Aue %t.0 2 24 (78.2% - Gud) CEM 3600 ~ Biophysical Chemistry Exam I - Energy, Enthalpy & Entropy September 15% 2015 Name: beg Short Answer /Fill in the Blank; 1. Consider a cup of hot coffee cooling on my desk. ‘a. Is the "heat content’ of the coffee is an extensive or intensive property? [4] extensin b. Is the mass of the coffee in the cup extensive or intensive? [4] evtensle ©. The specific heat ofthe coffee (basically the same as water) is that extensive or intensive? [4] < iateasine d. As steam rises from the coffee, what extensive property is changing? [4] Mis (een. br aby hengieg rot thot Ty iat ensia) ‘2. The First Law of thermodynamics, a. Sates what (I'm looking for a sentence or two, or a mathematical equation)? [5] DU weg % Magy ® “heat gad “work an seme nin, 'b. Is partially a restatement of what older law (though the 1* Law is much wider in scope)? 14] Law of Consecration oF energy 3.6 eralized statement (words or mathematical equation) of the Second Law of (rode _ amics: [8] Samy * M9sq* BS un 7% Far any Spontanouy Charge, the foto! atopy of an inlet) System mut increnre 4. Consider a series of 5 coin tosses. Does TTHHH have the same probability of occurring as THHHT? Where H means a "heads" and T means “tails.” [5] t 5. For question four, do the two possible results correspond to microstates or states? [2] Micro steer 4 State ir all pork Combe of 3B 21.6. Without working a problem, briefly describe why a gas will expand adiabatically (that is, a well insulated system into which heat cannot “flow”, though it will still work on the surroundings). Your answer should contain the concept of multiplicity. [8] > Seq type) easuuers - Quantitative Problems; 7. Apiston contains 0.256 mol of an ideal gas. It is suspended in a large coolant bath and expands ‘sothermally and reversibly at 250 K from 5.00 mL to 143.4 mL, Determine: a AULA] Ioatherml, 20 AVEO b. wid) DUO = Qt qr-w Wry * = PRT in Wp, ® *(0, 256 mid 43 Yarn dl 4584 250K) In (4 ©. ald) 49 9r-w : bd) qe brah d. AS [4) citer Ase 1% or ASR In, ee 216, 2k 8. Ifa piston/oylinder system at some low pressure containing 0.100 mol of an ideal gas is {sothermally compressed from 250.0 mL to 1.00 mL at 300K (at 1.00 mL, the pressure in the system is 0.995 atm) how much heat must be transferred to the surroundings? [6] Wy - Pep AV ® -O.195 ate (|.0Ux fo"? L - 25000) = 14Ty rata, 10)-320 - a5. bain Go ike insthermel + wg 0.14 7q btn So q° asad‘9. The chair and boat conformations of Cyclohexane are quite close in energy, though the “boat” form is higher, AU between the two being only 120 J/mol. You should assume that the boat and chair positions are the only two conformers available. ‘a. Calculate the ratio of the two forms at room temperature (you may use 300 K for a close approximation). [10] we ik Mer e (leo as/eg ay du 300)) : 00 1535 Nig, = O.9F3 Mew, — oF Pre lowe encgy Fim i only Slightly prfin/ 10. Consider 8 coin tosses. ‘a, Determine the multiplicity of getting 2 heads. [5] M>% N=2 1 = 2% 2 = milMeN)! = 2057 b. Determine the multiplicity of getting 5 heads. [5] m>Y Weg ! Ww: 6 516) c. Calculate the difference in entropy of the two cases (2 and 5 heads). [5] Seka ll ASE leg (inl, ~ In W,) NS= leg (bn Gy, Jo LBB (bn May) = 1.5610 11. Consider an osmotic setup similar to the one is the book. A system is divided into two equally sized halves by a semi-permeable membrane. The left-hand and right-hand side contains 2000 molecules each. Each half of the system is divided into 10° equal sized “slots” into which a single ‘molecule might fit, Only the right-hand side molecules can pass through the membrane. a. Determine the entropy of the right-hand side before any effusion across the membrane occurs. 15] Mz 1o* N=2I0° ‘ 2 leg tee) = Ig (wl B)* 35 70?y, (aver 2) = L720" I b. Determine the total entropy of the system after 10% of the molecules gas effuse from the right ~hand to the left-hand side. [5] Sty = Spt Dy, = Pook > Fe No(G)- Mee +(l-x)in(t-) ) 2ro? 2 2(2M0>IIn (#) = AL 10 Un 10) + (.40XCIn, 90) Sr*l36™ lo? ) (2.4% 400" (-7479)) 23.53 x0,