~. Aaryan International School ANNUAL EXAMINATION (23"February, 2019) | ae ibject: Chemistry ‘Time: 3 Hours | QI: What is the oxidation number of Cr in KyCr0;? (Q2:Arrange B, C, N, O in increasing order of their ionisation enthalpy. Q3:Why does the water boil below 1000 c at higher altitude? 4: What is meant by hydrolysis of salt? Q5:Define limiting reagent Q6:How many electrons in an atom may have the following quantum number? a) n= 4,ms=-1/2 b 0 Q7:Drive the relationship between K. and K,. Q8: Account for the following, a) Ananion is always bigger than its parent atom. b) Chlorine (Cl) have mare negative electron gain enthalpy than fluorine. [Atomic number F=9, CIT] Q9:(a) State Hund’s rule. (b) Draw the shape of dz’orbital. Q10: An orbital has n=3, what are the possible values of | and m? QI1: Balance the following ionic equations by ion-electron method MnO; + S03" + H+ Mn** + SO}- + H,0. Q12:Deseribe the hybridization scheme in case of PCls. Why are the axial bonds longer as compared to equatorial bonds? Q13: Write the molecular orbital configuration of Nz. Calculate its bond order and predict its magnetic behaviour. Q14xa) Define Dalton’s law of partial pressure. (b) Why are half filled and completely filled orbitals more stable? QI5: (a) Write the electronic configuration of Cut ion [2-29] (b) State Aufbau’s principle. Q16: Account for the following a) NF3 is pyramidal while BF; is triangular planar. b) Bond angle in HO is larger than bond angle in H,S. QI7:A hydrocarbon *X’ reacts with 03 followed by Zn and HO gives acetaldehyde and formaldehyde. Identify “X” and write chemical reactions involved. QI8: (a) Explain the following, 1) Sendern’s reaction 2) Friedal — craft acylation (b) Out of benzene and toluene, which will undergo nitration more easily and why? Q19:Complete the following reactions. KMn.04/KOH 1) CH; -CH = CH;——— Bally 2) CH; ~CH = CH,—>20: Explain nitration and sulphonation of benzene. Q21: Calculate the value of the equilibrium constant of following reaction at 295k H2(g) + 12(g) + 2HI (g), OH =+51.88KJmol" S° [H,(g)] = 1306JK"'mol S° [Ix(g)] = 116.73JK"'mol™ 8° [HI(g)] = 206.277K"'mol" (2: Consider the following species. N*, O*, F, Na’, Mg” and AP* 1) What is common in them. 2) Arrange them in the order of increasing ionic radii Q23:What do you understand by the terms. a) Hydrogen economy b) Syngas ) Water-gas shift reaction ) Hydrogenation ‘Section —E (5 Marks Each) Q24:Write the IUPAC of the following, a) HC= € -CH, - CH,OH ¢) CH3 - CH ~ CH; - CH- CH, CH a CH; b) CH;~C-CH-CH)~Cl d) CH; ~ CH - CH ~ CH ~ CH - CH; CH; CH, CH Q25: Explain the following terms. 1) Eutrophication 2) Ozone layer depletion (b) What are the radicals? How are they formed? (26: (a) Draw the staggered and eclipsed conformation of ethane. (b) What is electrophile in sulphonation?