LAMPIRAN

Tabel 1. Standarisasi Na2EDTA nondigesti

Volume Volume Volume
No
Awal (mL) Akhir (mL) Pemakaian (mL)
1 7,6 16,5 8,7
2 16,5 26,4 9,9
Rata-rata 9,3

Tabel 2. Standarisasi Na2EDTA digesti HNO3-H2SO4

Volume Volume Volume
No
Awal (mL) Akhir (mL) Pemakaian (mL)
1 0,0 5,0 5,0
2 5,0 10,7 5,7
Rata-rata 6,0

Tabel 3. Kesadahan Total

Volume Volume Volume
No Keterangan
Awal (mL) Akhir (mL) Pemakaian (mL)
1 Digesti 20,5 36,2 15,7
2 Nondigesti 36,2 45,55 9,35

Tabel 4. Kalsium
Volume Volume Volume
No Keterangan
Awal (mL) Akhir (mL) Pemakaian (mL)
1 Digesti 0,0 5,4 5,4
2 Nondigesti 5,4 5,65 0,25

Perhitungan
1. Pembuatan larutan b. 50mL Borat 0,02 M
a. 50mL NaOH 1M
𝑚𝑎𝑠𝑠𝑎 1000
𝑚𝑎𝑠𝑠𝑎 1000 𝑀= 𝑥
𝑀𝑟 𝑉
𝑀= 𝑥
𝑀𝑟 𝑉
𝑚𝑎𝑠𝑠𝑎 1000
𝑚𝑎𝑠𝑠𝑎 1000 0,02 = 𝑥
0,1 = 𝑥 381 𝑔/𝑚𝑜𝑙 50
40 𝑔/𝑚𝑜𝑙 50
Massa = 2 gram Massa = 3,842 gram
 c. 25mL NaOH 0,1 M
𝑚𝑎𝑠𝑠𝑎 1000
𝑚𝑎𝑠𝑠𝑎 1000 0,01 = 𝑥
100 𝑔/𝑚𝑜𝑙 100
𝑀= 𝑥
𝑀𝑟 𝑉
Massa = 0,1 gram
𝑚𝑎𝑠𝑠𝑎 1000
0,1 = 𝑥
40 𝑔/𝑚𝑜𝑙 25 e. 250mL Na2EDTA 0,01 M
𝑚𝑎𝑠𝑠𝑎 1000
Massa = 0,1 gram 𝑀= 𝑥
𝑀𝑟 𝑉

d. 100mL CaCO3 0,01 M 𝑚𝑎𝑠𝑠𝑎 1000

0,01 = 𝑥
372 𝑔/𝑚𝑜𝑙 250
𝑚𝑎𝑠𝑠𝑎 1000
𝑀= 𝑥
𝑀𝑟 𝑉 Massa = 0,9319 gram

1. Perhitungan Molaritas larutan baku Na2EDTA nondigesti

𝑀 𝐶𝑎𝐶𝑂3 𝑥 𝑉 𝐶𝑎𝐶𝑂3
𝑀 𝐸𝐷𝑇𝐴 = 𝑉 𝐸𝐷𝑇𝐴
0,01 𝑀 𝑥 10 𝑚𝐿
𝑀 𝐸𝐷𝑇𝐴 = 9,3 𝑚𝐿

𝑀 𝐸𝐷𝑇𝐴 = 0,011 M
2. Perhitungan Molaritas larutan baku Na2EDTA nondigesti
𝑀 𝐶𝑎𝐶𝑂3 𝑥 𝑉 𝐶𝑎𝐶𝑂3
𝑀 𝐸𝐷𝑇𝐴 =
𝑉 𝐸𝐷𝑇𝐴
0,01 𝑀 𝑥 10 𝑚𝐿
𝑀 𝐸𝐷𝑇𝐴 = 5,56 𝑚𝐿

𝑀 𝐸𝐷𝑇𝐴 = 0,0179 M

3. Perhitungan nondigesti
a. Kesadahan Total

1000
= 𝑥 𝑉 𝐸𝐷𝑇𝐴 (𝑎)𝑥 𝑀 𝐸𝐷𝑇𝐴 𝑥 100 𝑔/𝑚𝑜𝑙
𝑉𝑠

1000
= 𝑥 9,35 (𝑎)𝑥 0,011 𝑥 100 𝑔/𝑚𝑜𝑙
5𝑚

= 1870 mg CaCO3/L

b. Kalsium

1000
= 𝑥 𝑉 𝐸𝐷𝑇𝐴 (𝑏)𝑥 𝑀 𝐸𝐷𝑇𝐴 𝑥 40 𝑔/𝑚𝑜𝑙
𝑉𝑠
 1000
= 𝑥 0,25 (𝑏)𝑥 0,011 𝑥 40 𝑔/𝑚𝑜𝑙
5 𝑚𝐿

= 220 mg Ca/L

c. Magnesium

1000
= 𝑥 (𝑉 𝐸𝐷𝑇𝐴 (𝑎) − 𝑉 𝐸𝐷𝑇𝐴 (𝑏)𝑥 𝑀 𝐸𝐷𝑇𝐴 𝑥 24,3 𝑔/𝑚𝑜𝑙
𝑉𝑠

1000
= 𝑥 (9,35𝑚𝐿 (𝑎) − 0,25 𝑚𝐿 (𝑏)𝑥 0,011 )𝑀 𝑥 24,3 𝑔/𝑚𝑜𝑙
5 𝑚𝐿

= 486,486 mg Mg/ L

4. Perhitungan Digesti HNO3-H2SO4

a. Kesadahan Total

1000
= 𝑥 𝑉 𝐸𝐷𝑇𝐴 (𝑎)𝑥 𝑀 𝐸𝐷𝑇𝐴 𝑥 100 𝑔/𝑚𝑜𝑙
𝑉𝑠

1000
= 𝑥 15,70 𝑚𝐿 (𝑎)𝑥 0,0179 𝑀 𝑥 100 𝑔/𝑚𝑜𝑙
5 𝑚𝐿

= 5620,6 mg CaCO3/L

b. Kalsium

1000
= 𝑥 𝑉 𝐸𝐷𝑇𝐴 (𝑏)𝑥 𝑀 𝐸𝐷𝑇𝐴 𝑥 40 𝑔/𝑚𝑜𝑙
𝑉𝑠

1000
= 𝑥 5,4 𝑚𝐿 (𝑏)𝑥 0,0179 𝑀 𝑥 40 𝑔/𝑚𝑜𝑙
5 𝑚𝐿

= 773,28 mg Ca/L

c. Magnesium

1000
= 𝑥 (𝑉 𝐸𝐷𝑇𝐴 (𝑎) − 𝑉 𝐸𝐷𝑇𝐴 (𝑏)𝑥 𝑀 𝐸𝐷𝑇𝐴 𝑥 24,3 𝑔/𝑚𝑜𝑙
𝑉𝑠

1000
= 𝑥 (15,7 𝑚𝐿 (𝑎) − 5,4 𝑚𝐿 (𝑏)𝑥 0,0179 𝑀 𝑥 24,3 𝑔/𝑚𝑜𝑙
5 𝑚𝐿

= 896,03 mg Mg/ L
Persamaan Reaksi
 Larutan Standar CaCO3
Ca2+(aq) + EBT(aq)  [Ca-EBT]2+(aq)

 Ca2+(aq) + H2Y2-(aq)  [CaY] 2-(aq) + 2H+(aq)

 Kesadahan Sampel Air

Mg2+(aq) + EBT(aq)  [MgEBT]2+(aq)

 Titrasi
[MgEBT]2+(aq) + H2Y2-(aq)  MgY2-(aq) + 2H+(aq) + EBT(aq)