4-15 pHto precipitate ison Given: Groundwater has 1.800 mg/L Fe and desired concentration is 0.30 mg Solution: From Table 4-2 pKsp = 38.57 for Fe(OH)s Kep = 1077 = 2.69 x 10° o.30me/t. re]=_—_230ms/E___ sg 3710 mole/t (55.85g/mole)(1000 mg/g) Kee = [Fe][OHP lox 2.69x10 \* 5.3710" 01x10)” =7.94%10-" mole/L pOH = -log (7.94x 10) por 14.00- 11.10= 2.90 1.10 and pl 4-18 Fluoride solubility 345x104 F= 1.0 mg/L and Ca Given: Solubility product of C Solution: a, Convert Ca and F to moles/L 200me/L » |=___ 4 00107 mole/L lew] (40.08 g/mole\1000 me/e) a 1LOmg/L (19.00 2/mole)(1000mg/; 3.2610" mole/L ir b. Calculate solubility of F with 200 mg/L of Ca in solution. Kop = [Ca FP Kep = [4.99 x 10°F] =3.45x 10" ¢, Since 8.31 x 10” is greater than 5.26 x 10°, the 1.0 mg/L of F will be soluble. | 345x107 ” 8.3110~ mole/L. 4.99%104-19 Concentrations of Ca and SOs Given: CaSQy solution, addition of 5.00 x 10 M NaySOs, pKsp = 4.31 Solution: a. From Appendix A CaSO, @ Ca* +80," 898 x 10° Kep= 104 = b. Calculate the molar concentrations of Ca™” and SO, at equilibrium [ca*"] = [s04"] = 4.898 x 10°)! = 6.998 x 10° ¢. Set up quadratic equation where [ca (6998x102)-x ko. (6.998x107)+ (s.00x107)-x = (1.200x107)—x Kg = (6.998107 —x).200x107 —x)=4.898%10 (5.308% 10 )-(1.899x107 jk+x? = 4898x107 898x10% =. 89910 +(6.398x10"): ~(.899x10" k +6.s00%10")=0 4, Solve the quadratic equation for roots 1.999107 + x= 3384x107 and x =4.137%107 ¢. Because 3.384 x 107 > 6.998 x 10°, or more than we started with, select x=4.137 8 19 £ The amount of Ca” remaining is [ca] = 6.998 x 10° = 4.137 x 10" The amount of sulfate remaining is [S04] = 6.998 x 10° + 5.00 x 10° — 4.137 x 10° = 7.861 x 10° moleL4-31 Converting from mgiL as CaCO3 to mg/L. Give : Concentrations in mg'L as CaCOs Solution: 2 because HCO; has 2 H’ replaceable) tig. 1000 ai 8 C900 soe) », Ca(OH. (n~ 2 becanse Ca requires 2H for replacement) sig 13.50 iL. a8 C900 €- HPO, (n~ 3 because of 31) 97951 EW, 6650 3 32.6550 50.04 wt ~an.oo mar. ascacos (2282) or46 4.rip0xfn= 2b 6230 EW, 48.4936 96.9872 tig. $1.00 iL a8 C900 era