CONCEPT MAP Structure and Nomenclature Aldehydes ° + nL whe RH alloraylerap, 1 InIUPACstem,aldebyéesarenamed as aanals toes i 1) + 2- Eo where Rand both canbe seo eet ope | cIRtUPAC system, they ae named a alhanones "ALDEHYDES : AND i Physical Pr + Soba water 4 + canounds bong wt or en Hors a ‘cel dulyepnbondng 1) pata it enon up ae ehraat oc endoctnecear ches seca cacsnee weg inedey «Dero deen dnting sy op toes Riches dca as Distinction Tests ALDEHYDES, KETONES AND CARBOXYLIC ACIDS Preparation + Ovation of aes RCH,OH + [0] SAEOMESOUE poss 5 150, AGGIE + (ELAN, poops 3,0 + Catalytic decomposition ofcarbosylc acids ROOK + HoOcH EAS ReHO + cO;+ 0 coor toocR 2% gcox coy 0 « Hydraborationexidation of llynes Re seta Pre Se Saga [Td RogaG ate RctG HE Being important constituents of fabrics favouring’, pasties and drugs, carbonyl compounds are of lutmost importance to organic chemistry while ‘atboxylic aids are amongst the eatest organic ‘compounds tobe soloed rom nature and are sti knownby theircommonnames. + Oxomolysisefathenes: nc=o=n" => acto + Bono & + From gem-dialides Ty a8 08 qe Tram Eee 4 Aled wen (ren en = you ‘Chemical Properties i Hoon 3 + Nucleophilicadition reactions: SD rvordttn ye” we i ft 5/08 FQ ve Aldehydes Ketones (trieand electron reasons) HCHO» RCHO > PRCHO> RCOR> RCOP > PROP + Nucleophilcaditon-elimination reactions pea i = ‘ukayder [Rane a eg ako clu lng on eee Nope oe rere Soda ioc Breve inom] Nereis fcttcio) ac roiam [ A dep dos [id aon wh tepreaide” |(acep HCHO) |ehangestoornge ! Structure and Nomenclature i] catgre acide I 2 5 1) nH Lon wher A thaligorary group i | + taturacsyem heyatenumed atanccaci Physical Properties [+ Sotbityinwatee pa + Highbpt duetointertolecularhydrogen bonding. I+ septs and pts of aromatic cis are usualy higher than thove of aliphaicaid. MRE, So EN— 2410 + Reductionand oxidation re10 SESE ronan Joeman acon > genorn oe enx Pst ee ae tn + Maform acon Gen by componnde hang CHCO—rop or SHACHHOE pomp Reociiy > ro0NS + it + Alda condensation ony slNly cu, tad ow (aldeyee oc ktsne Sw wytoge) + Cannizaro reaction rico + cio 285 e4, 071» Heo ied one snag eacinge Preparation + Oxidation alah sctigo1 HMDS oo 915 ncooH + yds of nites and amides ew 28,0! 5ncoott Nt, oon, BP sne00t From Grignard reagent. enya BEE coos sett Chemical Rea + Reactions involving cleavage of -OF grovp + Hydrolysis of eters coo’ + H,0-#* HS acoon + KOM + Carbonylaion (Koch eatin) af alkenes eaty= cit, +60 + 14,0 78K, cr cr,cooHt + From methyl Ketones ° i net — Lhet, +3ns01- Bb cxxcxi,coo ++ Ct + 28011 + Ringsubstitution naromaticacds na “Gocttpeepucectatganénes drcig go jt por qoou | om Chemical Properties ct oul] rower aco em + Aci order: Caton ndoPhenoe Ache ne “ cates o. RDG decease the acidity and EWG increases the acy. aoe? 1 hore he econ of te nom ached |_| * Recto mahing proton of OF gop. + Reactions ining COOH 0: Uetabagipreup meretalbetescdiy ec oY wanmtcno 7 Ht COON HO Jeon scorn AY NO Distinction Tests. [R-¢—o3n[} _, sRcOONa + CO, + HO a in - = «Reins inalvng —Rroup * oer ids" [Phenols [Alcohol RCOONa + CO, +H1,0 o x! [anicorceererenc No [No | _s neainsiting3O=0 gs Ta) thts nex —coost JofC0, gar | reaction _fresetion mere 0 gr Gai} Eon] azo *-F ec, Bat clare pc Wa Hao Tou | tute wee alate oredccloufeecicn] [xed -on F Beamesbewtse 5 ner. on stint an