RollNo. || Answer Sheet No, Ludi Sig. of Candidate. Sig. of Invigilator. CHEMISTRY HSSC-I SECTION — A (Marks 17) Time allowed: 25 Minutes NOTE: Section-A is compulsory and comprises pages 1-2. All parts of this section are to be answered on the question paper itself. It should be completed in the first 25 minutes and handed over to the Centre Superintendent. Deleting/overwriting is not allowed, Do not use lead pencil. Q.1 Circle the correct option Le. A/8/C /D. Each part carries one mark. (1) Which of the following has least mass? A Imolof O, B 7 gramof lg © -3.01x10™ aomsof D. —2.gram atoms of N (i) ‘The Partial pressure of H, ina flask containing 2 grams of /7, and 16 grams of 0, is 1 2 A 8 4 3 1 1 c D 6 8 {Boling point of solution is independent of, A Nature of solvent 8 Amount of solution C Pressure D. Concentration of solution tiv) +1 value for an orbital ‘A’ is 241=3 while for ‘Bis 340=3. The energy order is, A AB 8 BA CAB D. Can not be predicted (wv For the reaction. V, +3, =!2NH, AH =~92kJ mol ', which of the following gives the greatest yield of NIZ,? A Adding a catalyst 8 Decreasing the temperature and pressure C. Decreasing the temperature and increasing the pressure D. increasing the temperature and decreasing the pressure (vi) Joule Thomson expansion of an Ideal gas produces, A Heating 8 Cooling C Gas tiquefies D. No change in temperature (vi) The frequency of X-rays having wavelength of 4.4” (Angstrom) is A 13310 Be 2x l0uiie 6 7.S8«10" He Dd. 26x10! (vil) A solution of glucose fs 10% wiv. The volume in which one mol of itis dissolved will be — A td 8 18a © Wd D. 18din Page 1 of 2iChem)(ix) (x) (xi) (xii) xi) (xiv) (xv) wi) owi) DO NOT WRITE ANYTHING HERE If the energy of activated complex lies close to the energy of reactants, it means that the reaction is. A Slow B Fast C. Reaction does not take place D. — Endothermic After three half lives of a reaction, the % fraction of the amount left is, A 15% Bo 50% Cc 12.5% Dd 26% For the reaction H, +, = 2H the value of Kc=64. Ifthe volume of the container is reduced to one haif ofits original volume, the value of Ke is. A 48 B16 c. 64 D. 32 Which of the following solutes will depress the freezing point of water the least, if one mole of each is added? A Nat 8 CaCl, c. CAO, . AICI, How many moles of oxygen atoms are there in 0.5 moles of Ca(ClO,),? A 3 moles B. 6 moles c. 0.5 moles D. 1 mole Which metal will dissolve in galvanic cell containing copper and silver electrodes? (Cu (Cu=+0.34V Ag/ Ag’ =-0.80V) A. Copper B Siver c. Both A and B 3D None of these ‘What is the unit cell with crystallographic dimensions a = # ¢ and @ = 8 =y =90°? A Cubic B.Tetragonal C.— Monoclinic D. —_ Rhombic For a chemical reaction CH,COOH =CH,COO™+ H* A AH zero De An Negative During the electrolysis of aqueous solution of NaC using inert electrodes, A. HY, liberates at cathode B. Ci, tiberates at cathode ©. Na deposits at anode D. 0, evolves at anode For Examiner's use only: Total Marks: aa Marks Obtained: HA 1909 4) — Page 2 of 2(Cchem)Time allowed: 2:35 Hours. NOTE: CHEMISTRY HSSC-1 ‘Sections ‘B’ and ‘C’ comprise pages 1-2 and qui >? Total Marks Sections B and C: 68 jons therein are to be answered on the separately provided answer book. Answer any fourteen parts from Section ‘B’ and any two questions from Section ‘C’. Use supplementary answer sheet i.e. Shect-B if required. Write your answers neatly and legibly. SECTION ~ B (Marks 42) Attempt any FOURTEEN parts. The answer to each part should not exceed 5 to 6 lines. (14 x 3 = 42) « wi) (i vt w (vi) (wi) (wit) (x) Asample of AICI, contains 5.410" C17 ions. Calculate: a Number of Formuta units of IC, b Number of 10" jons in the sample © Mass of the sample (Al =27 5 C1 =35.5) The rate of filtration can be increased by using Fluted Filter Paper. Why? During crystalization process, why do some crystals appear coloured? How will he undesirable colours of crystals be removed? a State Avogadro's Law. b Calculate the number of molecules in10S0cm'of CO, at25 “Cand 800 mm Hg pressure 2 Define Molar heat of Vaporization and Molar heat of Sublimation b. Explain why heat of sublimation of a substance is greater than heat of vaporization Why is it impossible to determine both the position as well as momentum of an electron in an atom simultaneously? a Whatis lionization energy? Wny is the 1* LE <2™1.E and so on? b. Why does the ILE increase along the period? For the processes taking place at constant pressure, prove AH! = 4, Gaiculate the value of Kip for the synthesis of \//, according to the equation : N, 431, 2 2NH, Ke =6x107 ar500 °C Define Molaiity, What is the Moiality of 10% wiw Nu solution? What is Electrode Potentiat? Standard electrode potential values are given. Zni Zn? =+0.76V 5 Cu? (C= 40.341 Calculate emf of the cell, Also write the complete cell equation, a What is the Order of Reaction? b —_Astudy of kinetics of a reaction 4 + B > Product, gave the following data: Expt | tnitial rate | Col 1007075 T2300 | 078 iw [1.00] 620— 4.210 Calculate the order of reaction Page 1 of 2 (Chem) of of of 15 16 o1 02 02 on 03 02 01 03 03 of 02 1 oz oO 02