Reactor intermitente adiabático

Datos del problema:

Vreactor (gal)= 10
Vagua (gal)= 5
Vmetanol (gal)= 1
T(°F)= 58
T0(°F)= 77
i mol ΔHf  (J/mol)
°
ΔGf° (J/mol)
óxido de propileno -1 -93637.5016 93637.5016 -26782.0768 26782.0768
Agua -1 -241656.1248 241656.1248 -228419.204 228419.204
Propilenglicol 1 -421220.016 -421220.016 -303796.8928 -303796.8928

∆�_��� -85926.3896 j/mol

∆�_��� -48595.612 j/mol T(K) R(j7mol)
j/R -26957.8950347441 298.15 8.314
J -224127.939318863
ln K 19.6043398246
I= -984.1425169949

∆�_𝑅𝑋𝑁 (���/�����)
∆�_𝑅𝑋𝑁 (𝐵𝑡𝑢/𝑙𝑏𝑚𝑜𝑙)
T( R) T (K) Cp metanol Cp agua
517.67 287.59 -36884.358405838 -21459.3848647 15.37 8.13
520 288.89 -36890.3327133327 -21389.9447297 15.40 8.13
525 291.67 -36904.2109519496 -21240.837148 15.44 8.13
530 294.44 -36919.4177019562 -21091.5909752 15.49 8.13
535 297.22 -36935.8181298711 -20942.1956235 15.54 8.13
540 300.00 -36953.2827590435 -20792.6419384 15.59 8.13
545 302.78 -36971.6874696527 -20642.9221088 15.64 8.13
550 305.56 -36990.9134987084 -20493.0295815 15.68 8.13
555 308.33 -37010.8474400505 -20342.9589778 15.73 8.13
560 311.11 -37031.3812443492 -20192.7060135 15.78 8.13
565 313.89 -37052.412219105 -20042.2674218 15.83 8.14
570 316.67 -37073.8430286489 -19891.6408791 15.87 8.14
575 319.44 -37095.5816941419 -19740.8249328 15.92 8.14
580 322.22 -37117.5415935753 -19589.8189324 15.97 8.14
585 325.00 -37139.6414617708 -19438.6229621 16.01 8.14
590 327.78 -37161.8053903806 -19287.2377765 16.06 8.14
595 330.56 -37183.9628278869 -19135.6647383 16.11 8.15
600 333.33 -37206.0485796022 -18983.9057576 16.15 8.15
605 336.11 -37228.0028076694 -18831.9632336 16.20 8.15
610 338.89 -37249.7710310618 -18679.8399984 16.24 8.15
615 341.67 -37271.3041255826 -18527.5392625 16.29 8.16
620 344.44 -37292.5583238658 -18375.0645617 16.34 8.16
625 347.22 -37313.4952153752 -18222.4197062 16.38 8.16
630 350.00 -37334.0817464055 -18069.6087313 16.43 8.17
635 352.78 -37354.2902200809 -17916.6358492 16.47 8.17
640 355.56 -37374.0982963566 -17763.5054029 16.52 8.17
645 358.33 -37393.4889920179 -17610.2218214 16.56 8.18
650 361.11 -37412.4506806801 -17456.7895756 16.61 8.18
655 363.89 -37430.977092789 -17303.2131368 16.65 8.18
660 366.67 -37449.0673156209 -17149.4969354 16.70 8.19
665 369.44 -37466.725793282 -16995.6453213 16.74 8.19
670 372.22 -37483.962326709 -16841.6625256 16.78 8.19
680 377.78 -37517.2355487592 -16533.3194959 16.87 8.20
690 383.33 -37549.072525871 -16224.4979256 16.96 8.21
700 388.89 -37579.744511428 -15915.2237145 17.05 8.22
Constantes para el cálculo de Cp de gas a diferentes temperaturas (Obtenidas a partir de una regresión con datos proporcionad
Óxido de propileno Agua Propilenglicol Δa
a 60.59354 40.01028 293.6234 Δb
b -0.2467595 -0.0481805 -1.937305 Δc
c 0.0014054 0.0001194 0.0060932 Δd
d -1.45E-06 -8.37E-08 -5.73E-06

Model: CP = A+ B*TEMP + C*TEMP^2 + D*TEMP^3

Metanol 1) Ecuación de diseño:

a 39.78672 𝑁_𝐴0 𝑑𝑋/𝑑𝑡=−𝑟_𝐴∗�
b 0.0983209
c -4.69E-05 2) Ley de velocidad
d 7.62E-09 −𝑟_𝐴=𝑘∗𝐶_𝐴
3) Estequiometría
FA0 (Lbmol/h)= 43.04 𝐶_𝐴=(𝑁_𝐴/�)(1−𝑋)
FB0 (Lbmol/h)= 802.8
FM0 (Lbmol/h)= 71.87 4) Combinar las ecuaciones
𝑑𝑋/𝑑𝑡=� (1−�)
VA0 (Ft3/h)= 46.62
VB0 (Ft3/h)= 233.1
VM0 (Ft3/h)= 46.62
𝐶_𝑝𝑠= ∑▒ 〖 (𝜃_𝑖∗𝐶_𝑝𝑖) 〗 =�_𝐴

(���/(�����∗𝑅))

Cp propilenglicol Cp óxido de prop ΔCp Σθ*Cp X k(s-1)

24.87 17.04 -0.30 194.360893 0 1276.34775
24.92 17.10 -0.32 194.459902 0.0105425941 1469.8224
25.02 17.24 -0.35 194.674937 0.0369259909 1981.36512
25.12 17.37 -0.38 194.893401 0.0633466331 2655.93231
25.23 17.51 -0.41 195.115202 0.0898033019 3540.71475
25.34 17.64 -0.43 195.340248 0.1162950929 4695.18164
25.46 17.78 -0.45 195.568447 0.1428213973 6193.91186
25.58 17.92 -0.47 195.799707 0.169381884 8129.99245
25.70 18.05 -0.49 196.033936 0.1959764805 10619.0798
25.82 18.19 -0.50 196.271041 0.222605354 13804.2321
25.95 18.33 -0.51 196.510931 0.2492688928 17861.6364
26.08 18.46 -0.52 196.753514 0.2759676873 23007.3671
26.21 18.60 -0.53 196.998697 0.3027025107 29505.3316
26.35 18.74 -0.53 197.246388 0.3294743006 37676.5761
26.49 18.88 -0.53 197.496495 0.3562841392 47910.1434
26.63 19.01 -0.53 197.748927 0.3831332354 60675.696
26.77 19.15 -0.53 198.00359 0.4100229048 76538.1404
26.91 19.29 -0.53 198.260394 0.4369545515 96174.5124
27.05 19.42 -0.53 198.519245 0.4639296491 120393.408
27.19 19.56 -0.52 198.780051 0.4909497216 150157.269
27.34 19.70 -0.51 199.042722 0.518016325 186607.869
27.49 19.83 -0.51 199.307163 0.545131028 231095.362
27.63 19.97 -0.50 199.573284 0.5722953935 285211.299
27.78 20.11 -0.49 199.840993 0.5995109597 350826.038
27.93 20.24 -0.48 200.110196 0.6267792216 430131.025
28.08 20.37 -0.47 200.380803 0.6541016115 525686.429
28.22 20.51 -0.46 200.65272 0.6814794805 640474.689
28.37 20.64 -0.45 200.925856 0.7089140796 777960.522
28.52 20.78 -0.44 201.200119 0.7364065407 942158.017
28.66 20.91 -0.43 201.475417 0.7639578572 1137705.46
28.81 21.04 -0.42 201.751657 0.791568865 1369948.59
28.95 21.17 -0.41 202.028748 0.8192402234 1645032.93
29.24 21.43 -0.39 202.585112 0.8747656284 2352931.11
29.52 21.68 -0.38 203.143772 0.9305350709 3330722.68
29.79 21.94 -0.36 203.703993 0.9865454688 4668264.69
ión con datos proporcionados de Aspen)
193.01958
-1.642365
0.0045684
-4.1954E-06
Para k
A= 1.70E+13
E= 32400 Btu/lbmol
R= 1.987 Btu/lbmol R
) Ecuación de diseño: �_0= 75.0605409
𝑁_𝐴0 𝑑𝑋/𝑑𝑡=−𝑟_𝐴∗� 𝑘=(4.71𝑋 〖 10 〗 ^9 ) exp(−32400/((1.987)∗(𝑇) )) �= 3.40343855

) Ley de velocidad �_0/�= 0.04534258

−𝑟_𝐴=𝑘∗𝐶_𝐴 𝑘=(2.73𝑋 〖 10 〗 ^(−4) ) exp[32400/((1.987) ) (1/535−1/𝑇)]
) Estequiometría 𝐶_𝐴= 0.57340381
𝐶_𝐴=(𝑁_𝐴/�)(1−𝑋)
5) Balance de eenergía
) Combinar las ecuaciones 𝑇=𝑇_0+((−∆�_��� (�_0 ))∗�)/(𝐶_𝑝𝑠+∆𝐶_𝑝 𝑋) Para el metanol:
𝑑𝑋/𝑑𝑡=� (1−�)
𝜃_𝑀= 〖� _𝑀0/� 〗 1.66984201
_𝐴0

= ∑▒ 〖 (𝜃_𝑖∗𝐶_𝑝𝑖) 〗 =�_𝐴∗�_�𝐴+�_𝐵∗�_�𝐵+�_�∗�_�� Para el agua:

𝜃_𝐵= 〖� _𝐵0/� 〗 _𝐴0

18.6524164

k*(1-x) t
1276.34775 0
1454.32666 14.475878616
1908.20125 56.232144966
2487.68794 113.12000387
3222.74688 189.20666357
4149.15505 244.53377622 Temperatura vs Tiempo
5309.28872 353.39506806 750
6752.91901 494.60975128
8537.98989 675.99787137
10731.3361 861.99529592 700
13409.2861 1131.9956567
16658.0772 1470.6817924
650

600
 700

20573.9936 1892.5477259 650

25263.1125 2369.5422662
30840.5192 2989.4131491
37428.8203 3746.0037454 600
45155.7497 4663.6903611
54150.6215 5724.875301
64539.3362 7028.0953129 550
76437.5993 8577.9742591
89941.9464 10409.180406
105118.11 12513.27082 500
121986.187 14995.944081 0 10000 20000 30000 40000 50000 60000 70000 80000 90000 100000

140501.983 17865.885381
160533.836 21157.312445
181834.089 24855.044972
204004.331 29049.550312
226453.354 33723.07154
248346.691 38868.858269
268546.435 44412.223862
285539.939 50360.771187
297355.786 56584.770341
294667.849 70890.939227
231368.415 84243.052287
62809.3131 90896.194768
ft3/h
ft3

lbmol/ft3

t
100000
90000
80000
70000
60000
50000
40000
30000
20000
10000
 80000
70000
60000
50000
40000
30000
20000
10000
0
0 0.2 0.4 0.6 0.8 1 1.2

80000 90000 100000

1.2
Para el óxido de propileno:

TEMP CP
K J/kmol-K J/mol
273.15 68494.68 68.49468
275.15 68884.45 68.88445
277.15 69276.6 69.2766
279.15 69670.98 69.67098
281.15 70067.44 70.06744
283.15 70465.86 70.46586
285.15 70866.1 70.8661
287.15 71268.04 71.26804
289.15 71671.54 71.67154
291.15 72076.49 72.07649
293.15 72482.77 72.48277
295.15 72890.26 72.89026
297.15 73298.85 73.29885
299.15 73708.44 73.70844
301.15 74118.92 74.11892
303.15 74530.18 74.53018
305.15 74942.13 74.94213
307.15 75354.68 75.35468
309.15 75767.73 75.76773
311.15 76181.19 76.18119
313.15 76594.98 76.59498
315.15 77009.01 77.00901
317.15 77423.21 77.42321
319.15 77837.49 77.83749
321.15 78251.78 78.25178
323.15 78666.02 78.66602
325.15 79080.12 79.08012
327.15 79494.04 79.49404
329.15 79907.69 79.90769
331.15 80321.02 80.32102
333.15 80733.97 80.73397
335.15 81146.49 81.14649
337.15 81558.52 81.55852
339.15 81970.01 81.97001
341.15 82380.91 82.38091
343.15 82791.17 82.79117
345.15 83200.74 83.20074
347.15 83609.59 83.60959 Model: CP = A+ B*TEMP + C*TEMP^2 + D*TEMP^3
349.15 84017.68 84.01768
351.15 84424.96 84.42496 Variable Value
353.15 84831.39 84.83139 A 60.59354
355.15 85236.95 85.23695 B -0.2467595
357.15 85641.6 85.6416 C 0.0014054
359.15 86045.3 86.0453 D -1.45E-06
361.15 86448.03 86.44803
363.15 86849.76 86.84976
365.15 87250.46 87.25046
367.15 87650.1 87.6501
369.15 88048.67 88.04867
371.15 88446.14 88.44614
373.15 88842.48 88.84248
+ D*TEMP^3
Propilenglicol
TEMP CP
K J/kmol-K J/mol
273.15 102344 102.344
275.15 102549 102.549
277.15 102769 102.769
279.15 103002 103.002
281.15 103249 103.249 Model: CP = A + B*TEMP + C*TEMP^2 + D*TEMP^3
283.15 103509 103.509
285.15 103780 103.78 Variable Value
287.15 104063 104.063 A 293.6234
289.15 104356 104.356 B -1.937305
291.15 104660 104.66 C 0.0060932
293.15 104974 104.974 D -5.73E-06
295.15 105296 105.296
297.15 105628 105.628
299.15 105968 105.968
301.15 106315 106.315
303.15 106670 106.67
305.15 107032 107.032
307.15 107401 107.401
309.15 107775 107.775
311.15 108156 108.156
313.15 108542 108.542
315.15 108933 108.933
317.15 109330 109.33
319.15 109731 109.731
321.15 110136 110.136
323.15 110545 110.545
325.15 110958 110.958
327.15 111375 111.375
329.15 111795 111.795
331.15 112217 112.217
333.15 112643 112.643
335.15 113072 113.072
337.15 113502 113.502
339.15 113935 113.935
341.15 114370 114.37
343.15 114807 114.807
345.15 115246 115.246
347.15 115686 115.686
349.15 116127 116.127
351.15 116570 116.57
353.15 117014 117.014
355.15 117459 117.459
357.15 117904 117.904
359.15 118350 118.35
361.15 118797 118.797
363.15 119244 119.244
365.15 119692 119.692
367.15 120140 120.14
369.15 120587 120.587
371.15 121035 121.035
373.15 121483 121.483
+ D*TEMP^3