CONFIDENTIAL ASIJUN 2018/CHM412, UNIVERSITI TEKNOLOGI MARA FINAL EXAMINATION COURSE : ORGANIC CHEMISTRY FOR TECHNOLOGY ‘COURSE CODE : CHM412 EXAMINATION : JUNE 2018 TIME : 2HOURS INSTRUCTIONS TO CANDIDATES 1 2. 3 This question paper consists of eight (8) questions. Answer ALL questions in the Answer Booklet. Start each answer on a new page. Do not bring any material into the examination room unless permission is given by the invigitator. Please check to make sure that this examination pack consists of i) the Question Paper ii) An Answer Booklet — provided by the Faculty ‘Answer ALL questions in English. DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO SO This examination paper consists of 7 printed pages © Hak Cipta Universiti Teknologi MARA CONFIDENTIAL,CONFIDENTIAL 2 QUESTION 1 Draw the structural formula for each of the following compounds. a) 3,5-dimethylhepta-2,4-diene b) p-dinitrobenzene ©) cyclohexane-1,3-dione d) N,N,3,4-tetramethylhexanamide e) 3-oxopentadioic acid QUESTION 2 Write a correct IUPAC name for the following compounds. a) cl ‘el b) 9° oot H c) OH ) Tor ° ° © Hak Cipta Universiti Teknologi MARA ASIJUN 2018/CHM412 (2 marks) (2 marks) (2 marks) (2 marks) (2 marks) (2 marks) (2 marks) (2 marks) (2 marks) CONFIDENTIALCONFIDENTIAL 3 ASIJUN 2018/CHM412 e) 9 0 oo (2 marks) QUESTION 3 a) Consider the following organic compounds A and B. OH ° A B i) Which of the compounds above will have the higher boiling point? Explain your answer. li) Suggest a simple chemical test with the observations that can be used to differentiate between A and B. (4 marks) b) Predict the solubility in water of the following compounds. Write your answer as soluble or insoluble. __| Cyclohexanol_ Propanone. (2 marks) ©) State the intermolecular force responsible for the boiling point in the following liquids: Ethanol i) Ammonia Hexane iv) Bromobutane (4 marks) (© Hak Cipta Universiti Teknologi MARA. CONFIDENTIAL