168. 167, 168. 169. following compounds yields °X’ on hydrolysis 7 (2004) 1) CH,CO,C,H, 2) ,H,0-6,4, 3) CH;CHO. 4) Ch,-cl, = GH Identify A and 6 in the following reactions, 410 sc, H,0n MB we (20088) A)A= CH, B= C,H, 2)A=C,H,Cl B= CH, SVA= CH; 4YA= C,H,Cl;, B= C,H,Cl In which of the following reactions the product is. fan ether? (2005) 41)G4H, + CH,COO! anhydrous AICI, 2)C,H,Cl+ aq. KOH A 3),,H, + C,H,COCI anhydrous AICI, 4) GH,Cl + C,H,0Ne Which of the following compoune's is the reactant in Rosenmund's reaction? (20088) 3 1) CH,COOH 2) CH,CHO 3),CH,CH,C! 4) CH,cocl ‘S¢hydroxy butanal is formed when (X) resets with (¥) in dilute (2) solution. What are X,Y and 2? (2005) 4) CH,cHO (cHy,co “NaOH 2) CH,CHO HCHO Nac! 3) (CH),CO (CH,,Co, Hot 4) CH,CHO CH.CHO NaOH ~S> x) The 174, 48 176. HCHO 5 ¢ 8 Sy ano) x x 1) C,H,0H oH, 2) CH,COOH (CH,co),0 3) CH,COOH ch,cooch, 4)0,H,0H cH,COoH Match the following lists (2005m) List - List - A) Ethylene 41) Natalite 2B) Acetylene 2) Preservative ©) Ethanol 3) Hawker’ lamp, D) Diethyl ether 4) Org answer is A 8B cp 14 3 2 1 24 3 1 2 Dhrioan vt Sete 932 1 4 'A compound X undergoes reaction with LiAIH, to yield ¥. When vapours of ¥ are passed over freshly Feduced copper at 300°C, X is formed what is ¥? (z00sm) 4) ch,coch, 2) CH CHO 3) CH,CH,OH 4) CH,-0-cH, Consider the following reaction C,HiOK +C,Hjl +X (Pleasant smelting liquia) which of the following reagents converts ethyl bromide to X? 470. In the reaction ¢,§,0H th Faso CHM wi aust Na a io ne s008R 1) Sodium: 2) Dry silver oxide 16,0 Hes & a * 3) Ethyl chloride 4) Dry silver powder 1 Cy ) CH 177. What are the reagent and reaction conditions used CHO 4) C,H, for converting ethyl chloride to ethyinitrite (as the 171. Which of the folowing compounds i tole jn major proguet)? benzene but almost insoluble in water? (a0nem) (20088) 4) KNO,,C,H,OH,H,0. a 1)¢,410H 2) CH,COOH mranol cite 9) CH,CHO 4) HNO, piisiov 172. Which ofthe folowing i obtained in acarbylamine reaction (2005M) 4) AgNO,, C,H,OH, H,0, 4 1). HN, 2) coc, 178. which of the following reagents converts both seek Revise acetaldehyde and acetone fo alkanes? 173, Identify X and Y in the following sequence of (apes 1) NiH, 2) UAH, 2) 1,NaoH 4) Zn-igleon HCI ERMCET CHEMISTRY VOLAT eT 73, ORGANIC CHEMISTRY179. Which of the following can give a Grignard reagent | 184. Which of the following forms an ester when treated when reacts with magnesium in dry ether? with ethy! alcohol (206m (2006m) yea, 2) C,H,c1 4) HNO, 2) Soci, 3)0,4,0H 4) C,H,CN 3) Con. H,S0/140% 4) PCI, 180: Match the following lists. 185. Which ofthe folowing is formed when the product ahi tia Of exidation of .. treated with ethyl alcoho? ‘Avalkcanes 1) Molassis eal ies Pao GHC 2) ethyl carbonate 3) Chioral hydrate 4) @hloral ©) ceniaelib 186. Which of the following compounds can give lodaform test? Dy Ethy"aloonOr” 4) Wurtz reaction (206m) 5) /Aldol'condensation 1) Formaldehyde 2)\Aeetaldenyde (206m 3) Diethyl ketone 4) Diethy! ether The correct answer is 187. What regent is used in Rosenmund's reduction? A 8 @ Do (206m) 4 % 2? 1 1) HyPe-Baso, 23 @ 52 5 2) ual, 3 2 8 ap008% “4 3) NH{WHYKOH/CH,OH'CH,0H a5 2 3 ae 4p 2mHgincl 181; The reagents afd the reaction‘ contitions Used: IniWhiichof the tollowing’ reactions ethylene is inthe: formation of benzene diazomium chloride ‘orn fom aniline are pil bat 1VO}H,OH a! HSO, o°c 1) Aq. NaNO,, HCl, 25°C aflinghiconliago, 1700 2),Dil. HCL; 0-8%C « CAE 3) Aq. NaCl, HC!, 20% SERB zn Na 4)Aq, NaNO,, HC}, 0-50 -4YIC,H,OH, cont HiS0,, 170%: 182 te wich abe flving reacoce iyaibiraee | "2: Sie Ses Cuatro *ibiiein : (2008) 1)iCH{COOH + Na: 1) C\H.NO, + Zn/KOH 2)(CH,COOH + NaHCO, 2) G\H.NO, + Zn/NH,Cl 3)(CH,COOH + NaOH 3) C,H,NO, + LIAIH, 4)CH,COOH + H,0. 4) C,H,NO, + 2n/Hicl 183. nc af te tooning reactions ety ehode | 0 When ot he towing eagnt when ead wih (0dnesy (2006) 1)Aq. KOH 2) Zain! Diets deh ror 3 3) Alcoholic KOH 4) HI 2)C,H,0.G,H, + CH,COC] 40, 4191. Which of the following is added to chloroform to ‘slow down its aerial oxidation in presence of ight? 3) 4,004, + Cl, (2008) 4) C,H,OH+ PCI, => | 1) Carbonyl chloride 2) Ethyl alcoho! ‘TS ORGANIC CHEMISTRY [go] ACE CHEMISTRY VOL3) Sodium hydroxide 4) Nitric acid 4192. Which of the products formed when acetone is reacted with.barium hydroxide solution? (2008) cn, @ 4) CHs-C=CHy- C -CHy on 2) CH - C-CH-CH- CH, 4) Cs -C-CH2CH=CH, on on on 4 Cly= C~ C-CHy ch, ch, 193. When Acetaldenyde is heated with solution, @ red precipitate is formed, Whi following is that? (2008) 1) Cu, 2)cu 3),Cu0 4) CuSO, 4194, Match the following List (2008) List - A) Grignard reagent 8) Clemmenson reduction ©) Rosenmund’s reduction 1D) Wolf-Kishner reduction ust 2 1) HJP4-BasO, 2) N,HJKOHICH,OH - CHOH 3) CHMox 4) Zn-Hgleon. HCl 5) WYN a . Bong D 3 oie 1 a8 eal 2 a 2 1 oo 5 45 3 eee 1 195. Which of the following compounds when heated CHEMISTRY with@o at-150°C and 500 atm. pressure in ‘presence of BF, forms ethyl propionate? (2008) 1).0,H,0H 3) G3H-0-C.H, 198. When compound 2) CH,OCH, 4) CH,-0-C,H, is oxidised by acidified K,0,0,, compound '''s formed..Compouond 'y is.on eduction with LIAIH, giv respectively are x. and’ (2096) £3) OiH,0H, GH,COCH, 4) CHySHO, CHEGEH, 497. sodium ethoxide to form n of the following reaction also.yields A? (2008) 4) 0)H,61, KOH (ale), A 22) 20,H,0H, con. H,S0,, 140°C 8) CjH,C1, Mg (ary ether) 4) C,H, di. H,80,, H9S0, 198. CH;CH,OH —2->CH;CHO —44C1,CCHO Swot In the above reactions the role of Ci, in Step-1 ‘and Step-2 respectively are (2008) 4) Oxidation, chlorination 2) Reduction, chlorination 3) Oxidation, addition 44) Reduction, substitution 499. Identify ‘B’ in the following reaction CH=CH, +HCI_240._, A+2(H] Gar BHC! (2007) cH, 2CH, acyl 4)C,H,0H 200. Ca0CI,+H,0 ->Ca(OH), +X X+CH,CHO >Y Y+Ca(OH), > CHCl, What is ‘Y'? (20078) 4)CH,CH(OH), 2) CH, Cl, 7