6 CARIBBEAN EXAMINATIONS COUNCIL ADVANCED PROFICIENCY EXAMINATION (CHEMISTRY. id Paper 0) 90 msiret aE TS) READ THE FOLLOWING INSTRUCTIONS CAREFULLY. “This tat consists of 45 items. You will have 90 binutes to answer thera, fl enswer shect and 2 Dats Booklet. In addition to this test booklet, you should have Each itcm in this tos has four suggested answei ‘you are about to answer and decide which choi ‘On your answer sheet, find the mamber which of having the same letter as the answer you have fs best. Look atthe sample item below. ‘Sample item Which of the following is the HIGHEST energy rinsition in an organic compound? GP atoce ‘Sample Answer (B) nton © cos ©2000 io oe ‘The best answer to this item is “orto a", so answet space (C) has been shaded. | HF you went to change your answer, be sure to erasé it completely before you fill in you! choice. ‘When you we told to begin, turn the page and work as quickly and as carefilly ws vou ep. IF you cannot answer an item, orat and go on to thelcext one. You ean come back to the or item ater. Your score will be the total number of garrect answers, i You may do any rough work ia this booklet, Figures are not necessarily drawn to seale The use of silent, non-progeammuble: ealeulators ix allowed, TOLD TO DO.SO, DO _NOT TURN THIS PAGE UNTIL YOU Al eral (A), (B),(C)-(D). Rend eal item izesponds to your item and shade the pace new itedBalt boas ItwasNOT part ofDalton’s atomicthedty 2, Aradioactive element, M, of mass number that atoms ‘A, and atomio number Z| indexgoes decay, followed by « decay. The final (A) ae indivisible clement, N, will be (@) ae characterised by their sp umber whe (©) of an element have ident properties t @ “tN (©) ofan clement dite from those df other elements | © BAN | @ EN t Item 3 refers to the following diagrams. | | i i i “a @|| © ) ‘The electronié configuration ofthe ele L. ‘with atomic number 20 (Z,= 20) is given by (A) tet 288 pt 368 3p at I © wewsya |) © Is? 2s" Qp* 3s? Spt 4s! 4p! (D) Is? 2s? 2p? 3s? 3p) da! 3d? i Which of the following solids has « giant molecular lattice’? | | (A) Carbon dioxide (B) Copper oxide (C}— Magnestum oxide (0} Silicon dioxideWhich of the following describes potsssium bromide? (A) A actwork of covalently bonded ‘atoms (B) A substance which boils at 59°C and decomposes at high tempera- tures (A solié with a very high molar enthalpy of vaporization end, in 4 liquid state, does not conduct clectricity (D) — Anon-conducting solid which melts to form liquid that conducts alectricity ‘The equation for the reaction of magnesium with hydrochloric acid is, Mg(s)+ 24"(eq)—+ Me™ (aq) + H(8) “The molar volumeofa gasatet.p.=24¢dm? ‘The votume of gas produced when [.2.g0f Mag reacts at om termporature and pressure is (AY Lad (8) 24d (C) © 12.0dm" (D) 24.0 dee Which of the following is TRUE about 3 din’ of hydrogen and 5 den’ of oxygen at O°Gand 101 kPa? {A} They react to produces $ den! of water (B) They possess the same amount of kintic energy. (©) ‘They contain the sume eumber of molecul (2) ‘They eeact completely with eael ‘ter Ia the following redox reactions involving chromium compounds, whats thy oxidation ‘umber of chromium in EACH cpmpound? Naor ltt 0, > Necro, — CHO? andwater —-HS0, G0, | NaGo, Tle,0* @l 3 +6 +6 es a 6 © | +6 +6 @) +3 +6 =6 ‘When 86 g of the ionic salt, CeS(), 21,0, is heated co that all ofits water of crystallisation is drivenoff and 68.0g 0fCaSO, tema, the value of xis fat @ 2 © 3 © 4 HEV ENRCPEVCLILE NEWT One