QUESTIONS FROM OTHER COMPETITIVE EXAMS Wark the element which displaces three | 42. When cold NaOH reacts with Cl, which of the halogens from their compounds ? following is formed (aFMC) (eHu) (1) Nacio (2) Nnacio, (ye @ 01 (3) Nacio, (4) None (3) Br I 48,, When chiorine is passed over dry slaked time 2. Which of the following arrangement for the three ‘at room temperature, the main reaction products Ci, Br and | when placed in the order is of their increasing electron affinity is correct 7 cése) (cpu) (1) caeio), ">" (@) cach, oH (1) 61, Br, | (2)1, Br, cl () Caoci, (4) cacocly, () Br, Ct (4) 1. Cl Br 44. Fluorine is a stronger oxidising agent than 3. The element which liberates ©, trom water is chlorine in aqueous solution. This is attributed (MPP MT) to many factors except we Qn (Pucen QF @ (1) heat of dissociation 4, Bleaching powder reacts with tow drops of (2) electron affinity dilute H,S0, to give finally (3) heat of hydration (cBse) (4) ionisation potential (1) Chlorine (2) Hypochlorous acid 418. The type of hybrid orbitals used by chlorine atom (3) Calcium oxide (4) Oxygen in ClO, is 8. Br, can be liberated from KBr solution by the om action of 1) sp (2) sp cu) @) sp (4) none (1) lodine solution (2) Chiorine water 16. Which of the following is the strongest acid ? (8) Sodium chloride (4) Potassium iodide oo) 6. The reaction of sodium thiosulphate with |, gives, (4) c10,(0H) (2) cio(oH) (DELHL-PMT) (8) SO(OH), (4) 80,0H), (1) Sodium iodide (2) Sodium suiphite 17. Chlorine acts as a,pleaching agent only in (3) Sodium sulphate (4) Sodium tetrathionate presence of 7. Hydrogen bonding does not play any role in a boiling of (1) Dry air (2) Moisture (armo) (3) Sunlight (4) Pure oxygen (1) NH, (2) H,0 18, Mark the incorrect statement (3) HI (4) 0,H,04 ‘Strong oxidising character is favoured by 8. Which is the most volatile compound (eHu) (DELHI PMT) (1) Low ionisation eneigy of the halogen atom (1) HE @) He! (2) A high hydration energy ofthe gaseous halide (3) HBr @ HI ton 9% Oxidising action increases in the following order. (@) A high electron attinity of the halogen atom (PMT) (4) Low heat of dissociation of the moleculear (1) CleBreter (2) Clei4HF + 0, Hence (3) is correct choice. 4. 2 CaCl, + H,S0, —>CaCl, + CaSO, + 2HOCI 2 HOC S°3Her+ (Oy . Hence (4) is correct choice. 6. +2 KBr > 2KCI + Br, Hence (2) is correct choice. 6..WIp#Na,S,0, —>Na,S,0, + 2Nal Hence (4) is Gérrett choice. 7. There isno hydrogen, bond in ‘HI Hence (3) Is correct choice. Due High ENN. of Fluorine it displaces three 8 nm 12, 13. 14. 15. 18) 47. 18. 18, 2. 23, 24. 25. In HF, H-bond is present._In the remaining "HCI is least mal. wt. compound. Hence (2) is correct choic ‘The order of oxidising action is I< Br Eaocl, + H,0 Hence (3) is correct choic Strong oxidising nature:of fluorine cannot attributed to the factor 1.P. Hence (4) is correct choice. In ClO," hybridisation of Cl is sp Hence (1) is correct choic IO, (OH) i.e. HCI, is strongest acid, Hence (1) is correct choice. Cl, acts as bleaching agent only in the presence of moisture Hence (2) is correct choico, For strong oxidising. agent .P, must. be high Hence (1) is correct choice. HCI Is weak acid among the given. Hence (1) Is correct choice. Because of the absence of empty d-orbital F, ‘cannot show. multiple oxidation states. Hence (1) is the correct choice. HI has highest Widlar"heat of vapourisation due to high molecular weight Hence (4) Is corfect choice, HI can easily looses ‘H’" ion, Hence (4) is the correct choice. With CCl, 1, gives\violet colour. Hence (2) is correct choice. K,Gr,0, + 2HOI > (cone) Hence(4) is correct choice, 6 Ca0Gl, Ca (Cl0,), + 5 CaCl, Hence (3) is the correct choice. ‘{C). GROUP 17 ELEMENTS (via GROUP ELEMENTS) [a0] EAMCET CHEMISTRY VOLASSIGNMENT Number of unpaired electrons and valence jctrons in chlorine respectively are 48: During the reaction of chlorine with alkali the oxidation state of chlorine (1) 181 (2) 387 (1) increases (3) 187 (4) 787 (2) decrease 2. oreo Nolatity. order of halogen i (3h bath -ineraane: a daches oipacrcenmariemeries (ae hahse 0) Foiperge - Wa) Gekosiek 16; Tha gases brated ducig tho laces of £0” Gone olan Seger nea ine usittir Ceoneakie (1) FpCl>Br al, (2) CL>Br,>F,F1, (1) H, & 0, (@)H, & F, (8) l>BrCleF, | (4) CaF SBr1, (3) 0, &F, (4) cannot be electrolysed 4. The bord big wiSOF ISNA ove || 17." For envy wanoprtaton fuori, lie Cooverted than the expected value, This is due to greater into Pe etme || ti cor, (avr sion oF foctng. Te eeeimericn Meee! by || forcin @ cro, roan” wha 14, The MF mount retention tan bo ned : Tamoved by pada Weigh 6. The elomanisthifighestslectanvattty and | (1) KH, (2) Ner Tico eoeianae (cr, (a) car, aed eae sm Tr fea Tega fe oe opel tipi (4) cla F (1) COLF, & (C,F), (2)'(C,F,),& CF,CHCIBr ne raxinur GENCE EAD INEEan be 3) (CFI,8 OARS 4) (OF. CCF, extioted'by a halogen its second excted stato | 20, Hyosonosreniee ecw is 7 oz has (1) HSiF, (2) HSiF, i Je (3) H,SiO, (4) H,SiO, rE he Weleeueeentiantie ape ittd || oy. temtnrs metas cP Metis nittae amperes || 2 oS diva Stevo anon pars oeeoreremaccwey | 1) XC aeecerae 22. Schosle prepare alo forthe fete nto iene ch aaa leboretory by ouing HC! wth nino, (2) Acai Kw, 2 The deseasing ere nding Sena ot |e Reciag nen, 4) com tm halogen lt URN 2a. hoon and Fst sr. than a oabsiety GY IsBrScisF ay CloBrer a (1) Lighter-& lighter (2) Heavier & heavier 9. Iodine molecules:can ‘absorb../light and {2) Hapwlonda toner (6) Liobienidi nearer hora, ak mahietaebactoagen toe &: Bian, Makaeoes ct poeegis {i} Oxoaton fevelon (a) fedveton reagon Bato e seesaw A hae Ee (3) Recon rekon a) deoroprion easton 10: SEONG be ot REELS alae 25. Inthe acon boRtGQl ARGH ol Haees of (1) HF>HCI>HBr>HI (2) HIF HB HCIsHF chlorine the products are ies (NG! 8 Ny (2) Ne& NOL (3) HEPHI>HBHE ta) MFsHIMBe-H 8 Ne 8 NCL, 11, Order othe characte of tycogen hades io |, NSA NHAE! (4) NC, 8H er of Aide terete ase Na 28. Tre hydaien of clone nCleine ote (3) HePHP-HeHF (a) HsHoleHBr=H Ae dean 42, Fluorine reacts with water to give ee oe (1) HF & HOF (2) HF & F,0 errs (4) ese0} C1 annie icaneewas 7 " Hep'v leans geemoeen rome: ee Mae eee hybricisation The C16,C! bond angle is (2) Chiorites & Chiorates (1) 109° 28" (2) 10718" (3) Chlorates & Perchlorate (3) 104°30" (4) 111" oes: 28 The oxidation stato of Fluorine n-OF 6 14. Fluorine reacts with hot, concentrated alkali and (4) -1 (2) +1 cold, dilute alkali to give HF and respectively (3) +3 (4) +4 (OF, £0, Q)0, 8 OF, 28. Chlorine contd Wine ninad dn nj ot (3) 0, 8 0, (4) OF, & OF, (1) HCIO & HCIO, (2) HCIC, & HCI, EAMCET CHEMISTRY VOL. }403] 8(C). GROUP 17 ELEMENTS (via Group ELEMENTS)