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XvPhysics Chapter# 11 Pagot3
11.1 _ | Caloric Theory. 0s
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XiuPhysios Chaptort 11 Paget 4
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Q. Why C,>C, 7 Explain
Prove tat the difference of Molar specific heat enpacity a constant
11.27 | pressure and at constant volume 's equal to the universal gas] 17
constant.
11.28 | For a monoatomie gas prove that, C, 3 R and Cp= 3 R. 18
11.29 | Work Done in Thermodynamics. [9
11.30 | Thermodynamics. wv
[11.31 | First Law of Thermodynamics, 19
11.32. | Sign Conversions. 2»
11,33 | Isolated System. 20
11.34 | Cyclic Process. 20
11.35 _| Applications of the First Law of Thermodynamics 20
11.36 | Second Law of Thermodynamics. 23
11.37 | Kelvin's Statement. 23
11.38 | Clausius Statement, ’ 24
11.39 _| Equivalence of Kelvin and Clauaiul Si. 24
11.40 | Camot Engine, 24
1141 | Camot Cycle. 24
11.42 _| Efficiency of Enging® 25
11.43 | Theoretical liit of Efficiency of Carnot Engine. 26
11.44 | Entropy. 26
11.45 | Questions from Past Papers. 27
11.46 | Solved Numericals of Book. 30
11.47 | Solved Numericals of Papers. 38
11.48 | Numericals for self practice from past papers 39
11.49 | MCQs of Papers. 41
11.50. | Multiple Choice Questions (For Self Practice) “a
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HEAT
11.1- Caloric Theory:
In order to explain the nature of heat, in the beginning of nineteenth century a
famous scientist Calorie presented the theory called as Caloric Theory. According to
this theory “Heat is present in every material body in the form of a hypothetical
weight less fluid called Caloric”. Further if there is no transfer of heat takes place from
the material body then the amount of caloric remains constant in the body. Difference of
temperature between the bodies was assumed to be due to the presence of different
amounts of caloric.
The reason of acceptance of caloric theory was its successful explanation of heat
transfer, such as conduction and convection.
Drawbacks of Caloric Theory:
One of the main problem with the caloric theory was its unability to explain the
heat generated by the friction, which was first noticed by Gounb>Rumford. Later on
when it was proved that the sun-rays reaches the carth after-traveling through space and
not through the material medium, caloric theory could.not explain this way of heat
transfer which is called as Radiation. Hencé caloric theoty was rejected
11.2- Internal Energy:
Internal energy is the energy contained ifa Body. It is the sum of all types of
energies possessed by a body. For a mono al6tnje. or on ideal gas Microscopically it is
defined as the sum of Translatory Kinetic energies of molecules.
11.3- Heat Energy:
Heat is that internal energy whieh transfers from one object to another object
due to the temperature difference bebween them. It is the energy in transit. Once the
energy is transferred to a body then it Becomes internal energy of the body.
‘The S.1. unit of heat is Joule
11.4 Temperature;
The measure of tie degree of hotness or coldness of a body is called Temperature.
‘Temperature is the property which determines the direction of flow of heat when two bodies
are brought in thetmal contact with each other. Microscopically temperature is defined as,
“the average of Translatory Kinetic Energy of molecules.”
11.5-Relation between Celsius and Fahrenheit Scales:
at‘ consider that both Celsius thermometer
and Fahrenheit thermometer are dipped in the same
water bath placed at the room temperature, as shown in
the figure. The final and initial points in Celsius
thermometer are labelled as A and B, and that are in the
Fahrenheit thermometer as A’ and B' respectively,
where as the mercury level in both are labelled as C and
C.. As the mercury level in both the tis will tise
to the same height, therefore,the ratio of mercury level
raised in the Celsius thermometer to the total height of
mercury level is equal to the ratio of mercury level
raised in the Fahrenheit thermometer to the total height
of mercury level, mathematically.
XiLPhysics Chaptert 11 Pages 5