Professional Documents
Culture Documents
System of Classifying
Chemicals
Rosalee B. Fajilan
Senior Industrial Hygienist,
Occupational Safety and Health Center
Introduction
The production and use of chemicals
is fundamental in the economic
development of all countries and, at
the same time, it may pose a risk to
the health and well-being of all
people and the environment if not
managed in a responsible manner.
History of GHS
• In 1989-90, ILO developed and
adopted a convention and
recommendation on Safe Use of
Chemicals at Work.
• These instruments require
countries to adopt a system for
hazard classification and labeling.
History (cont.)
• In 1992, United Nations Conference on
the Environment and Development
(UNCED) took place in Brazil, often called
the “Earth Summit”
Hazard Class
Hazard Category
Acute Toxicity 1 2 3 4 5
1A 1B 1C 2 3
Skin Corrosion/Irritation
1 2A 2B
Serious Eye Damage/Eye Irritation
1 1A 1B
Respiratory or Skin Sensitisation
1A 1B 2
Germ Cell Mutagenicity
1A 1B 2
Carcinogenicity
1A 1B 2 Lactation
Reproductive Toxicity - Fertility
1 2 3
Specific Target Organ Toxicity - Single Exposure
1 2
Specific Target Organ Toxicity - Repeated Exposure
1 2
Aspiration hazard
Environmental Hazards
• Labels
Specific Hazard
(White)
National Fire Oxidizer ---- OXY
Acid ---- ACID
Protection Alkalai ---- ALK
Corrosive ---- COR
Agency (NFPA) Radiation Hazard ----
Use No Water ----
Polymerizes --- P
No special hazard ----
Labels Currently In Use
Flammable &
Compressed Gas Oxidizing Material 1. Materials Causing
Combustible Material
Immediate & Serious Toxic
Effects
Class D Class D Class E Class F
China
U.S.A.
Flammability
Symbols Malaysia
South Africa Australia
SYMBOLS
MALAYSIA
US CANADA EU
and
WORKPLACE CONSUMER CONSUMER
HONG KONG
WORKPLACE
THAILAND
EU TAIWAN
WORKPLACE
CHINA
CANADA
WORKPLACE
INTERNATIONAL TRANSPORT
Standardized Label Elements
• Harmonised label elements:
–Symbol/pictogram
–Signal word
–Hazard statement(s)
• Other core information to be provided
–Product identifier
–Supplier identification
–Precautionary statement(s)
Allocation of label elements
Product Identifier
Identity of Hazardous Ingredients
Background: white
Symbol: black
39
GHS Pictograms and Hazard Classes
Flame Flame over Exploding Bomb
Flammables Circle Explosives Corrosion Gas Cylinder
Self Reactives Oxidizers Self Reactives * Gases under Pressure
Pyrophorics Organic Peroxides Organic Peroxides
Self Heating
Danger Warning
Hazard statements
• Describe the hazards covered by the GHS
• Indicate the degree of severity of the hazard
• Text of the statements has been harmonised
• Harmonised statements are assigned to each hazard
class and category, and have been codified (a
numbering system has been applied to them for ease
of reference)
• Example: H318 Causes serious eye damage.
Other required information
• Precautionary statements are required. The GHS
includes possible statements, but they have not yet
been harmonised
• There are 5 types of statements: General,
Prevention, Response, Storage, and Disposal
• These have been assigned to hazard classes and
categories, and codified (numbered).
• Example: P280 Wear eye protection/face
protection.
Precautionary pictograms
• Some systems may choose to illustrate
precautionary information using pictograms.
These are not harmonised in the GHS.
Product and supplier identification
• Chemical identity required for substances
• For mixtures either:
–All the ingredients contributing to the
hazard of the mixture/alloy, or
–All the ingredients contributing to any health
hazards presented by the product other than
irritation and aspiration
• Supplier identification required on all labels,
including name, address, and phone number
Other label provisions
•Supplementary information may also
be required or permitted by
competent authorities to provide
other items such as directions for use
•Competent authorities should also
specify how often labels are to be
updated
GHS Label
ToxiFlam (Contains: XYZ)
Danger
Toxic if Swallowed, Flammable Liquid and Vapor
Do not eat, drink or use tobacco when using this product. Wash hands thoroughly after handling. Keep
container tightly closed. Keep away from heat/sparks/open flame. – No smoking. Wear protective
gloves and eye/face protection. Ground container and receiving equipment. Use explosion-proof
electrical equipment. Take precautionary measures against static discharge. Use only non-sparking
tools. Store in cool/well-ventilated place.
In case of fire, use water fog, dry chemical, CO2, or “alcohol” foam.
See Material Safety Data Sheet for further details regarding safe use of this product
Danger
Toxic if Swallowed
Highly Flammable Liquid and Vapour
(ECHA Guidance
on Labelling… ,2011)
GHS Hazard
Communication – Safety
Data Sheets (SDS)
What is CSDS/MSDS?
Chemical Safety Data Sheet/
Material Safety Data Sheet
Purple Book:
provides explanatory
information on how to
apply the system
• United Nations (UN) publication of the GHS
• Outlines the provisions in four parts:
–Introduction (scope, definitions, hazard
communication)
–Classification criteria for physical hazards
–Classification criteria for health hazards
–Classification of environmental hazards
Annexes
1 Allocation of label elements
2 Classification and labelling summary tables
3 Codification of hazard statements, codification and
use of precautionary staement, and examples of
precautionary pictograms
4 Guidance on the preparation of Safety Data Sheets
(SDS)
5 Consumer product labelling based on the likelihood
of injury
Annexes (cont.)
6 Comprehensibility testing methodology
7 Examples of arrangements of the GHS label
elements
8 An example of classification in the Globally
Harmonized System
9 Guidance on hazards to the aquatic environment
10 Guidance on transformation/dissolution of metals
and metal compounds in aqueous media
Purple Book
National GHS
Implementation Strategy
National Implementation Structure
Governing Body:
The National GHS Implementation Committee
with representatives from:
Government
(30 Agencies)
Civil Society
Industry
(5 Public Interest
(6 Associations)
& Labor Org.)
• DOTC
• OSHC
B. Comprehensibility Testing • University of the
Philippines – National
Engineering Center
(UP-NEC)
Components of the UNITAR GHS Phase I
Project (conducted from 2006 to 2008)
Phase Activity/Sector Responsible Entity
2 A. National GHS Workshop • BOI
B. Industry and Civil Society-
Directed Activities
1. Industry • SPIK
2. Civil Society
a. Agriculture • PAN, Phils.
b. Consumer Products • NACI
c. Transport • TUCP
d. Industrial Workplace • TUCP
C. Preparation of Draft • GHS Subcommittee and TWG
Legislation on Legislation co-chaired by
the BOI and the EMB
June 2002
Accomplishments and Milestones
The eight (8) agencies which signed the GHS JAO are the
following:
- DTI (thru BOI, BPS and PEZA)
- DENR (thru EMB)
- DA (thru FPA)
- DOLE (thru OSHC and BWC)
- DOTC (thru Its Main Office, Maritime Industry and
Authority & Philippine Ports Authority, etc.)
- DOH (thru Food and Drugs Administration),
- DILG (thru Bureau of Fire Protection),
- DOF (thru Bureau Of Customs)
June 2002
GHS MAJOR MILESTONE IN 2010
• DA - FPA
June 2002
Status of GHS Implementation by Concerned Agencies
• DENR - EMB
– EMB has been continuing the promotion of GHS Basic
Principles and awareness raising and capacity building
through seminars and lectures.
June 2002
Status of GHS Implementation by Concerned Agencies
• DENR – EMB
A Plenary Session on the Draft DENR DAO and the Guidance
Documents was held on 02 August 2012:
The following transition periods were also suggested:
A. Three (3) years transition period for the implementation of:
• CCO Chemicals
• PCL Chemicals
B. Two years after the aforesaid transition period, this Order shall take
effect on the following :
• High Volume Toxic Chemicals
C. A year after the two periods, the Order shall take effect on:
• Toxic Chemicals under the International Air Transport Assn.
(IATA) and International Maritime Dangerous Goods (IMDG) lists.
June 2002
Status of GHS Implementation by Concerned Agencies
• DOF - BOC
– As soon as the BOC was provided a copy of the published GHS
JAO, a Customs Memorandum Circular (CMC) was issued by
the BOC to implement the provisions of GHS, with effectivity on
15 July 2009. However, since the implementing agencies have
yet to issue their respective IRRs requiring the adoption of GHS,
the BOC cannot yet implement its function with respect to the
GHS, i.e., in monitoring the import and export of all kinds of
chemical substances, mixtures and products in accordance with
the GHS.
• DOH - FDA
– FDA, together with the DOH main office, has started working on
the preparation of the IRR for consumer chemicals.
June 2002
Status of GHS Implementation by Concerned Agencies
– BWC has already prepared a draft of the IRR for GHS implementation
in the workplace.
• DILG – BFP
June 2002
Status of GHS Implementation by Concerned Agencies
June 2002
Awareness Raising & Capacity Building Activities
Seminars/Workshops Conducted by JETRO/AOTS
Type/Title Year No. of No. of
Seminars Participants
Conducted
Basic Training/ Seminar on 2004 to 2005 (Manila, 3 162
GHS Phils.) 1
2009 (Tokyo, Japan) –
under the AOTS –
VINACHEM Training
Basic Workshop on GHS 2004 to 2005 (Manila, 4 162
Phils.)
Intermediate Workshop on 2004 to 2005 (Manila, 3 41
GHS Phils.)
Advanced 2005 (Manila, Phils.) 2 18
Seminar/Workshop 2007 (Tokyo, Japan) 1 2
Instructors Training Course 2006 (Tokyo, Japan) 2 8
(in Tokyo, Japan) 2007 (Tokyo, Japan) 1 2
2008 (Tokyo, Japan) 1 4
GHS Practitioners Course 2008 (Tokyo, Japan) 1 4
2009 (Tokyo, Japan) 1 2
GHS Practical Skills Course 2008 (Tokyo, Japan) 1 5
2010 (Tokyo, Japan) 1 3
2011 (Tokyo, Japan) 1 4
Brochure Prepared by SPIK
June 2002
Brochure Prepared by SPIK
June 2002
GHS Poster in Pilipino
June 2002
Thank You for
your attention