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    OTHER COMPETITIVE EXAMINATION QUESTIONS. 4. A spontaneous change is one in which the system suffers (1) ‘€' increases (2) H’ decreases (3) "© decreases (4) 'H’ decreases 2. H,0(0) > H,0(v), AS Is (1)increases. (2) decreases (3) nochange (4) either't or 2 In which “as” is decreases (1) Crystallisation of sucrose from its solution (2) Dissolving of sucrose in water (3) Melting of ice (4) Sublimation of camphor For the precipitation reaction of Ag* fons with NaCl, which is true (1) an =0 (2) AG=0 (3) AG=-ve (4) AG=aH 5. If AH.<0 and AS<0, then the reaction is, at all temperatures (1) spontaneous (2) non-spontaneous (3) either 1 or 2 (4) Won't takes place 6. At absolute zero, the entropy of a crystal is zero, this is (1) Zero th Law (2) 1st Law (3) 2nd Law (4) 3rd Law AS is maximum for 7. (1) Cag) +5009 Ca. (2) CaCOy,, + CaO.) + CO;:) (8) Coy + Org) 7 COre (4) Naxgy * Qxxg) > 2NO) At 30°C, if AW >Qand AS>0 fora non- spontaneous reaction, for the convertion into spontaneous, by (1) decreasing of temp (2) increase of temp (3) temp. should be constant (4) not possible 9. Which state have minimum randomness (1) steam water (2) liquid water (3) crystal ice (4) all (2) AH =4ve,AS=-ve AH < TAS: (3) "AH 24¥e, AS = +e" and ‘An S TAS (4) AH =4ve,AS = +e, AH > TAS |. The enthalpy and entropy change, for 2 reaction are -2.5 x 10° cal and 7.4 cal deg" respectively: At 298K, reaction is (1) non-spontaneous,... (2) spontaneous (3) equilibrium...» (4)irreversible KEY A909 Mw Org! gs gy 4 24 9 1 82 1) 2 31 64 ‘Sp 08) SOLUTIONS = LEVEL - tl 1. A spontaneous change is one in which ‘E* decreases. Hence (3) is correct choics 2. H,O(I) + H,O(y). for this system asincreases. Hence (1) is correct choice. 3. In the process of crystallisation of sucrose from its solutions. ss value decreases. Hence (1) is correct choice. 4. For precipitation of Ag* lons with NaCl, AG ="- ve, Hence (3) is correct choice. 5, if AH<0&S<0, then’that reaction is ‘spontaneous. Hence (1) is correct choice. 6. “At absolute zero, the entropy of a crystal is zero’ is the third law of thermodynamics. Hence (4) is correct choice. 7. If an=0, then As is maximum for the given reactions. Hence (4) is correct choice. 8. By icnreasing temperature non spontaneous reaction is changes to spontaneous. Hence (2) is correct choice. 9. Crystal ice is having minimum randomness. Hence (3) is correct choice. ‘AHand ASare ve and AH NHOH HCI Hence (1) is correct choice. which is true for the spontaneous reaction | 11. (2) is correct choice. (1) AH and as are +ve and AH aH (1) zero @) te $ ee ial eae eee (3) ve (4) negative or zero (ag ees anes 12. Which of the following processes is not 2. For the combustion of gasoline (C,H,,) in an accompanied by increase of entropy? ‘automobile, the signs Of 477, AS! and AG wilbe (1) dissolution of NH,CI in water (4-4 2-4, 2) burning of rocket fuel 9 $4.3, @) tts (3) sublimation of dry. ice 3. Which of the following pair contain only (4) condensing. steam, extensive properties: 13. Which of the following conditions is not {1 Ent, retractive indo favourable for the feasibility of a process? (2) Volume, temperature (3) Enthalpy, volume (1) “AH =—ve, TAS and TAS AH 4. The value of As for the process (3) AH =-We, TAS = +ve and AH =TAS H,0(s)—> H,0(}) at tatm pressure and 260K (4) AH =+ve,TAS = ve and AH > TAS is greater than zero. The value of AG will be 14. In which of the following cases, the reaction (1) >0 (2) <0 is spontaneous at all temperatures? (3) 0 (4) lies between —1 and 0 (1) AH >0, AS >0 (2) AH <0, a5 >0 5. The physical significance of free energy change can be defined by the relation (8) AH<0, AS <0 (4) AH >0, AS <0 16. When potassium chloride is dissolved in water 1) -aG= 2) W, (1) AG Tag. 21g: ~ (1) Entropy increases (3) -AG=Pav—W,,, (2) Entropy decreases laoen te 8 Entropy ieroad then decreases 8. The correct relationship between free energy i ma ‘ change and equilibrium constant (K) is 16. According to third law of thermodynamics, the entrophy of crystalline substances at absolute (1) AG=RTIogK (2) AG? = RT tog K zero is taken as (1)Maximum (2) Zero (9) 40° =-er in x (a) AG= 23031084 (8) Minimum T (4) Different for different substances Which of the following is not an’intensive | 17, When a solid is converted directly into Property? gaseous state, the process is called (1) Entropy (2) Pressure Sublimation.. The entropy change during the (3) Temperature (4) Molar volume Process is 8. If temperature remains constant during the (1) zer0 (2) negative process, it is called an (3) positive (4) may be negative or zero (1) Isothermal process 18. Which of the following processes is (2) Adiabatic process ‘accompanied by decrease in entropy? (3) Isobaric process (1) Evaporation of water (4) Isochoric process (2) Sublimation of dry ice 8. The entropy of the universe (3) Metting of ice (1) tends towards @ maximum (4) Codensing steam * (2) tends towards @ minimum 19. A spontaneous change is one in which the (3) tends to be zero system suffers, (aj rarnaine'Gonaiant (1) Increase in internal energy 6. THERMODYNAMICS: 302] ‘EAMCET CHEMISTRY VOL. 24. 22. 23. 24. 26. (2) Lowering of entropy \, 3 (3) Lowering of free energy (3) always > 0 (4) 3RT (4) No energy change : ). For an equilibrium state, Consider the reaction (1) a>0 (2) aG>0 2C,Hiy(w)+250,(g) > 16CO4(g) #181102) (3) aH=Tas (4) AH >TAS The signs of AH,AS and AG f0F the above ‘The standard free energy change ( 4G’) is reaction would be ‘ related to equilibrium constant (K) as Eka ; c sau (1) aG® = -2.303 RT In K 30. Which of the, following set.contain only all 2) AG = 2.903 RT tog K extensive or intensive properties? Le oa (1) Volume, enthalpy, vapour pressure (3) aG® = -2.303 RT log K (2) Viscosity, surface tension, heat capacity {3) Energy, heat capacity, volume (4) ac? = RI (4) ag’ T log K (4) Refractive index, surface area, dielectric The units of entropy are constant we (1) J mor" (2) JK" mot" 31. Which of the folldwing ‘Statements is false? (3) Jo" (4) JK mot" (1) Work is a state function In an electrochemical cell, if € is the emf of (2) Temperature is a state function the cell.involving n mole of electrons, then (3) Change in the state is completely defined ac? is (4) Work appears at the boundary of the system és Hi : 32. The total entropy change for a system and Its (1) AG? = nFE*'” (2) \sG? = nFE" surroundings increases, if the process is nk. (1) reversible (2) irreversible AG? (3) E&=nFaG* (4) PE (3) exothermic (4) endothermic 33. ‘The change in entropy of an ideal gas during For a spontaneous endothermic reaction see rene iecthental ekpenesn ta (1) aG>0 (2) G=0 (1) negative (2) positive ‘AH (3) zero (4) infinite (3) aH <0 (4) Sa 34, For the reaction For the reversible vaporisation of water at 373K 2NH;(g) + CO,(g) «> NH,CONH, + H,0 and 1 atmosphere pressure, AG is equal to Standard Gibbs energy change, aG® at 2 (1) AH as given temperature is 13.6. The value of (3) zero (4) aHIT ‘equilibrium constant is Which of the following properties of a system (12.38 (2) 2.4 x 10° undergoing change at a constant temperature (3) 6.2 x 10° (4) 1.36 x 10° and pressure is a measure of the maximum | 35. In which of the following entropy decreases useful work that the system can do? (1) Temperature of a crystalline sold is raised (1) ag (2) as from 0°K to 120K. 8) se w PP 2 anatica ge etm CO,(s) + CO,(g) + (et iesin ee (8) Aliquid crystalizes into solid (1) AG and aH should be negative (a) Halo) > 2G) 2 : KEY - ASSIGNMENT. (2) aH=aG a fo) 2,-19) 3 28) 1 (3) AG and aH should be positive 2) 3, Mk Bh aed 3) 3 42) 4 21) 3 30) 3 (4) AH

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