ARIA OF STUDY 1 CHEMICAL ANALYSIS 1.2 Volumetric analysis Multiple-choice questions Question 1.2.1 Consider the following equations. I C10,7 (aq) + H,0"(aq) > HCr0, (aq) + #00) TE 2C"(aq) + 24" (aq) -> 2Cr™*(aq) + Hy(e) MI Cr,0,(8) + 3C(s) + 2Cx(8) + 3C0(g) IV_Ba(NO5)9(aq) +Na,SO,(aq) > BaSO,(s) + 2NaNO,(aq) ‘The redox reactions are represented by equations A. Lendl. B, Wand Ill. land IV. . Land IV. Question 1.2.2 ‘Three 10.00 g samples of brandy were acidified and then titrated with 2.50 M potassium dichromate (K,Cr,0,) solution in order to determine the amount of ethanol that the brandy contained. The average titre obtained was 20.25 mL. The equation for the reaction that occurs is 2C1,0,* (aq) + 3CyH,OH(2q) + 16H (aq) ~> 4CE(aq) + 3CH,COOH(aq) + 111,00) orange green Based on these results, the percentage by mass of ethanol in this sample of brandy is A. 15.5% B. 165% C. 23.3% D. 349% Question 1.2.3 ‘Consider the reaction shown in the equation below. SH,0,(aq) + 2MnO, (aq) + 6H*(aq) > 2Mn™ (aq) + 8H,O() + 50,(8) ‘The oxidant in this reaction is A, HO, B. MnO,” c 0, D. Mn Question 1.2.4 Ethanoic acid (CH,COOH) is a weak acid, Sulfuric acid (H,SO,) and perchloric acid (HCIO,) are strong acids. 0.10 M solutions of ethanoic acid, sulfuric acid and perchloric acid are prepared. ‘The order of increasing pH of the three acid solutions is A. CH,COOH, HCIO,, H,S0,. B. _HCIO,, H)S0,, CH,COOH. C. H,S0,, CH,COOH, HCIO,. D. _H,S0,, HCO, CH,COOH. Question 1.2.5 How much water must be added to 1.0 L of a solution of a strong base of pH 13.0 in order to decrease the pH to 12.07 A. 09L B LOL c 90L Dd. 10L,yee CHEMISTRY UNIT 3: SMARTSTUDY® VOR THE MID-YEAR RXAM Question 1.2.6 0.40 g of sodium hydroxide was weighed and dissolved in 15.0 ml. of water in a conical flask, The solution was Jater titrated with 0.50 M hydrochloric acid. The endpoint was detected when 19.5 mL of acid had been added. The yalue 19.5 mL was less than the expected 20.0 mL. ‘This difference could be explained if |A. the burette had been rinsed with water prior to adding the hydrochloric acid solution B. the equivalence point was reached before the endpoint. ‘C. _ the sodium hydroxide solution had been left exposed to the air for a long period of time before the titration was performed. D. the conical flask contained 25.0 mL of water instead of 15.0 mL. Questions 1.2.7 and 1.2.8 refer to the following information. ‘Consider the following equation, 2HCI(ag) + Ba(OH),(aq) > BaCl(aq) + 2H,0(1) During a titration experiment, the results below were obtained when a 25.00 mL aliquot of barium hydroxide solution was titrated with a 0.1000 M hydrochloric acid solution. Burette readings (mL) Ist titration 2nd titration 3rd titration final reading 24.53 25.48 25.34 initial reading 1.00 2.01 184 Question 1.2.7 ‘The concentration of the barium hydroxide solution was A. 0.04700 B. 0.04706 M c. 0.09400 D. 0.09412. Question 1.2.8 During the titration, the pH of the solution in the conical flask was recorded. Which of the following graphs shows the expected result for this experiment? AL B. PH my [4 —j}-» bp 15 205 2 25 30 volume of acid added (mL) ‘volume of acid added (mL) . D. Coy pa L_4_+_+> {___}_-» 18 2 2 00 18 20 volume of acid added (mL) Volume of acid arlded (rl)AREA OF STUDY 1 ~ CHEMICAL ANALYSIS Question 1.2.9 30 mL of 0.10 M NaOH is mixed with 20 mL of 0.10 M HCL. ‘The pH of the resulting solution is A 10 B30 Cc. 70 D. 123 Question 1.2.10 How much water must be added to 2.0 L of a solution of a strong acid of pH.2.0 in order to increase the pH to 3.0? A. LOL B. 10L c 18k D. 20L Question 1.2.11 ‘Which one of the following is not a conjugate acid-base pair? A. H,S0,/S0,7 —-B.- HCO; C0," C. OHO D. H,O/0H” Question 1.2.12 In which of the foll6wing compounds does phosphorus have an oxidation number that is different from the oxidation number of phosphorus in the other three compounds? + = AL P4Og B. POs c. PO, D. HPO; Questions 1.2.13 and 1.2.14 refer to the following information, 10.0 mL of a 0.0250 M nitric acid solution was added to a 250 mL standard flask, and the volume was made up to 250.0 mL. with distilled water. Question 1.2.13 ‘The pH of the resultant solution would be A. 10% B. 107 c 3 DS ‘Question 1.2.14 The hydroxide ion concentration in the resultant solution would be A. 10°M B. 10M c. 10M DIM ‘Question 1.2.15 ‘The hypochlorite ion, OCI’, can be oxidised or reduced. Which one of the following could result when OCT is reduced? A. ClO, B. HCIO, c Clog D. CIBr Question 1.2.16 A 10.00 mL pipette delivers a volume of 10.00 mL plus or minus A. 0.001 mL. B. 0.01 mL. Cc 0.10 mL. D. 1.00 mL