Tutorial #14 – Group 2 elements

1. Describe and explain the trend in atomic radii down Group 2

2. Water was gradually added to a Group II metal oxide and a white solid X was formed. X
is slightly soluble in water and is used in agriculture.
a. Identify X
b. Predict the pH of a solution of X in water
c. Explain why X is used in agriculture

3. The Group II elements all burn fiercely in oxygen

a. Describe the trend in reactivity down Group II when the elements burn in oxygen
b. Explain the observed trend in reactivity in terms of ionization energies
c. Write a balanced equation for the reaction when magnesium burns in oxygen
d. Using your equation from (c) and oxidation states, identify the oxidation state changes
which take place in this reaction. Identify which element is oxidized and which is
reduced. Give reasons for your answer.

4. (i) Explain what is meant by the terms lattice enthalpy and enthalpy change of hydration
(ii) Describe the trend in the solubility of the Group II sulphates
(iii) Explain this trend in terms of lattice enthalpy and enthalpy change of hydration