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aaa YY c= Gera fora: Hoy HO UAC ame: Alkane Co Nite) a Ua Na) 3 ALDEHYDES, KETONES AND ‘Nuclopcaddton ection 9 I po aldehydes and ets are higher han hyocnons and thers a omporable rleclarmaendactoweadpsiedipainerachems > B pt ofaldehydesand ketone re wer han lool of ir maeclar mars due 10 sheer fimrmaeclarhyanogen ending 0 8. pt of Ketones ae lh higher har dehy es dae othe presence of two all groups wich naecarony group mere paar poner Aco >Renes Abit der es iacarbore 2 Soli = Moecusr mass 2 SolubltyinvaterisduetoF-bondingbeeen polacuibonylsroupand water, © Aromat alley ae Keon area soluble thn oreponting alpha aldehyde an tkeones de tolage hydration painbwozen ing 2 React onder: ‘Aldeyden> Ketones (eric and lecronic non) PP Nucleophilcaddition-elimination reactions PBS» scanstain0 N-Z4H0 [2 Alby Ary OH, =NHs—NHCQH, i ee aie == a sete ee Fehling’s solution | Red ppt. No ppt ae sar : “Tallens! reagent Silver mistor Noi 2 RCH EES crs, Sor Bene | Bes sour a Tae | —— No eco eee | oases does not give this te=t) ne ie ‘Alkaline sodium | Adsep red colour (formaldehyde does | Red colour which changes 2 RCHO PES ROCIO ven with aM ong agent) 2 RCOR’ PSH COOH (With tong osc as) Cor py alana COOH Sieh ee TNAHCO, | Brsketlervesceneeof | Noreacton a pond ee te | ime pete ee ete Ey Caste be enectoeepetne tare eptonto 2 Hyon qroupofacieismoreaidic than the hydroxy group fakechasand penal > Acidtyorder: Carbonless» Phenals> Alcoa > EDG eceasestheacityand WG increas the ack Mot isthe distance beten the coon group and elaczon withdewing gro, leer swe esc trength > Move ste decroneaty ofthe ata atache tothe cxboxl group, more wil be sei, Reactonsnsiving deavage of -O1 group ‘undergn a encionn the presence ise aalascaalyt ie ee eS eer (et nspecvey. 2 Thealoland kta edly oswaterto giveo, Burcaturted cottony compounds CCannasanrsctone De cc ae eee teeter apeoporortin heating with enceate lk > 0B potcabowiicacid are higherthan adhd ketones and alas of comparable molecular masses due to Intermolecular ¥nding ponder: Carmien» Alohole>Alehyes> Ketores> Hydrombone 2 Invapourphons orinaprtcsonents thy estas diner © Solubility sn yaterisdueto H-bonding. RHE > aco. ing! eotettaton in rowan Sa a = Ls Son = Pt [20H > RCOONa +10 oy i a0, ome RC= ci} > apcoons 10, 1,0 oy ie LMHEO S RCOONa+ CO, “1,0 coer = 7 a retpon austerity || StaerOl, Reston involving “COOH group Metts as xeo, 7 xia iB, |S?» e-ct—coon ncrise¢—onf— aga > BGC (er bad Zin rte

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