

cl 5

sl 0
cp /25

cf 0

3/ 4

l
llb
50

cs 0

sl 5
0

3
2
c
/5
/5

/2

/5

l
/5

/7

/5

/3
5/
5/

5/

c0

0/
0/
50
50

75

75

50

50

25

50

33
2 /7
2 l7

2 l5
7

f5
2s
cs

cl
cf
c

c
c

f3
c

sl
Stabilising agent

Fig. 10. Effects of binders in the present project compared with results obtained in the EuroSoilStab project, 28 days after mixing. EuroSoilStab data from
Åhnberg et al. (2000). For abbreviations see Table 2, columns 4 and 5

after 28 days with a binder quantity of 100 kg=m3 was about stabilised clays, and somewhat larger in the stabilised gyttja,
300 kPa in the peat, but less than 25 kPa in the gyttja. 1·1–1·7%. The relatively distinct changes from large failure
strains to limited failure strains probably reflect a transition
Strength increase with time from contractive to dilatant behaviour as the strength of the
As can be seen in Fig. 9, the strength increase with time stabilised soils increases.
varies strongly with the type of binder. There are also large The presented strains refer to total measured strains. A
variations in the strength increase with time between differ- certain allowance for embedment errors was made by
ent soils: see Fig. 11. For the binders containing cement, substituting measured initial strains at increasing tangent
there is a marked increase in strength for the first 1–3 moduli with strains estimated by back-extrapolating a
months after mixing, after which the strength increase levels straight stress–strain relation from the point of maximum
out or continues at a slower rate. In the lime-stabilised soils, modulus. However, as no internal measurements of strains
there is a steadier, almost constant increase with time. were performed, the strains at failure are believed to be even
However, the time after which the effect of binders contain- smaller than those presented in Fig. 13. Nevertheless, the
ing lime surpasses those of the other binders varies consid- general pattern of decreasing failure strains with increasing
erably in the different soils. strength as well as the difference between organic soils and
A normalisation of the measured strength at different clays should be the same. Mean measured strains at failure
times after mixing to that measured after 28 days showed in the stabilised peat and gyttja from the Dömle test site in
that the ratio of 7-day strength to 28-day strength varied the EuroSoilStab project are included in the figure for
from 0·1 in the slag–lime-stabilised gyttja to almost 1 in the comparison. Both gyttjas showed somewhat larger strains at
lime-stabilised Linköping clay (Fig. 12). The corresponding failure at higher strength than the clays. The stabilised peat
ratios for 91 days and one year vary from 1·1 to 5·5 and 1·1 exhibited a more tenacious behaviour with greater strains at
to 12·3 respectively. The smallest variation is found for the failure than the other soils at all strength levels. This
cement- and cement–fly-ash-stabilised samples. In cement- behaviour is believed to be affected by a reinforcing effect of
stabilised samples, quc7d was 0:4–0:7 quc28d , quc91d was 1·2– the peat fibres.
1·4 quc28d , and quc364d was 1:4–1:9 quc28d . This is in the same
order as the correlations recommended by the Deep Mixing
Association of Japan in 1994 (Porhaba et al., 2000): that is, Comments on the choice of binders
qu7 ¼ 0:64–0:67 qu28 and qu91 ¼ 1:20–1:33 qu28 .
In choosing binders, there are technical as well as
economic aspects and, to an increasing degree, also environ-
Strains at failure mental aspects to consider, which will affect the final choice
The measured strains at failure varied with the type and of binder.
strength of the stabilised soil. A scatter in measured failure The effect of the different binders can vary considerably,
strains was observed, especially at lower strength levels, but depending on the type of soil. The measured strengths in
no significant variation with type of binder was seen. the present project can serve only as indications of strength
The strains at failure decreased rapidly with increasing levels that can be reached in relatively ‘binder-friendly’ soils
strength at unconfined compressive strengths lower than when using cement or composite cements with additions of
about 200 kPa: see Fig. 13. At higher strengths, the mean latent hydraulic cement or pozzolanic materials, such as slag
strains at failure were almost constant: 0·7–1·0% in the two or fly ash respectively. When using lime as a binder, alone
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Stabilising effects of binders in Swedish soils

2000 2000
l l
100 kg/m3 c 100 kg/m3
c
cs50/50 cl50/50
cf50/50 cf50/50 sl
cs50/50
cl50/50 sl50/50
1500 sl50/50 1500

cl
l
cs
quc: kPa

quc: kPa
c
1000 1000
cs

500 500
cl
cf cf

sl
l 0
0
0 50 100 150 200 250 300 350 400 0 50 100 150 200 250 300 350 400
Time: days Time: days
(a) (b)
2000
c 100 kg/m3
cs50/50
cf50/50
cl50/50 sl
1500 sl50/50
quc: kPa

1000 cl
c
cs

500
cf

0
0 50 100 150 200 250 300 350 400
Time: days
(c)

Fig. 11. Measured strength plotted against time for cement, lime and composite binders 50 : 50: (a) clay 1, Linköping; (b) clay 2, Löftabro; (c) gyttja 1,
Holma. For abbreviations see Table 2, columns 4 and 5

12.3 10.2
8
Clay 1

7 Clay 2
Gyttja 1 cl sl l
6
c cs cf
5
quc: kPa

0
d

1d
d

5d
1d
7d

5d

1d

d
d

5d

-7
-7

65

-7

-7

65

l-7

65
91

-9

6
-9

-9

l-9
c-

-9

6
36

sl
cs

cf

cl

-3
-3

-3

l-3
c-

-3

sl
cs

cf

cl
c-

sl
cs

cf

cl

Binder – Time: days

Fig. 12. Ratio of measured strength to 28-day strength 7, 91 and 364 days after mixing. For abbreviations see Table 2, column 5

or in combination with other binders, the strength is affected therefore as a rule not be used for estimates of possible
to an even higher degree by the properties of the soil, as the strengths in other types of soil.
binder to a large extent reacts with the soil itself. The results Many factors differ in effect between the field and the
from tests on these types of lime-based binder should laboratory. Factors such as mixing effort, temperature,
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H. Åhnberg et al.

15
Clay 1 – 100 kg/m3
Clay 1 – 150 kg/m3
Peat 1 (100–300 kg/m3) - EuroSoilStab Clay 2 – 100 kg/m3
Clay 2 – 150 kg/m3
Gyttja 1 – 100 kg/m3
Gyttja 1 – 150 kg/m3
Gyttja 1 (100–200 kg/m3) - EuroSoilStab
εfuc: % 10

0
0 500 1000 1500 2000
quc: kPa

Fig. 13. Measured strains at failure in the different stabilised soils. Comparative EuroSoilStab data from Åhnberg and Holm (1999)

confining stresses and pore pressures will all affect the ja and peat in the EuroSoilStab project have indicated
strength of the stabilised soil. The mixing procedure is of negligible impact on the environment (Håkansson et al.,
importance, especially when using cement-type binders, 2000). The local environmental impact of some of the binders
which act by forming reaction products locally at the site of used in the investigations, as well as the durability of the
the binder grains: therefore these should be spread out as stabilised soils, are important aspects being studied in other
evenly as possible in the soil. A thorough mixing of lime- projects within the Swedish Deep Stabilisation Research
type binders is also important, but here the distribution is Centre programme, and will be reported on at a later date.
further improved by diffusion processes in the soil. Further- The presented results could be used as a guide for binders
more, the binder reactions will lead to increased tempera- of interest for use in similar types of soil. The choice of
tures in the field, which may prevail for a long time binder should normally be based on tests in the laboratory
(Åhnberg et al., 1989). As the heat evolution from the with more than one type of binder combination. As the
hydration processes varies depending on the binder type, conditions in the field differ from those in the laboratory,
the strength increase for binders containing quicklime, or the final choice of binder quantity, and sometimes also the
accelerators generating an increased heat evolution, will be type of binder to use in a project, should as a rule be based
considerably faster at field temperature than under labora- on full-scale column tests.
tory conditions. The difference will be smaller for the
binders generating less heat.
Depending on the application, the optimal binder combi-
nation is not necessarily the combination yielding the high-
Conclusions
est possible strength in the shortest possible time. The fact A large number of binders and binder combinations were
that more moderate strength levels often permit a higher used in the laboratory to perform stabilisation tests on three
degree of interaction with the surrounding soil is an soils. All three of these very soft soils were stabilised with
important aspect to be considered, as well as the possible good results using many of the binders. Varying effects were
benefits of a long-term strength increase. measured, indicating that the binders were of different
In choosing binders, the binder cost is one decisive factor. effectiveness for stabilisation purposes. The results illustrate
However, since the cost for transportation may constitute a several differences and similarities in the way binders affect
large part of this, relatively large differences in the costs for strength in stabilised soils.
binders themselves are often evened out, depending on the
location of the soil improvement object relative to the binder (a) When stabilising soils with chemical binders, the water
plant. content and the different consistency limits will change
Depending on the composition of different industrial by- to different extents, depending on the type and amount
products, reuse of these could sometimes have a more of binder used and the type of soft soil. The principal
negative impact on the environment than ‘traditional’ ways in which these factors change proved to be quite
binders. However, the use in soil stabilisation of some of the similar, regardless of the type of binder used.
binders of the former type, even though having a certain (b) A large number of binders can be used for stabilisation
impact locally, could be environmentally more beneficial in of soils. The optimum binder combination varies with
a total perspective compared with various alternative treat- the type of soil. Binders containing lime, which to a
ments such as disposal in waste landfills. Leaching tests high degree acts through pozzolanic reactions with the
conducted on cement–lime- and cement–slag-stabilised gytt- constituents of the soil particles, are more sensitive to
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Stabilising effects of binders in Swedish soils

the type of soil than binders reacting primarily with the A˚ hnberg H., Bengtsson P.-E. and Holm G. (2000) Task 2·2 and 7.
pore water in the soil. Common binders of the latter Laboratory Tests of Mixtures: Test Sites Dömle Mosse and Holma
type are those containing cement, either alone or Mosse, Sweden. National report, part 1. Internal Report. Euro-
SoilStab project, SGI 3-9705-239 and 3-9708-395.
together with mineral additions of slag or fly ash.
ASTM (1994) Standard Specification for Coal Fly Ash and Raw or
(c) Relatively high short-term strengths are mainly obtained Calcined Natural Pozzolan for Use as a Mineral Admixture in
with binders containing a certain amount of cement. Portland Cement Concrete. American Society for Testing and
(d ) High strengths can often also be obtained with binders Materials, Philadelphia, ASTM standard C618-94a.
giving relatively low short-term strengths. A steady Carlsten P. and Ekström J. (1995) Lime and Lime Cement Columns:
long-term strength increase caused mainly by pozzola- Guide for Project Planning, Construction and Inspection. Swedish
nic reactions can then be observed, especially for Geotechnical Society, Linköping, Report 4:95E.
CEN (1998) Building Lime—Part I: Definitions, Specifications and
binders containing pure lime and slag–lime, and also Conformity Criteria. CEN standard pr-EN459-1: 1998, Brussels.
cement–lime. CEN (2000) Cement—Part 1: Composition, Specifications and Conformity
(e) Very large differences in effect were measured between Criteria for Common Cements CEN standard pr-EN197-1: 2000,
the two clays used in the investigations. Further studies Brussels.
of soil parameters and chemical reactions are necessary Cesareni C. and Frigione G. (1968) A contribution to the study of
in order to improve the means of evaluating the the physical properties of hardened pastes of Portland cements
containing granulated blast-furnace slag. Proceedings of the 5th
chemical reactivity of different types of soil. International Symposium on the Chemistry of Cement, Tokyo
(f) None of the different admixtures used proved to have a 1968, 4, pp. 237–247.
generally positive effect on the strength of stabilised Cortellazzo G. and Cola S. (1999) Geotechnical characteristics of
soils. Varying positive or negative effects were obtained two Italian peats stabilised with binders. Proceedings of the
depending on the type of soil and type of main binder International Conference on Dry Mix Methods for Deep Soil
used. Stabilisation, Stockholm 93–100.
den Haan E. (1998) Cement based stabilisers for Dutch organic
(g) The strains at failure decrease with increasing strength
soils. In Problematic Soils, Sendai. Balkema, Rotterdam, pp. 53–
of the stabilised soils. The strength dependence varied 56.
somewhat with the type of soil but not significantly Håkansson K., Johansson S.-E., Bengtsson P.-E., Holm G. and
with the type of binder. A˚ hnberg H. (2000) Task 2·2 and 7. Results of Chemical Analysis of
(h) The results can be used for guidance in choosing the Soils and Stabilised Soils: Test Sites Dömle Mosse and Holma Mosse,
type of binder for stabilisation of a soil. Their display of Sweden. National Report, part 2. Internal Report. EuroSoilStab
project, SGI 3-9705-239 and 3-9708-395.
ranges of stabilising effects can be considered as more
Hebib S. and Farrell E. (1999) Some experience of stabilising Irish
important than the measured absolute strength levels. organic soils. Proceedings of the International Conference on Dry
It should be observed that the strength achieved by a Mix Methods for Deep Soil Stabilisation, Stockhom, 81–84.
certain binder will vary with the type of soil, and will Holm G. and A ˚ hnberg, H. (1987) Use of Lime-Fly Ash for Deep
also depend on how the soil–binder complex is Stabilisation of Soil. Swedish Geotechnical Institute, Linköping,
handled: that is mixed, compressed, heated and Report No. 30 (in Swedish).
drained/saturated. Hurley C. and Thornburn T. (1972) Sodium silicate stabilisation
of soils: a review of the literature. Highway Research Record,
No. 381, pp. 46–79.
Jelisic N. and Leppänen M. (1999) Mass stabilisation of peat in road
Acknowledgements and railway construction. Proceedings of the International Con-
ference on Dry Mix Methods for Deep Soil Stabilisation, Stockholm,
Financial support for the project has been provided by the 59–64.
Swedish Deep Stabilisation Research Centre (SD). The Karlsson R. (1981) Consistency Limits: Performance and Interpretation
of Laboratory Investigations, Part 6. Byggforskningsrådet, Stock-
financial contributions of the participants Cementa AB,
holm, D9: 1981.
Partek Nordkalk AB, Merox AB, the Swedish Geotechnical Klemm W. and Adams L. (1990) An Investigation of the Formation of
Institute and SD are gratefully acknowledged. Permission Carboaluminates: Carbonate Additions to Cement. American Society
from the participants within the European Community for Testing and Materials, Philadelphia, STP 1064, pp. 60–72.
project EuroSoilStab under contract Brite EuRam BRPR- Lahtinen P., Jyrävä H. and Kuusipuro K. (1999) Development of
CT97–0351 to present data from this project is also much binders for organic soils. Proceedings of the International Con-
appreciated. ference on Dry Mix Methods for Deep Soil Stabilisation, Stockholm,
109–114.
Mitchell J. K. (1976) Fundamentals of Soil Behavior. New York,
Wiley.
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deep mixing technology. Part III: Geomaterial characterization.
˚ hnberg H. and Holm G. (1999) Stabilisation of some Swedish
A Ground Improvement, 4, No. 3, 91–110.
organic soils with different types of binder. Proceedings of the Robson T. D. (1962) High-Alumina Cements and Concretes. Contractors
International Conference on Dry Mix Methods for Deep Soil Record Ltd, London.
Stabilisation, Stockholm 101–108. Taylor H. F. W. (1997) Cement Chemistry. Thomas Telford, London.
˚ hnberg H. and Pihl H. (1998) Effect of different quicklimes on
A Wood D. M. (1990) Soil Behaviour and Critical-State Soil Mechanics.
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Conference on Ground Improvement Techniques, Singapore 47–54.
˚ hnberg H., Bengtsson P.-E. and Holm G. (1989) Prediction of
A
strength of lime columns. Proceedings of the 12th International
Conference on Soil Mechanics and Foundation Engineering, Rio de Discussion contributions on this paper should reach the
Janeiro, 2, 1327–1330. editor by 1 July 2003

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