PHY./INO.

CHEMISTRY

TARGET : JEE (Main + Advanced) 2016

Course : VIJETA (JP) NO. 37

This DPP is to be discussed in the week (31.08.2015 to 05.09.2015)

DPP No. # 37 (JEE-ADVANCED)

Total Marks : 73 Max. Time : 49 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.8 (3 marks, 2 min.) [24, 16]
Multiple choice objective ('–1' negative marking) Q.9 to Q.11 (4 marks, 2 min.) [12, 06]
Comprehension ('–1' negative marking) Q.12 to Q.14 (3 marks, 2 min.) [09, 06]
Single Integer type Questions ('–1' negative marking) Q.15 to Q.18 (4 marks 3 min.) [16, 12]
Double Integer type Questions ('–1' negative marking) Q.19 (4 marks 3 min.) [04, 03]
Match the Following (no negative marking) Q.20 (8 marks, 6 min.) [08, 06]

1. A + H2O  B + HCl

B + H2O  C + HCl
Compound (A), (B) and (C) will be respectively :
;kSfxd (A), (B) o (C) Øe'k% gksxs :
(A) PCl5, POCl3, H3PO3 (B*) PCl5, POCl3, H3PO4
(C) SOCl2, POCl3, H3PO3 (D) PCl3, POCl3, H3PO4
Sol. (B) PCI5 + H2O  POCI3 + 2HCI
(A) (B)
POCI3 + 3H2O  H3PO4 + 3HCI
(B) (C)

2. Select the incorrect reaction(s) :

xyr vfHkfØ;kvksa dk p;u dhft;s&
(A) K2Cr2O7(s) + 4NaCl(s) + 3H2SO4(conc.) ¼lkUnz½  2CrO2Cl2 + 2Na2SO4 + K2SO4 + 3H2O

(B) K2Cr2O7(s) + 6K(s) + 7H2SO4(conc.) ¼lkUnz½  3I2 + Cr2(SO4)3 + 4K2SO4 + 7H2O

(C*) MnO2(s) + NaCl(s) + 2H2SO4 (conc.) ¼lkUnz½  NaHSO4 + MnSO4 + HCl + H2O + 1/2O2

(D) KI(s) + H3PO4(conc.) ¼lkUnz½  HI + KH2PO4

3. Which of the following statement (s) is/are incorrect ?

(A*) Ammonia is oxidised to NO 2 by oxygen at 8000C in presence of a catalyst platinum.
(B) Nitric acid on standing slowly turns yellow.
(C) Colloidal sulphur is formed when H2S gas is passed through nitric acid solution.
(D) N2O3 gas dissolves in water giving a pale blue solution.
fuEu esa ls dkSulk@dkSuls dFku vlR; gS ?
(A*) 8000C rki ij] IysVhue mRizsjd dh mifLFkfr esa veksfu;k] O2 ds }kjk NO2 esa vkWDlhd`r gksrh gSA
(B) ukbVªhd vEy j[kus ij /khjs&/khjs ihyk gks tkrk gSA
(C) H2S xSl dks ukbVªhd vEy foy;u ls izokghr djus ij dksykbMy lYQj curh gSA
(D) N2O3 xSl ty esa foys; gksdj] gYdk uhyk foy;u nsrk gSA

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4. 'V1' ml of an aqueous urea solution having osmotic pressure as 2.4 atm is mixed with 'V2' ml of another
V1
aqueous urea solution having osmotic pressure as 4.6 atm at same temperature. What will be value of
V2
if resulting solution after mixing has osmotic pressure as 2.95 atm.
leku rki ij ,d tyh; ;wfj;k foy;u] ftldk ijklj.k nkc 2.4 atm gS] ds 'V1' ml vk;ru dks nwljs tyh; ;wfj;k foy;u
V1
ftldk ijklj.k nkc 4.6 atm gS] ds 'V2' ml esa feyk;k tkrk gS rks ifj.kkeh foy;u ds fy, dk eku Kkr dhft,A ;fn
V2
fefJr djus ij ifj.kkeh foy;u dk ijklj.k nkc 2.95 atm gks tkrk gSA
(A) 1 (B) 1.5 (C) 2 (D*) 3
2.4 V1  4.6 V2
Sol. R = V1  V2 = 2.95 atm (assume temperature constant) (eku rki fu;r gSA)

V1
V2 = 3.

5. STATEMENT-1 : NO(s) is a neutral oxide, diamagnetic and is not an acid anhydride.

STATEMENT-2 : NO as a ligand is a three electron donor and paramagnetic in gaseous state.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B*) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True
dFku-1 : NO(Bksl) ,d mnklhu izfrpqEcfd; vkWDlkbM gS rFkk ;g ,d vEy ,ugkbMªkbM ugha gSA
dFku-2 : NO xSlh; voLFkk esa gS rFkk vuqpqEcfd;] rhu bysDVªkWu nkrk fyxs.M gSA
(A) dFku&1 lR; gS] dFku&2 lR; gS ; dFku&2, dFku&1 dk lgh Li"Vhdj.k gSA
(B*) dFku&1 lR; gS] dFku&2 lR; gS ; dFku&2, dFku&1 dk lgh Li"Vhdj.k ugha gSA
(C) dFku&1 lR; gS] dFku&2 vlR; gS ;
(D) dFku&1 vlR; gS] dFku&2 lR; gS
Sol. Both statement are correct but not correct explanation
NO solid is dimerised so diamagnetic O=N – N=O (s) but gasesous form is paramagnetic.
nksuks dFku lgh gS ijUrq f}rh; dFku izFke dFku fd lgh O;k[;k ugh djrk gSA
Bksl NO ,d f}yd gS ¼f}yfdd`r gks tkrk gS½ blfy, izfrpqEcfd; gS (O=N – N=O (s)) ysfdu xSlh; voLFkk esa ;g
vuqpqEcfd; gSA

6. S1 : Calcium carbide reacts with nitrogen gas at 11000C to form a fertilizer, nitrolim.
11000C rki ij dSfY'k;e dkckZbM ds lkFk ukbVªkstu xSl fØ;k dj ukbVªksfy;e moZjd cukrh gSA
S2 : (C) All the elements of nitrogen family are polyatomic.
ukbVªkstu ifjokj ds lHkh rRo cgqijek.kfod gksrs gSA
S3 : The melting point of antimony is less than arsenic.
,UVheuh dk xyukad vklZsfud dh rqyuk esa de gksrk gSA
(A*) T T T (B) T F T (C) F T T (D) T F F
Hint : S3 : Avalability of electrons for metallic bonding .
Hint : S3 : /kkfRod ca/k ds fy, bysDVªkWu dh miyC/krk de gksrh gSA

7. (A) Dry ammonia gas can be obtained by passing it through a U-tube containing anhydrous calcium chloride.
(B) The brown ring test for nitrates depends on the ability of Fe2+ to reduce nitrates to nitric oxide which then
reacts with Fe2+ to form a brown coloured complex.
(C) Metals like chromium, aluminimum dissolves in concentrated nitric acid (80%).
(A*) F T F (B) T F T (C) F T T (D) T F F

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 (A) futZyh; dSfY'k;e DyksjkbM ;qDr U-ufydk ls veksfu;k dks izokghr djus ij 'kq"d veksfu;k xSl izkIr gksrh gSA
(B) Hkwjh oy; ifj{k.k Fe2+ dh ukbVªSV ds ukbVªhd vkWDlkbM esa vip;u dh {kerk ij fuHkZj djrk gS tks fd Fe2+ ds lkFk
vfHkd`r gksdj Hkwjh oy; ladqy cukrk gSA
(C) /kkrq tSls dh Øksfe;e] ,Y;qfefu;e (80%) lkanz ukbfVªd vEy esa foy;'khy gSA
(A*) F T F (B) T F T (C) F T T (D) T F F

8. A mixture of bauxite and coke on strongly heating to about 1800 0C in nitrogen atmosphere gives a white
compound (A). The compound (A) is readily hydrolysed in aqueous solution giving a colourless gas (X) and
a white precipitate. Select the incorrect statement of gas (X).
(A) reduces the heated CuO to copper.
(B) produces white precipitate with Hg2+ ions and black precipitate with Hg22+ ions.
(C) decolourises pink colour of KMnO 4 with the formation of MnO 2 (black) and liberating nitrogen gas in
neutral medium.
(D*) by the catalytic oxidation of gas 'X' nitrous acid is prepared (Ostwald's process).
(E) X gives white fumes with HCl.
yxHkx 18000C rki ij ckWDlkbV rFkk dksd ds feJ.k dks ukbVªkstu ds okrkoj.k dh mifLFkfr esa xeZ djus ij ,d lQsn
;kSfxd (A) izkIr gksrk gSA ;kSfxd (A) tyh; foy;u esa rhozrk ls tyvi?kfVr gksdj ,d jaxghu xSl (X) rFkk ,d lQsn
vo{ksi nsrk gSA xSl (X) ds fy, vlR; dFku dk pquko dhft,A
(A) xeZ CuO dks dkWij esa vipf;r djrh gSA
(B) Hg2+ vk;u ds lkFk 'osr vi{ksi rFkk Hg22+ vk;u ds lkFk dkyk vo{ksi nsrh gSA
(C) MnO2 (dkys) ds fuekZ.k ds lkFk KMnO4 ds xqykch jax dks jaxghu djrh gS] rFkk mnklhu ek/;e esa ukbVªkstu xSl mRiUu
djrh gSaA
(D*) xSl 'X' ds mRizsjdh vkWDlhdj.k ds }kjk ukbVªl vEy cuk;k tkrk gSaA ¼vkWLVokYM izØe½
(E) X, HCl ds lkFk 'osr /kqze nsrk gSA
Sol. Al2O3.2H2O + 3C + N2 1800C
  2AlN + 3CO + 2H2O
(A)

2AlN + 3H2O  Al(OH)3 + NH3

(white ppt) (x)
(D) Reaction involed in ostwald's process :

4NH3(g) + 5O2(g) Pt/Rh

  catalyst
  4NO(g) + 6H2O(g)
5 atm, 850º C

NO + 1/2O2 
 NO2 ; 3NO 2 + H2O 
 2HNO3 + NO.
Sol. Al2O3.2H2O + 3C + N2 1800C
  2AlN + 3CO + 2H2O
(A)

2AlN + 3H2O  Al(OH)3 + NH3

(white ppt) ¼'osr vo{ksi½ (x)
(D) vkWLVokYM izØe esa fufgr vfHkfØ;k,a fuEu gSa %

4NH3(g) + 5O2(g) Pt/Rh

  catalyst
  4NO(g) + 6H2O(g)
5 atm, 850º C

NO + 1/2O2 
 NO2 ; 3NO 2 + H2O 
 2HNO3 + NO.
9. A mixture of two inorganic salts give following chemical reactivity.
(i) Mixture on reaction with dilute H2SO4 and zinc dust produces a colourless and unpleasant gas which
turns acidified lead acetate solution black.
(ii) Mixture on reaction with concentrated. H2SO4 gives reddish brown gas which does not produce orange red
spots on starch paper.
(iii) The mixture gives white precipitate with barium chloride solution which is soluble in dilute HCl.
(iv) The sodium carbonate extract of mixture responds to brown rings test.
The mixture contains :
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 (A*) SO32– and NO3– anions (B) S2– and NO3– anions
(C*) SO32– and NO2– anions (D) SO32– and Br– anions
nks vdkcZfud yo.kksa dk feJ.k fuEufyf[kr jklk;fud vfHkfØ;k,a nsrk gSA
(i) feJ.k] ruq H2SO4 rFkk ftad pw.kZ ds lkFk vfHkfØ;k dj jaxghu rFkk v:fpdj xSl mRiUu djrk gS] tks vEyhd`r ysM
,lhVsV foy;u dks dkyk djrh gSA
(ii) feJ.k lkanz H2SO4 ds lkFk yky] Hkwjh xSl nsrk gS tks fd LVkpZ i=k ij ukjaxh] yky /kCcs mRiUu ugha djrh gSA
(iii) feJ.k csfj;e DyksjkbM foy;u ds lkFk lQsn vo{ksi nsrk gSA tksfd ruq HCl esa foys; gSA
(iv) feJ.k dk lksfM;e dkcksZusV fu"d"kZ Hkwjh oy; ijh{k.k nsrk gSA
(A*) SO32– rFkk NO3– _.kk;u (B) S2– rFkk NO3– _.kk;u
(C*) SO32– rFkk NO2– _.kk;u (D) SO32– rFkk Br– _.kk;u
Hint. (i) SO32– + 3Zn + 8H+  H2S  + 3Zn2+ + 3H2O
H2S + Pb (CH3COO)2  PbS  (black) + 2CH3COOH
(iii) SO32– + Ba2+  BaSO3  (white)

SO32– + 2H+  SO2  + H2O

(ii) 4NO3– + 2H2SO4  4NO2  + O2  + SO42– + 2H2O
As does not produce orange red spots on starch paper, it can not be Br 2. So the anion is NO 3–.
(iv) 2NO3– + 4H2SO4 + 6Fe2+  6Fe3+ + 2NO  + 4SO42– + 4H2O
Fe2+ + 5H2O + NO  [Fe(H2O)5NO]2+.

10. KBr + MnO2 + H2SO4 (conc.)  KHSO4 + MnSO4 + H2O + [X] (unbalanced equation)
(A*) X turns starch paper orange red
(B) X with AgNO3 solution gives a pale yellow ppt which is completely soluble in dilute ammonium hydroxide.
(C*) X produces violet colour in organic layer in KI solution
(D*) X is liberated when a mixture of KBr, K2Cr2O7 and conc. H2SO4 is heated
KBr + MnO2 + H2SO4 (lkUnz)  KHSO4 + MnSO4 + H2O + [X] (vlarqfyr lehdj.k )
(A*) X, LVkpZ i=k dks ukjaxh yky dj nsrk gSA
(B) X, AgNO3 foy;u ds lkFk xgjk ihyk vo{ksi nsrk gS tksfd ruq veksfu;e gkbMªksDlkbM esa iw.kZr;k ?kqyu'khy gSA
(C*) X, KI foy;u esa dkcZfud ijr ij cSaxuh jax mRiUu djrk gSA
(D*) KBr, K2Cr2O7 rFkk lkUnz H2SO4 ds feJ.k dks xeZ djus ij X eqDr gksrh gSA
Sol. 2KBr + MnO2 + 3H2SO4  2KHSO4 + MnSO4 + 2H2O + Br2(X)
(A) Br2 + starch  starch bromine adsorption complex (orange red)
(C) 2K + Br2  2KBr + 2 (violet) soluble in organic layer..
(D) K2Cr2O7 + 6KBr + 7H2SO4  3Br2 + Cr2(SO4)3 + 4K2SO4 + 7H2O
(B) AgBr ppt. (pale yellow) is only partially soluble in NH4OH
g y& 2KBr + MnO2 + 3H2SO4  2KHSO4 + MnSO4 + 2H2O + Br2(X)
(A) Br2 + LVkpZ  LVkpZ czksehu vf/k'kks"k.k ladqy (ukjaxh yky)
(C) 2K + Br2  2KBr + 2 (cSaxuh) dkcZfud ijr esa foy;'khy
(D) K2Cr2O7 + 6KBr + 7H2SO4  3Br2 + Cr2(SO4)3 + 4K2SO4 + 7H2O
(B) AgBr dk vo{ksi (ihyk) dsoy NH4OH esa vkaf'kd foys; gSA

11. Which of the following is/are not correctly matched ?

(A) [Co(PMe3)4] - sp3 and one unpaired electron.
(B) [Ni(en)3](NO2)2 - sp3d2 and two unpaired electrons.
(C*) [V (NH3)6]Cl3- sp3d2 and two unpaired electrons.
(D*) [Mn (NO+)3(CO)] - sp3 and two unpaired electrons.

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 fuEu esa ls dkSulk@dkSuls fodYi lgh lqesfyr ugha gS@gSa ?
(A) [Co(PMe3)4] - sp3 rFkk ,d v;qfXer bysDVªksu
(B) [Ni(en)3](NO2)2 - sp3d2 rFkk nks v;qfXer bysDVªksu
(C*) [V (NH3)6]Cl3- sp3d2 rFkk nks v;qfXer bysDVªksu
(D*) [Mn (NO+)3(CO)] - sp3 rFkk nks v;qfXer bysDVªksu

Sol. (A) [Co(PMe3)4]

(B) [Ni(en)3]2+

(C) [V (NH3)6]3+

(D) [Mn3– (NO+)3 (CO)]

(A) [Co(PMe3)4]

(B) [Ni(en)3]2+

(C) [V (NH3)6]3+

(D) [Mn3– (NO+)3 (CO)]

Paragraph for Question Nos. 12 to 14

iz'u 12 ls 14 ds fy, vuqPNsn
Bond length is the average distance between the nuclei of the two atoms held by a bond. This represents the
internuclear distance corresponding to minimum potential energy for the system. Main factors which affects
the bond length are given below :
(1) Multiple bonds are shorter than corresponding single bonds.
(2) Sometimes single bond distance are some what larger than sum of their respective covalent radii of
bonded atoms (e.g. F 2). It is due to strong repulsive interaction between the lone pair electrons on adjacent
atoms.
(3) Some time, single bond distances are decreased due to bond acquiring some double bond character by
resonance.

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 cU/k yEckbZ] fdlh cU/k }kjk cfU/kr nks ijek.kqvksa ds ukfHkdksa ds e/; dh vkSlr nwjh gksrh gSA ;g ra =k ds fy, U;wure fLFkfrt
ÅtkZ ds laxr esa vUrjukfHkdh; nwjh dks iznf'kZr djrh gSA cU/k yEckbZ dks dks izHkkfor djus okys eq[; dkjd fuEu gaS %
(1) cgqcU/k yEckbZ mUgh ijek.kqvksa ds e/; ,dy cU/k yEckbZ dh rqyuk esa de gksrh gSA
(2) dqN mnkgj.kksa (tSls F2) esa la;qXeh ijek.qkvksa ij izcy ",dy ;qXe&,dy ;qXe" izfrd"kZ.k ds dkj.k cU/k yEckbZ dk eku
nksuksa ijek.kqvksa dh lgla;kstd f=kT;kvksa ds ;ksx ls vf/kd gksrk gSA
(3) dqN mnkgj.kksa esa ,dy cU/k dh yEckbZ vuqukn ds dkj.k vkaf'kd f}cU/k y{k.k mRiUu gksus dh otg ls de gks tkrh
gSA

12. Which is not true about the N—N bond length among the following species :
(I) H2N—NH2 (II) N2 (III) N2H2 (IV) N3–
(A) N—N bond length is shortest in II.
(B*) N—N bond length in I is shorter than that in III.
(C) N—N bond length in IV is shorter than that in III.
(D) N—N bond length in IV is intermediate between II and III.
fuEu nh xbZ Lihf'kt esa N—N cU/k yEckbZ ds fy, vlR; dFku NkafV, %
(I) H2N—NH2 (II) N2 (III) N2H2 (IV) N3–
(A) N—N cU/k yEckbZ II esa U;wure gSA (B*) N—N cU/k yEckbZ I es]a III ls de gSA
(C) N—N cU/k yEckbZ IV esa] III ls de gSA (D) N—N cU/k yEckbZ IV esa] II o III dh e/;orhZ gksrh gSA
Sol. (I) H2N – NH2 (II) N  N (III) H – N = N – H (iv) [N  N  N]  [N = N  N]–
N – N bond length in I is longer than in III.
Sol. (I) H2N – NH2 (II) N  N (III) H – N = N – H (iv) [N  N  N]  [N = N  N]–
I esa N – N caèk yEckbZ III ls c<+h gSA

13. In which of the following case central atom - F bond has partial double bond character :
fuEu esa ls fdl mnkgj.k esa "dsUnzh; ijek.kq - F" ds cU/k esa] vkaf'kd f}&cU/k ds vfHky{k.k gSA
(A) NF3 (B) CF4 (C*) BF3 (D) OF2
Sol. In BF3 due to back bonding.
BF3 esa i'p caèku ds dkj.kA

14. The correct order about of C—O bond length is

C—O cU/k yEckbZ ds fy, fuEu esa ls dkSulk Øe lgh gS %
(I) CO (II) CO2 (III) CO32–
(A) II < I < III (B) III < II < I (C*) I < II < III (D) I < III < II
Sol. Bond order  Bond Length 
caèk Øe  caèk yEckbZ 

(i) C  O (ii) O = C = O (iii)

15. In the disproportionation reaction of NaOH with one molecule of P4, number of molecules of NaOH reacting
are .............. .
P4 ds ,d v.kq dh] NaOH ds lkFk fo"kekuqikru vfHkfØ;k esa] NaOH ds fdrus v.kq vfHkd`r gksrs gS \ .............. .
Ans. 3
Sol. P4 + 3NaOH + 3H2O  PH3 + 3NaH2PO2

16. Hybridisation state of Xe and number of lone pair of electron in Xe in

XeO3, XeO2F2, XeF2 are spxda, spydb, spzdc, p, q and r respectively, the sum of a + b + c + p + q + r is :

XeO3, XeO2F2, XeF2 esa Xe dh ladj.k voLFkk rFkk Xe ij ,dkdh bysDVªkWu ;qXeksa dh la[;k Øe'k% spxda, spydb, spzdc,
p, q o r gSA a + b + c + p + q + r dk ;ksx gSA
Ans. 7

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Sol.

a = 0, b = 1, c = 1, p = 1, q = 1, r = 3
a+b+c+p+q+r =0+1+1+1+1+3=7

17. NH3 can be nearly entirely liberated on boiling which of the following aqueous solutions with NH 4Cl?
fuEu esa ls dkSuls fdrus tyh; foy;u NH4Cl ds lkFk mckyus ij yxHkx iw.kZ :i ls NH3 dks eqDr djrs gSaA
NaNO2, HNO3, Ca(OH)2, Na2CO3, NaCl, Na3PO4, CH3COONa
Ans. 3

Sol. Ca(OH)2 + 2NH4Cl  2NH3 + CaCl2 + 2H2O

Na2CO3 + NH4Cl  NaHCO3 + NaCl + NH3

Na3PO4 + NH4Cl  Na2HPO4 + NaCl + NH3

18. The compressibilty factor of N2 at 330K & 800 atm is 1.90 and at 570K & 200 atm is 1.10. A certain mass
of N2 occupies a volume of 1dm 3 at 330K and 800 atm. Calculate the volume of N2 gas at 570K and 200
atm.
N2 dk lEihM~;rk xq.kkad 330K rFkk 800 atm ij] 1.90 gS rFkk 570K rFkk 200 atm ij 1.10 gSA 330K rFkk 800 atm ij
N2 dk ,d] fuf'fpr nzO;eku] 1dm3 vk;ru ?ksjrk gSA 570K rFkk 200 atm ij N2 xSl ds vk;ru dh x.kuk dhft;sA
Ans. 4
PVm 1  800
Sol. Z 1.9 =
nRT n  R  330
1  800
n=
1.9R  330
V  200
Z  1.1 
nR  570
V  4L

19. Consider the equilibrium

Ni(s) + 4CO(g) Ni(CO)4(g)
–3
Kp = 0.125 atm .
If equal number of moles of CO and Ni(CO)4 (ideal gases) are mixed in a small container fitted with a piston,
if the maximum total pressure is P (in cm of Hg) to which this mixture must be brought in order to just
precipitate out metallic Ni then report your answer as P/4.
fuEu lkE; dk voyksdu dhft,
Ni(s) + 4CO(g) Ni(CO)4(g)
Kp = 0.125 atm–3.
;fn ,d fiLVu ;qDr ,d NksVs ik=k esa CO rFkk Ni(CO)4 (vkn'kZ xSlksa) ds eksyksa dh leku la[;k dks fefJr fd;k tkrk gS]
rc ,d vf/kdre~ dqy nkc P (cm Hg esa) gS] ftl ij /kkfRod Ni dk vo{ksi.k Bhd izkjEHk gksus yxrk gSA viuk mÙkj
P/4 ds :i esa O;Dr djsaA
Ans. 76
Sol. Ni(s) + 4CO(g) Ni(CO)4(g)
P P
For backward reaction (i'p vfHkfØ;k ds fy,)
Qp  Kp
P
 Kp
P4
1
 0.125 atm -3
 P3
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 P3  8 atm 3
P  2 atm
PTotal = 2 P = 4 atm.
P = 4 × 76 cm of Hg
P/4 = 76

20. Match the column :

Column-I Column-II
(Reactions) (Type of reaction/process involved)
(A) P4 — PH3 + H2PO2– (p) Hydrolysis
(B) [B4O5(OH)4]2– — B(OH)3 (q) Addition of KOH
(C) (CH3)2 SiCl2 — [(CH3)2 SiO]n (r) Condensation
(D) [Al(OH)4]– — Al(OH)3 (s) Redox reaction
(t) Acidificaton
feyku dhft,&
dkWy e-I dkW ye -II
( vfHkfØ;k ) (vfHkfØ;k dk iz dkj@fughr iz Øe )
(A) P4 — PH3 + H2PO2– (p) ty vi?kVu
(B) [B4O5(OH)4]2– — B(OH)3 (q) KOH dk ;ksx
(C) (CH3)2 SiCl2 — [(CH3)2 SiO]n (r) la?kuu
(D) [Al(OH)4]– — Al(OH)3 (s) jsMkWDl vfHkfØ;k
(t) vEyhdj.k
Ans. (A - p, q, s); (B - p, t); (C - p,q, r); (D - t)
0 Alkaline hydrolysis 3 1
Sol. (A) P4 + 3OH– + 3H2O      PH3 + 3H2 PO 2

Redox reaction

(B) [B4O5(OH)4]2– + 5H2O 2B(OH)3 + 2[B(OH)4]–

[B(OH)4]– + 2H3O+ — 2B(OH)3 + 4H2O
2nH 2O / 2nKOH Condensation
(C) n(CH3)2SiCl2 Hydrolysis
   [(CH ) Si(OH) ] 
3 2 2
   [(CH3)2SiO]n
 nH 2 O
dimethyl polysiloxanes are produced by hydrolysis of (CH3)2SiCl2 with KOH.
(D) [Al(OH)4]– + H+  Al(OH)3 + H2O

0 3 1
(A) P4 + 3OH– + 3H2O    
 PH + 3H PO
2
 3 2

jsMkWDl vfHkfØ;k
(B) [B4O5(OH)4]2– + 5H2O 2B(OH)3 + 2[B(OH)4]–
[B(OH)4]– + 2H3O+ — 2B(OH)3 + 4H2O
2nH2O / 2nKOH
(C) n(CH3)2SiCl2       [(CH3)2 Si(OH)2]  
 [(CH ) SiO]
nH2O 3 2 n

(CH3)2SiCl2 ds KOH ds lkFk ty vi?kVu }kjk] MkbZesfFky ikWyhlhyksDlsu (dimethyl polysiloxanes) mRikfnr gksrk gSA
(D) [Al(OH)4] + H  Al(OH)3 + H2O
– +

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