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Chemistry 2017 P2 PDF
Chemistry 2017 P2 PDF
CHEMISTRY
UNIT 2 -Paper 02
2 hours 30 minutes
1 This paper consists of SIX questions in TWO sections. Answer ALL questions
7 If you need to rewrite any answer and there is not enough space to do so on the
original page, you must use the extra lined page(s) provided at the back of this booklet.
Remember to draw a line through your original answer.
8 If you use the extra page(s) you MUST write the question number clearly in the
box provided at the top of the extra page(s) and, where relevant, include the
question part beside the answer.
MODULE 1
[3 marksl
(b) On analysis, one gram of Compound A (containing carbon, hydrogen and oxygen only)
provided 0.40 g of carbon and 0.54 g of oxygen. Compound A has a molecular mass of
60 and effervesces readily with calcium carbonate.
Calculate the
[2 marks]
[1 markl
[1 mark]
[1 markl
(d) Comment on the relative pK" values of A and its related compound in (c) (ii)
[2 marks]
Describe a simple laboratory test to distinguish between EACH of the following pairs
-l
of
compounds:
[3 marksl
(ii)
and
[2 marksl
Total 15 marks
2
-l
ANALYTICAL METHODS AND SEPARATION TECHNIQUES
(i) Accuracy
[2 marks]
(ii) Precision
[2 marks]
(b) Suggest a separating technique that would be MOST effective in the extraction of eugenol
(oil) from cloves (plant) in its natural source.
[1 markl
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-10- -l
INDUSTRY AND THE ENVIRONMENT
3. (a) (i) State the reason why the presence of ozone in the stratosphere is beneficial to
humans-
I markl
(ii) Write the relevant equations which show the formation of ozone in the stratosphere.
[4 marks]
(b) (i) Ozone in the troposphere is harmful to humans and is therefore considered to be
apollutant. List TWO effects of the harmful presence of ozone on humans.
[2 marks]
(ii) The internal combustion engine of motor vehicles is responsible for the production
of ozone in the troposphere.
Describe, with relevant equations, the production of ozone as a result of the use
of these engines.
[3 marks]
GO ON TO THE NEXT PAGE
02212020/CAPE 2017
Complete Table 1 by inserting the relevant test and inferences in order to identiff the
pollutants.
[2 marks]
[1 mark]
[1 mark]
[1 markl
Total 15 marks
SECTION B
-l
AnswerALL questions.
MODULE 1
4. (a) Define the terms 'primary', 'secondary'and 'tertiary'as applied to alcohols. Give relevant
examples using structural formulae.
Primary alcohol
Secondary alcohol
Tertiary alcohol
[6 marks]
GO ON TO THE NEXT PAGE
022t2020lcAPE20t7
Two isomeric phenyl alcohols, A and B, (C8Hroo), on treatment with concentrated sulfuric
-l
acid produced Compound D, which decolourized a solution of bromine in an organic
solvent. Oxidation of the isomers with acidified potassium dichromate(Vl) produced
compounds E and F which both gave yellow precipitates with 2, 4-DNP reagent. However,
only Compound F formed a silver mirror with a solution of silver nitrate.
(i) State the type of reaction which produced Compound D and write its structural
formula.
Type of reaction
[2 marksl
(ii) Explain the reactions which led to the production of Compounds E and F.
[2 marks]
[2 marksl
(ii) A and B.
[2 marks]
[1 mark]
Total 15 marks
[3 marksl
(ii) State whether sodium hydroxide can be considered a primary standard and suggest
a reason for your answer.
[2 marks
(b) A student standardized an unknown solution of an acid, HrA, by adding successive 5 cm3
portions of the acid to 25 cm3 of a solution of sodium hydrogen carbonate of concentration
b.ZS mol dmr. The temperature was taken after each addition. From the data collected,
2 on
a graph of temperature versus volume of acid added was plotted as shown in Figure
page 16.
[4 marksl
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Temp ("C)
40
30
20
10
10 20 30 40 50 Volume (cm3)
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-17 - -l
(i) the number of moles of carbonate used
[1 markl
[2 marksl
[1 markl
(d) State ONE other titrimetric method that could be used without an indicator by the student
in (b).
[1 markl
(e) Identify the responding variable involved in the method stated in (d).
[1 markl
Total 15 marks
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MODULE 3
18 -
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INDUSTRYAND THE ENVIRONMENT
(i) Cracking
[2 marksl
(ii) Reforming
[2 marksl
(b) Using an appropriate equation, apply the principles of chemical equilibrium to deduce the
theoretical conditions for the production of ammonia.
[4 marks]
[5 marks]
(d) Explain ONE possible effect of the ammonia industry on groundwater usage
[2 marksl
Total 15 marks
END OF TEST
IF YOU FINISH BEFORE TIME IS CALLED, CIIECK YOUR WORK ON THIS TEST.
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