| CR, test cope 02112020 } FORM TP 2007172 /MAYIJUNE 2007 CARIBBEAN EXAMINATIONS COUNCIL (CHEMISTRY UNIT 1- PAPER 02 2 hours 30 minutes READ THE FOLLOWING INSTRUCTIONS CAREFULLY | 1. this paper consists of SEX compulsory questions in TWO sections 2 Section A consists of THREE structured questions, ONE from each Module Section B consists of THREE extended response questions, ONE from each Module. t 3, For Section A, write your answers in the spaces provided in this booklet For Section B, write your answers in the separate answer booklet provided. 4. ALL working MUST be shown, 5. The use ofnon-programmabie ealeulators is pemited. 6. _Adata booklet is provided, ‘Copyright © 2006 Caribbean Examinations Counell @ ‘All sights reserved, e21120201CAPEF 2007SECTIONA Answer ALL questions in this section, Write your answer in the spaces provided in this booklet. MODULE 1 FUNDAMENTALS IN CHEMISTRY ‘Hles's law states thatthe total energy change in a reaction ‘rom reactants to products if the initial and final conditions se identical, lemperaure and pressure Given the following dats: Mg() + 2H'G@q) > MaM(eq) + Hy®) aH = si. MgO(s) + 2H (aq) > Me™ (aq) + HOG) AH = ~ 151.1 2G) + Os) > 28,068) AH = 483.610 ‘Use Hess's law to calculate the enthalpy change for the following reaction: Me @) + 0,8) > 2ME06) [3 marks] ‘A student caries ut an experiment to determine the enthalpy change of the reaction ‘between magnesium and hydrochloric acid. She measures the steady temperature of 100/em’ of hydrochloric aid in a polystyrene cup. Sho then places a 10 cm long piece of| ‘magnesivm, of mass 0.5971 g, in the aid and records the temperature every 30 seconds or minutes, while string at regular intervals. (@) plain the reason for strsing the mixture at regular intervals Timark] GO ON TO THE NEXT PAGEwo Given that the initial and final temperatures are 28°C and 57°C respectively sketch 4 (ical graph for the results ofthe experiment to illustrate how the student strived atthe temperature change, T, forthe experiment. [2 marks) Gil) Give the main source of error forthe experiment. ee ~ famed GO ON TO THE NEXT PAGE