va Resonence Educating for better tomorrow TARGET : JEE (Main + Advanced) 2017 | —bany Practice ProsLems Course : VIKAAS (JA) Date : 21-12-2015 NO. 51 & 52 TEST INFORMATION DATE : 00.00.0000 Syllabus :_ (All Cheminfos and Handouts till date) This DPP is to be discussed in the week (21-12-2015 to 26-12-2015) DPP No. #51 (JEE-ADVANCED) Total Marks : 61 Max. Time : 40 min. Single choice Objective ('-1" negative marking) Q.1 to 6 (3 marks, 2 min.) __[09, 06] Multiple choice objective ('-1" negative marking) Q.7 to Q.12 (4 marks, 2 min.) __[16, 08] Comprehension ('-1' negative marking) Q.13 to Q.15 (3 marks, 2 min.) [12, 08] Single Integer type Questions ('-1" negative marking) Q.16 to 17 (4 marks 3 min.) 16, 12) Double Integer type Questions ('-1" negative marking) 0.18 (4 marks 3 min.) 16, 12] ques.no. [1] 2]3]4]5]6][7] 8 | 9 | 10] 11] 12] 13] 14] 15] 16] 17] 18] Total Mark obtained 1. Which of the following option is correct, (A) When a liquid and its vapour are at equilibrium and the pressure is suddenly increased, cooling occurs. ®)N,@) + 0,@) > 2NOG)-Heat; the equilibrium shifts in backward direction on increasing the temperature. (C) Vapour pressure of particular liquid at a particular temperature depends upon surface area of liquid exposed. (0*) None of these fre a a wat feos aise & (A) 9a ga a gat am aren A Ba, stare aa age wR hte eT TT # (©) N,G) + 0,0) = 2NO(@)-Se awa agry oe AP, ea fe A cere eh | (©) a are wR Pata 2a a ATE ara GS gy aa STS daw wT PH we eT CO) A 8 OE ae Sol. (A) Due to condensation of vapour , heat is liberated. (A) ae 8 sors F om, Go yaa et #1 Sol. (B) Reaction goes in forward direction. (@) sath sen Fen H errata eet & | 2 For the reaction PCI5(g) ==> PCl,(g) + Cl,(g) ; AH = +ve, taking place in a closed container, initially starting with only PC, the value of observed vapour density at equilibrium with decrease in temperature (A) Decreases (8) Increases (C) Remains constant (O) First decreases, then increases Resonance Educating for better tomorrowSol Sol. Sol. PCI(Q) + Cl,(Q); AH= +ve, 3 WH de ors A Ber GHA B| BHAT a bas, PCLyzt fra core & | ra arora Ae ob er ae oe RT aTOT ae AI ae) Aa @) He (©) Pram vert & (©) ed BA ven fe a As temperature is decreased, the equilibrium will sift in backward direction according to Le-Chatelier's (Ory principle, leading to an decrease in value of « (degree of dissociation). Now, (V.D.)aps = 4..." 50, as « decreases, (V.D.)x,, increases. arr Hat ret, ata fears B ogee, ae re Fer Pen eh 8, geo (Rabo = Ar) 4 fw art, ort (VD), = Wear et, cH AS AT (VD)yy, HT ae ar 21 3 A monoatomic ideal gas (C,= 5 R) is allowed to expand adiabatically and reversibly from initial volume of 8 Lat 300K toa volume of V, at 250 K. V, is : (Given (4.8)'2= 2.2) 3 , work done in (b) process () Work done in (b) process > work done in (a) process, (©) Work done in (b) process = work done in (a) process (©) Work done in both processes cannot be compared ve he at Pet @h ull @ onrreet V, AV, re eR Pr ae & (RIL RW aa 8) (FAV, 8 2V, 210 sapere sae aU Fb sen ae fb 2V, & AV, a1 Gane wT Te cpr sort Pre aa | (0) 1831 V, 8 2V, ap Samet hon rN a Gee Apa cM be 2V, spr sort fre aa | aa fr a ate ors ae (Ae) sae (a) 3 far me ar > sa (b) fran are a (8) aH (b) 4 oar ara apd > waPH (@) A Per a rE (C) aH (b) 4 fee ae ord = ae (a) 4 fen va wr (0) ai aoe & fA a oe a geen TE a oT a ay, 3 sorta aera aSol. ‘One mole of an ideal monatomic gas is caused to go through the cycle shown in figure, Then the change in the internal energy of gas from a to b and bto cis respectively ww Germ oreet te ar 4 the, fers A aa a cw agUTe ToT et Saw b aon ba od ager saraftes Gat % oad are: ae 2 PV. 9P.Vo 15P.Vo, 15P.Vo, =F .6RT, = BF .1ORT, =) FORT, ) 9. 10RT,, 4, W, AE and AH for the following process ABCD on an ideal monoatomic gas are we sree Treads te oe fret aA ABCD & fey gq, W, AE cen AH mare: fT Isothermal c Ve ON, AV, 2P,V,In 2, =P,V,In2, ()W=-2P,V,in2, ()W=-2P,V,(F+In2, g=2P,V,In2 AtAand D the temperatures of the gas will be equal, so Aa Ba fe or ary aay er ort AE=0, AH=0 Now ara w= Wy, + Wa. + We, and weg = -W=2P, V, In2 =P,V,—2P,V, In2 +P, V, =-2P, V, In2 Identity the correct statements) (A) Asolution prepared by dissolving 0.1 mole of H,PO, in 250 mL solution will have [H,PO,] + [H.PO,]+ [HPO,*] + [PO,]= 0.4 M. (B*) Titration curves for the titration of 0.1 M oxalic acid with 0.1 M NaOH and 0.2 M oxalic acid with 0.2 M NaOH both pass through the same pH at the 1st equivalence point. (C*) Solubility of Fe(OH), (K,, = 4 * 10°") in waters less than 4K, /27 {D") The solubility of StF, in water exceeds YK, /4 Resonance Educating for better tomorrow