PLANT SAFETY AND ENVIRONMENT
bd ied
What you should know about
liquid thermal expansion
Decision flowchart aids in correct thermal relief valve requirements
S. NOROUZI, Sazeh Consultants, Engineering and C
Construc tran;
Tehran
and S. RAHIMI MOFRAD, Petrofac Engineering and Construction, Sharjah, UAE
between process valves may cause limicing effects, bu it
P pe rupture due co thermal expansion of blocked liquid
could produce unaeceprable c
sequences, especially with
dangerous liquids. Most references provide proper guidelines
rding thermal expansion relief valve tequitements; however,
there is no straight forward method to specify when a thermal
relief valve (TRV) is required. Furthermore, in the absence of a
stepswise approach, sometimes the TRY is provided based on the
{uid’s volume or nature (hazardous or flammability} while check
ing thermal expansion's initial requirements has been mistakenly
neglected
TRV requirement. Fg, | js « simple flowchart represent
ing questions regarding decisions for a TRV requirement for
1 specific pipe oF equipment. Equipment refers to any process
volume including differene cypes of heat exchangers, ai cool
crs, vessels and pumps that satisfy the liquid therm
initial requirements. The decision flowchart consists of three
boxes. Box I checks the
ial requirements needed for initiat
thermal expansion, while Box 2 investigates existing safety
measures, design provisions and other alternatives that may be
utilized instead of TRVs. The consequences of equipment/pipe
rupture on human health, safety and environmental aspects,
‘equipment integecy, and economical and operational cost fol~
lowed by ruptures, are reviewed in Box 3. IFany of these con
sequences are nor tolerated, then a TRV should be provided 10,
direct the exeess blocked liquid to the confined volume such as
another vesel or flare network
Each question in the decision flowchart is described below in
greater detail
1. The system is considered completely liquid-flled at 9
greater volume. For a ewo-phase system with ower liquid fraction,
and gas syste
‘can absor’y the increase in liquid volume due co thermal expan-
sion, Small vapor or gas pockets ean disappear upon h
a TRV is nor usually required because existing gas
ig due
0 compression andor solubilization. In contrast, multi-compo-
nent mixtures with a wide boiling range can have suficient vapor
preset rect coming comply iui ile The gd
the sapor pocker volume is sufficient for liquid expansion.!
2. Process plant piping (on-plot piping) is not normally
bMocked in, but storage or trinspore piping sections are regularly
due o heating should be estimated to determine if
shut in during normal operation. This is why few process lines
have TRVs,
ay [1-18 te system competi al of gid?
not | 2 l6the line o equipment normaly blocked in or
operationalemergency purposes?
3.18 the heating system temperature higher than
operating liquid temperature?
ee
4:1 the estimated al pressure lower than the sytem
sin lis?
51s there any other orm of pressure safety device on
Any | proiactod system?
es | 6.15 there any administrative operating procedure, reliable
system ost operator for dang the Hau ator
‘he system is bockoa in?
74s thre any roiion prevrtng tho tight blockage
ofliqia?
4.4 here any weak pont inthe syst where expansion
coud be rived without any major consequence?
—— a —
he igi eta ton oc corrosive?
10s the quid combustible or explosive?
A114 the qu environmentally harm?
10° | 12:1 tne quid highly volte?
13s the pipetequipmentin ries need of sevice from a
plant operation viewpoint?
4.1 he ppe/eqipment size 0 large tat me rupture cost
snot tolerable?
any yes
{TRY nt ote ize eral een Wl oc
TMV eteqe She eng sd rane aie Ket ut
‘gn wi et
TR ett see Ho pe ks axa Home poses
‘Seubert tg rire cree
Exception. Process lin
lower tha
‘or equipmene that handle fluids
ambient temperature are exceptions, In this case
the answer to question ewo is yes, whether liquid blockage is
normally done or no(sn, ote (in, toe)
——$$_h— >_>
¥ Ded Cosad vale ye 3-ay wae
Ded Chock valve Pe Open vale
fd ate valve
3. The heat source can be internal or external. An internal
ing coil, heat
ing jacket, heat tracing, sole radiation, radiation ftom flares and
ambient temperature are external heating sources. Unlike steam
and hot fluid tracing, electrical tracing isnot considered a heating
heat source is usually a chemical reaction. A be
ce the temperature is maintained by a control system,
The maximum temperature expected from solar heating is usu
ally about 60°C-70°C. A'TRY is not required if fuid temperacure
is greater than heat so
liquid wich relatively high operating temp
keep its temperature instead of he:
increase the metal surface temperature to a muuch higher tempera-
cure depending on flare gas flowrate, dist
External fire is not considered a heat source ifthermal expan-
sion is studied fora system consisting of only pipes. The fire case
is a heat source if the system includes liquid-Full equipment. In
this cas, ifthe liquid’ initial boiling point at
is lower than the fie temperature, an external fice leads to three
sid thermal expansion, owo-phase relieving and vapor
re caxe—liquid vaporization). From a pressure safety
temperature, This is because blocked
re tends to cool or
g. Flare heat radiation can
ice from» the flare and
eving pressure
valve (PSV) sizing viewpoint, a PSY sized for the vapor relieving,
stage is adequate because the first two stages are short transient
periods. If the fils boiling point is very high, the relief device
should be sized only for thermal expansio
4, Inestimating pressure rise duc to thermal expansion, equa:
tions recommended in API-521 section 5.14.4.1! are used. The
API relation needs many design parameters, If parametets are
tunknoven, the allowing simplified equation may be utilized:
aut, -1)
P=P
a
@
When calculating final pressure, the fi
be known, The heating source temperature can be considered the
final emperature. Generally. TRV will pop up long before liquid
temperature reaches the source temperarure. In other words, a
5°C-10°C increase in liquid cemperauure is suflieient to increase
nal emperature needs to
the pressure from operating to design pressure, For example, the
3 | movemmen 2008 \*voROCAABON mOESSING
PLANT SAFETY AND ENVIRONMENT
ise about 4 bats for each 1°C increase in water
blocked in eemperature at 20°C as per Eq, 3 caleulation:
aixo “(14
ange fc) _ sale
a ce!
5. The roquited relief rate due to liquid thermal expansion
is very small, so if another pressure safety device is provided to
protect the system fom any other emergency ease, it will relieve
the presse by pop-up actin.
‘the liquid trapped between block valves isa nor
mal practice done by the operator within the process pl
a TRY is nor normally provided for on-plot piping, If there is
any specific requirement for liquid draining, it should be clearly
mencioned in shutdown or maintenance procedures. Draining
10% liquid volume is enough co prevent thermal expansion
Conversely, storage area piping oF liquid transport lines (off-plot
piping) due to the operation «ype ane! accessibility imitation are
regularly blocked in without liquid draining. Uslizing lock-open
(LO) valves can be considered a reliable preventive device since
this valve type is locked in the open postion during operation and,