Bobot PS = 1.

06
Larutan 1% sebanyak = 100ml
0.75%
Vlarutan yang diambil = 𝑥100% hasil 75ml
100%

75ml x 1.06
= hasil 0.795 g/ml
100ml

Penentuan nilai viskositas relative (ᶯr)

Waktu Air toluene murni (t0) = 0.6766
Waktu air larutan 0.75% (t) = 0.20

ᶯ t 0.20
ᶯr =
ᶯ0
=
t0
=
0.6766
= 0.2955

ᶯsp = ᶯr -1
= 0.2955 – 1
= -0.7045

ᶯsp −0.7045
ᶯred = C
= 0.795
= 0.8861

Tabel 2

Larutan konsentrasi ᶯr ᶯsp ᶯred

%
1.00 1.0600 0.3394 -0.6606 -0.8309
0.75 0.795 0.2955 -0.7045 -0.8861
0.50 0.53 0.1697 -0.8303 -0.4151
0.25 0.265 0.0848 -0.9152 -1.1511

[ᶯ] = KMV2
dengan K = 1.1 x 10-4 k/cm3 g-1
dan a = 0.725
maka :
0.2333 = 1.1x10-4 . MV0.725
0.2333 – 1.1x10-4 = MV0.725
-0.8667 x 10-4 = 0.725 log MV
-Log 0.8667 x 104 = 0.725 Log MV
620.555 = Log MV
MV = 2.7928 g/mol
= 0.0279 mg/mol
Tabel 3

Larutan Konsentrasi ᶯred K

% g/ml
1.00 1.0600 -0.8309 -24.6342
0.75 0.795 -0.8861 -25.9120
0.50 0.53 -0.4151 -15.0092
0.25 0.265 -0.1511 -32.0462

Penentuan Konstanta Huggens : −1.0692

=
0.0432
ᶯred = [ᶯ] + K’ [ᶯ]2 C
= -24.6342
(0.75)
(0.5)
ᶯred − [ᶯ]
𝐾 =
[ᶯ]. [ᶯ]𝑥 𝐶 (−0.4151)−0.2333
K = [0.2333].[0.2333]𝑥
0.795
−0.8861−0.2333
= [0.2333].[0.2333]𝑥 0.795 −0.6484
= 0.0432
−1.1194
= = -15.0092
0.0432

K = -25.9120 (0.25)

(1,0) −1.1511 − 0.2333

K =
0.0432
(−0.8309)−0.2333
K(100%) =
[0.2333].[0.2333]𝑥 0.795 = -32.0462
Tabel 4.

Konse
α β ro2 r2 so2 s2
ntrasi
1,0 -0,3850
0,75 -0,3777
0,50 -0,4530
0,25 -0,3519

(1,00) (0,50)

0,2333 0,2333
α3 = α3 =
−24,6342 𝑥 (0,0275)1⁄2 𝑔⁄𝑚𝑜𝑙 −15,0092 𝑥 (0,0279)1⁄2 𝑔⁄𝑚𝑜𝑙

0,2333 0,2333
= =
−4,1139 −2,5065

= -0,0371 = -0,0930

= 0,3850 α = -0,4530

(0,75)

0,2333 (0,25)
α3 =
−25,9120 𝑥 (0,0275)1⁄2 𝑔⁄𝑚𝑜𝑙
0,2333
α3 =
0,2333 −32,0462 𝑥 (0,0239)1⁄ 𝑔
= 2 ⁄𝑚𝑜𝑙
−4,3273

0,2333
= -0,0539 =
−5,3517

α = -0,3777 = -0,0436

α = 0,3519
penentuan betha

ᶇ = ø . α3 . β3 . µv1/2 . Mo3/2

dimana Mo = ½ BM Polistirena

= 1/2 . 0,0275

= 0,01395

Ø = 2,86x10 23

(1,0)

0,2333

β3 = (2,86x10 23) x (-0,0571) x (0,0279) 1/2

(0,01395) 3/2

0,2333

β3 = (2,86x10 23) x (-0,0571) x 0,1670

0,001647

0,2333

β3 = (2,86x10 23) x (-0,0571) x 101,3964

0,2333

β3 = (2,86x10 23) x (-5,7897)

0,2333

β3 = -16,5585 x 10 23

β3 = -0,01408 x 10 -23

β = -0,2414 x 10 -8
(0,75)

[n]

β3 = Ø . µv ½ . α 3

Mo 3/2

0,2333

β3 = (2,86x10 23) x (-0,0539) x (0,0279) 1/2

(0,01395) 3/2

0,2333

β3 = (2,86x10 23) x (-0,0539) x 0,1670

0,001647

0,2333

β3 = (2,86x10 23) x (-0,0539) x 101,3964

0,2333

β3 = (2,86x10 23) x (-5,4652)

0,2333

β3 = -1,5630 x 10 24

β3 =
-0,1496x10 -24

β = -0,5305 x 10 -8

(0,50 %)

0,2333

β3 = (2,86x10 23) x (-0,0930) x (0,0279) 1/2

(0,01395) 3/2
 0,2333

β3 = (2,86x10 23) x (-0,0930) x 0,1670

0,001674

0,2333

β3 = (2,86x10 23) x (-0,0930) x 101,3964

0,2333

β3 = (2,86x10 23) x (-9,4298)

0,2333

β3 = -26,9692 x 10 -23

β3 = -0,0086 x 10 -23

β = -0,2052 x 10 -8

(0,25%)

0,2333
β3 = (0,0279)1⁄2
(2,86 𝑥 1023)𝑥−0,0436 𝑥
(0,01395)3⁄2

0,2333
= 0,1670
(2,86 𝑥 10 23)𝑥−0,0436
0,001647

0,2333
=
2,86 𝑥 10 23 𝑥−4,4208

0,2333
=
−12,6434 𝑥 10 23

Β = -0,018452 x 1023 = β = -0,2642 x 10-8

(0,50) Penentuan nilai r0

Penentuan niali r0 Mv
r0 = α2 β2 Mo
Mu
r02 = α2 β2 0,0279
Mo r02= (-0,3850)2 x (-0,2052x10-8) x
0,01395
r02 = (0,4530)2 x (-0,2052 x 10-8)2 x
= 0,1402 x (0,0421 x 10-16) x 2
0,0279
0,01395
= 0,0124 x 10-16

= 0,2052 x (-0,0421 x 10-16) x 2

Penentuan nilai r
= 0,0173 x 10-16
r2 = r02 x α2

Penentuan nilai r
r2 = (0,0124 x 10-16) x (-0,3850)2

r2 = r0 x α2
r2 = 0,0018 x 10-16

= (0,0173 x 10-16) x (0,4530)2

Penentuan nilai S02
-16
= 0,0035 x 10
𝑟02 0,0124 x 10−16
S02 = = = S02 = 0,0020
6 6

Penentuan nilai SO2 x 10-16

r02
SO2 = Penentuan S2
6

(0,0173 x 10−16)
= S2 = α2 x SO2
6

= ( -0,3850)2 x (0,0020 x 10-16)

= 0,0029 x 10-16

= 0,1482 x (0,0020 x 10-16)

= 0,00029 x 10-16
Penentuan S2

S2= α2 SO2 (0,25)

= (-0,4530)2 x (0,0029 x 10-16) Penentuan nilai r0

Mv
= -0,2052 x (0,0029 x 10-16) r0 = α2 β2 Mo

= 0,0007 x 10-16 0,0279

r02= (-0,3519)2 x (-0,2642x10-8) x
0,01395
(1,00)
 = 0,1238 x (-0,0698 x 10-16) x 2 (0,75)

= 0,0172 x 10-16 Penentuan nilai r0

Penentuan nilai r Mv
r0 = α2 β2 Mo

r2 = r02 x α2 0,0279
r02= (-0,3777)2 x (-0,53052x10-8) x
0,01395
r2 = (0,0172 x 10-16) x (-0,3519)2
= 0,1426 x (-0,2814 x 10-16) x 2
2 -16
r = 0,0022 x 10
= 0,080 x 10-16

Penentuan nilai r
Penentuan nilai S02
r2 = r02 x α2
𝑟02 0,0172 x 10^−16
S02 = =
6 6
r2 = (0,0862 x 10-16) x (-0,3777)2
= 0,0028 x 10-16
r2 = 0,0114x 10-16

Penentuan nilai S02

Penentuan S2 𝑟02 0,0802 x 10^−16
S02 = = = 0,0134x 10-
6 6
S2 = α2 x SO2 16

= ( -0,3519)2 x (0,0028 x 10-16)

Penentuan S2
= 0,1238 x (0,0028 x 10-16)
S2 = α2 x SO2
= 0,00003 x 10-16
= ( -0,3777)2 x (0,0134 x 10-16)

= 0,1426x (0,0134 x 10-16)

= 0,0019 x 10-16