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Chemical Sample Book PDF For Gate Exam PDF
Chemical Sample Book PDF For Gate Exam PDF
CHEMICAL
ENGINEERING
GATE SOLUTION
ALL RIGHTS RESERVED. No part of this work covered by the copyright herein may be
reproduced, transmitted, stored or used in any form or by any means graphic, electronic, or
mechanical & chemical, including but not limited to photocopying, recording, scanning,
digitizing, taping, Web distribution, information networks, or information storage and
retrieval systems.
Tel: 011-26514888
ISBN: 978-93-5137-754-2
R.K. Rajesh
Director
eii.rkrajesh@gmail.com
Linear Algebra: Matrix algebra, Systems of linear equations, Eigen values and eigenvectors.
Calculus: Functions of single variable, Limit, continuity and differentiability, Mean value theorems,
Evaluation of definite and improper integrals, Partial derivatives, Total derivative, Maxima and
minima, Gradient, Divergence and Curl, Vector identities, Directional derivatives, Line, Surface and
Volume integrals, Stokes, Gauss and Green’s theorems.
Differential equations: First order equations (linear and nonlinear), Higher order linear differential
equations with constant coefficients, Cauchy’s and Euler’s equations, Initial and boundary value
problems, Laplace transforms, Solutions of one dimensional heat and wave equations and Laplace
equation.
Complex variables: Analytic functions, Cauchy’s integral theorem, Taylor and Laurent series,
Residue theorem.
Probability and Statistics: Definitions of probability and sampling theorems, Conditional probability,
Mean, median, mode and standard deviation, Random variables, Poisson, Normal and Binomial
distributions.
Numerical Methods: Numerical solutions of linear and non-linear algebraic equations Integration by
trapezoidal and Simpson’s rule, single and multi-step methods for differential equations.
CHEMICAL ENGINEERING
Process Calculations and Thermodynamics: Laws of conservation of mass and energy; use of
tie components; recycle, bypass and purge calculations; degree of freedom analysis. First and
Second laws of thermodynamics. First law application to close and open systems. Second law
and Entropy. Thermodynamic properties of pure substances: equation of state and departure
function, properties of mixtures: partial molar properties, fugacity, excess properties and activity
coefficients; phase equilibria: predicting VLE of systems; chemical reaction equilibria.
Fluid Mechanics and Mechanical Operations: Fluid statics, Newtonian and non-Newtonian
fluids, Bernoulli equation, Macroscopic friction factors, energy balance, dimensional analysis,
shell balances, flow through pipeline systems, flow meters, pumps and compressors, packed and
fluidized beds, elementary boundary layer theory, size reduction and size separation; free and
hindered settling; centrifuge and cyclones; thickening and classification, filtration, mixing and
agitation; conveying of solids.
Heat Transfer: Conduction, convection and radiation, heat transfer coefficients, steady and
unsteady heat conduction, boiling, condensation and evaporation; types of heat exchangers and
evaporators and their design.
Mass Transfer: Fick’s laws, molecular diffusion in fluids, mass transfer coefficients, film,
penetration and surface renewal theories; momentum, heat and mass transfer analogies;
stagewise and continuous contacting and stage efficiencies; HTU & NTU concepts design and
operation of equipment for distillation, absorption, leaching, liquid-liquid extraction, drying,
humidification, dehumidification and adsorption.
Chemical Technology: Inorganic chemical industries; sulfuric acid, NaOH, fertilizers (Ammonia,
Urea, SSP and TSP); natural products industries (Pulp and Paper, Sugar, Oil, and Fats); petroleum
refining and petrochemicals; polymerization industries; polyethylene, polypropylene, PVC and
polyester synthetic fibers.
MARKING SCHEME
Engineering Mathematics : 15 Marks
General Aptitude Section : 15 Marks
Technical Section : 70 Marks
Total Marks : 100 Total Question : 65 Duration : 3:00 Hour
CONTENTS
GATE Solution
1. Process Calculations …………………………… 1-19
1. PROCESS CALCULATIONS
(GATE Previous Papers)
GATE-2013
Common Data for Questions 1 and 2:
A reverse osmosis unit treats feed water (F) containing fluoride and its output consists of a permeate
stream (P) and a reject stream (R). Let CF, CP, and CR denote the fluoride concentrations in the feed,
permeate, and reject streams, respectively. Under steady state conditions, the volumetric flow rate of
the reject is 60 % of the volumetric
olumetric flow rate of the inlet stream, and CF = 2 mg/L and CP = 0.1 mg/L.
Q.1 The value of CR in mg/L, up to one digit after the decimal point, is ________ (2-Marks)
Q.2 A fractionf of the feed is bypassed and mixed with the permeate to obtain treated water having
a fluoride concentration of 1 mg/L. Here also the flow rate of the reject stream is 60% of the
flow rate entering the reverse osmosis unit (after the bypass). The value of f , up to 2 digits after
the decimal point, is __________ (2-Marks)
GATE-2012
Notation:
Molar flow rate of fresh B is FFB
Molar flow rate of A is FA
Molar flow rate of recycle gas is FRG
Molar fraction of B in recycle gas is YRB
Molar flow rate of purge gas is FPG
Molar flow rate of C is FC
Here, FFB = 2 mol/s; FA = 1 mol/s, FB/FA = 5
and A is completely converted.
Q. 3 If YRB = 0.3 , the ratio of recycle gas to, purge gas ( FRG / FPG ) is (2-Marks)
(A) 2 (B) 5 (C) 7 (D) 10
Q. 4 If the ratio of recycle gas to purge gas ( FRG / FRB ) is 4 then FRB is (2-Marks)
3 2 1 3
(A) (B) (C) (D)
8 5 2 4
SOLUTIONS
Explanations-2013
1.
Feed (F)
RO Reject (R)
CF = 2 mg/L
Explanations - 2012
3. (B)
FB
Given: FFB = 2mol / sec = 5mol / sec
FA
FA = 1mol / sec
A is completely converted
Assume separator separatesall C ∴ FC = 1mol / sec
Overall Material Balance across the dotted circle
FA + FFB = FC + FPG
FPG = FA + FFB - FC = 1 + 2 -1 = 2 mol / sec
Material Balance for component B at the point (1)
FB = FFB + YRB FRG
FB - FFB
FRG =
YRB
YRB = 0.3 given so FRG = 10mol / sec
FRG 10
= = 5.
FPG 2
FRG
4. (A) = 4 ( given )
FPG
∵ FPG = 2 from Question ( 50 )
FRG = 4 × FPG = 4 × 2 = 8 mol / sec.
Material Balance at point (1)
FB = FFB + YRB × FRG
FB - FFB FB = 5mol / sec
YRB = given
FRG FFB = 2mol / sec
5-2 3
= =
8 8
2. THERMODYNAMICS
(GATE Previous Papers)
GATE-2013
Q.1 A gaseous system contains H2, I2, and HI, which participate in the gas-phase reaction
H 2 + I 2
2HI
At a state of reaction equilibrium, the number of thermodynamic degrees of freedom
is _________ (1-Mark)
Q.2 The thermodynamic state of a closed system containing a pure fluid changes from (T1, p1) to
(T2, p2), where T and p denote the temperature and pressure respectively. Let Q denote the heat
absorbed (> 0 if absorbed by the system) and W the work done (> 0 if done by the system).
Neglect changes in kinetic and potential energies. Which one of the following is CORRECT
(A) Q is path-independent and W is path-dependent (1-Mark)
(B)Q is path-dependent and W is path-independent
(C) (Q − W) is path-independent
(D) (Q + W) is path-independent
Q.3 An equation of state is explicit in pressure p and cubic in the specific volume v. At the critical
point ‘c’, the isotherm passing through ‘c’ satisfies (1-Mark)
∂p ∂2 p ∂p ∂2 p
(A) < 0, 2 = 0 (B) >, 0 2 < 0
∂v ∂v ∂v ∂v
∂p ∂2 p ∂p ∂2 p
(C) = 0, > 0 (D) = 0, =0
∂v ∂v 2 ∂v ∂v 2
Q.4 The units of the isothermal compressibility are (1-Mark)
-3 -1 3 -1
(A) m (B) Pa (C) m Pa (D) m-3 Pa-1
Q.5 In a process occurring in a closed system F, the heat transferred from F to the surroundings E
is600 J. If the temperature of E is 300 K and that of F is in the range 380 - 400 K, the entropy
Changes of the surroundings (∆SE) and system (∆SF), in J/K, are given by
(A) ∆S E = 2, ∆S F = − 2 (B) ∆S E = −2, ∆S F = 2 (2-Marks)
(C) ∆S E = 2, ∆S F < − 2 (D) ∆S E = 2, ∆S F > − 2
Q.6 A binary; liquid mixture is in equilibrium with its vapor at a temperature T = 300 K. The liquid
mole fraction x1 of species 1 is 0.4 and the molar excess Gibbs free energy is 200 J/mol. The
value of the universal gas constant is 8.314 J/mol-K, and γi denotes the liquid-phase activity
coefficient of species i. If ln ( y1 ) = 0.09 , then the value of ln ( γ 2 ) , up to 2 digits after the
decimal point, is ________ (2-Marks)
Q.7 Calculate the heat required (in kJ, up to 1 digit after the decimal point) to raise the temperature
of1 mole of a solid material from 100 °C to 1000 °C. The specific heat (Cp) of the material (in
J/mol-K) is expressed as Cp = 20 + 0.005T, where T is in K. Assume no phase change.
_________ (2-Marks)
SOLUTIONS
Explanations - 2013
1. (c)
H2 ( g ) + I2 ( g )
2HI( g )
Degree of freedom = C – P + 2 = 2 – 1 + 2 = 3
2. (c)
The difference of two path dependent functions ends up in a property which does not depend
on anything but the state of the system.
∆U = Q − W
Q and W are path dependent. U depends only on the state of the system.
3. (d)
For pure substances, there is an inflection point in the critical isotherm (constant temperature
line) on a PV diagram. At the critical point
∂p ∂2 p
= =0
∂v T ∂v 2 T
4. (b)
Isothermal compressibility
1 ∂V
βT = −
V ∂ P T
Unit of βT is Pa −1 .
5. (b) ∆ Q system = − 600 J
∵ ∆ Qsystem + ∆ Qsurrounding = 0
∴ ∆ Qsurrounding = 600 J
dqrev
We know ∆S = ∫
T
∆ Q surrounding 600
∴ ∆ Ssurrounding = = =2
Tsystem 300
6. ∆ G = RT( x2 ln v1 + x1 ln v2 ) and x2 + x1 = 1
∴ ∆ G = RT((1 − x1 ) ln v1 + x1 ln v2 )
f = 300 K x1 = 0.4
ln v1 = 0.09
∴ 200 = 8.314 × 300((1 – 0.4) × 0.09 + 0.4 ln v 2 )
After solving ln V2 = 0.0654
7.
∆ Q = ∫ n CP d T
1000 + 273 1273
0.005 T 2
= ∫ (20 + 0.005T)d T = 20T +
100 + 273 2 273
3. FLUID MECHANICS
(GATE Previous Papers)
GATE-2013
Q.1 The apparent viscosity of a fluid is given by
0.3
dV dV
0.004 where is the velocity gradient. The fluid is (1-Mark)
dy dy
(A) Bingham plastic (B) dilatant (C) pseudo plastic (D) thixotropic
Q.2 The mass balance for a fluid with density ( ρ ) and velocity vector (V ) is (1-Mark)
∂ρ ∂ρ
(A)
∂t
( )
+ ∇. ρ V = 0 (B)
∂t
+ V . ( ∇ρ ) = 0
∂ρ ∂ρ
(C)
∂t
( )
+ ρ . ∇V = 0 (D)
∂t
+ V . ( ∇ρ ) = 0
Q.3 An incompressible Newtonian fluid, filled in an annular gap between two concentric
cylinders of radii R1 and R2 as shown in the figure, is flowing under steady state conditions.
The outer cylinder is rotating with an angular velocity of Ω while the inner cylinder is
stationary. Given that ( R2 − R1 ) << R1 , the profile of the θ − component of the velocity Vθ
can be approximated by, (1-Mark)
Q.4 For a Newtonian fluid flowing in a circular pipe under steady state conditions in fully
developed laminar flow, the Fanning friction factor is (1-Mark)
−0.2 0.125
(A) 0.046 Re (B) 0.0014 +
Re0.32
16 24
(C) (D)
Re Re
Solutions
Explanations– 2013
1. (b)
In non-Newtonian fluid, the shear stress due to viscosity is
n
du
τ xy = K
dy
Where, K = Flow consistency index
n = Flow behavior index(dimensionless)
n −1
du du du
or τ yx = k =n
dy dy dy
n −1
du
where, n = k
dy
For question
0.3
dV
n = 0.004
dy
So, n – 1 = 0.3 ⇒ n = 1.3 > 1
n> 1 for dilatant
n< 1 for pseudo plastic
n = 1 for Newtonian fluid
2. (a)
The continuity equation states that, in any steady state process, the rate at which mass enters
a system is equal to the rate at which mass leaves the system.
Differential form of the continuity equation is given by
∂ρ
+ ∇ . (ρu ) = 0
∂t
Where, ρ – Fluid density
u – Flow velocity vector field
t – Time
If, ρ = constantthen ∇ . u = 0
3. (d)
Point: A(R 1 , 0) B( r , Vθ )
C(R 2 Ω . r )
Slope between A and C = Slope between B and A C
Ωr − 0 Vθ − 0 B
= A
R 2 − R 1 r − R1
r − R1
∴ Vθ = Ωr
R 2 − R1
f ρv 2
4. (c) τ=
2
where, f – Fanning friction factor of the pipe
τ – Shear stress at the wall
ρ – Density of the fluid
16
Fanning friction factor for laminar flow in round tubes f =
Re
4. MECHANICAL OPERATIONS
(GATE Previous Papers)
GATE-2010
Q.1 The critical speed (revolutions per unit time) of a ball mill of radius R, which uses balls of
radius r, is (1-Mark)
1 g 1 g 1 g 1 g
(A) 2π Rr (B) 2π R (C) 2π r (D) 2π R-r
GATE-2008
Q.2 The power required for size reduction in crushing is (1-Mark)
1
(A) Proportional to
Surface energy of the material
1
(B) Proportional to
Surface energy of the material
(C) Proportional to Surface energy of the material
(D) Independent of the Surface energy of the material
GATE-2007
Q.3 In Tyler series, the ratio of the aperture size of a screen to that of the next smaller screen is
(1-Mark)
1
(A) (B) 2 (C) 1.5 (D) 2
2
Q.4 Size reduction of coarse hard solids using a crusher is accomplished by
(1-Mark)
(A) attrition (B) compression (C) cutting (D) impact
Q.5 In constant pressure filtration, the rate of filtration follows the relation (v: filtrate volume,
t:time, k and c: constant), (1-Mark)
dv dv 1 dv
(A) = kv + c (B) = (C) = kv (D)
dt dt kv + c dt
dv
= kv 2
dt
Q.6 Sticky material are transported by (1-Mark)
(A) apron conveyor (B) screw conveyor
(C) belt conveyor (D) hydraulic conveyor
GATE-2006
Statement for Linked Answer Question 7&8:
A continuous grinder obeying the Bond crushing law grinds a solid at the rate of 1000 kg/hr from the
initial diameter of 10 mm to the final diameter of 1 mm.
Q.7 If the market now demands particles of size 0.5 mm, the output rate of the grinder (in kg/hr)
for the same power input would be reduced to (2-Marks)
(A) 227 (B) 474
(C) 623 (D) 856
SOLUTIONS
Explanations - 2010
1. (D)
1 g
nc =
2π R-r
Where nc- Critical Speed
r – radius of ball
R – Radius of ball mill
Mills run at 65 to 80% of the critical speed
Explanations - 2008
2. (C) Energy required for size reduction is directly proportional to the change in surface
area, According to Rittinger’s low
w 1 1
= Kr − ve sign
m D sb D sa
Surface energy is the work per unit area done by the forces that creates the new
surface.
Explanations - 2007
3. (B) Tyler mesh size is the number of openings per linear inch of mesh.
The ratio of the aperture size of a screen to that of the next smaller screen is 2
4. (B) Size reduction of coarse hard solids crushers utilizes the compressive force between two solid
surface. Crushers are used for size reduction of minerals, gravel and ores.
dv ∆PA
5. (B) =
dt αx V
µ s + Rm
A
1
=
µα xs µ Rm
2
V+
A ∆P ∆PA
∴∆P = Const for const press filtration
1 µα xs µ Rm
= Where K = 2
C =
KV + C A ∆P ∆PA
6. (B) Screw conveyor:Screw conveyor uses a rotating helical screw blade to move the liquid or
granular material. For sticy material we use shaftless screw conveyor.
Explanation - 2006
1 1
-
=
T2 1 10
T1 1 1
-
0.5 10
T2 0.684 T2
= = 0.623
T1 1.098 T1
T2 = T1 × 0.623 Given T1 = 1000 kg / hrS
= 1000 × 0.623 = 623 kg / hr