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  • Thermodynamic analysis of SO2 oxidation reaction at varying temperatures and pressures

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    David Zarate Mansilla
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    The document contains data from experiments on the reaction of sulfur dioxide (SO2) with oxygen (O2) to produce sulfur trioxide (SO3) at different temperatures and pressures. It provides the reaction quotient (K), conversion (X), and molar fractions of reactants and products for temperatures ranging from 750 to 1061.3784 K under pressures of 1, 5, and 7.5 atm. The data shows that higher temperatures and pressures favor the production of more SO3 and less unreacted SO2 and O2.

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    The document contains data from experiments on the reaction of sulfur dioxide (SO2) with oxygen (O2) to produce sulfur trioxide (SO3) at different temperatures and pressures. It provides the reaction quotient (K), conversion (X), and molar fractions of reactants and products for temperatures ranging from 750 to 1061.3784 K under pressures of 1, 5, and 7.5 atm. The data shows that higher temperatures and pressures favor the production of more SO3 and less unreacted SO2 and O2.

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    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
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    3 views6 pages

    Thermodynamic analysis of SO2 oxidation reaction at varying temperatures and pressures

    Uploaded by

    David Zarate Mansilla
    The document contains data from experiments on the reaction of sulfur dioxide (SO2) with oxygen (O2) to produce sulfur trioxide (SO3) at different temperatures and pressures. It provides the reaction quotient (K), conversion (X), and molar fractions of reactants and products for temperatures ranging from 750 to 1061.3784 K under pressures of 1, 5, and 7.5 atm. The data shows that higher temperatures and pressures favor the production of more SO3 and less unreacted SO2 and O2.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
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    of 6

    PRESION DE 1 1(SO2) + 0.5(O2) =1(SO3) ΔG(J)RX = -96232 + 90.

    667 T,(JOULES)
    atm
    TEMPERATURA ΔG(J) K X ȠSO3 ȠO2 ȠSO2 SO3 % O2 %
    1 750 -28231.75 92.4631232 0.9402784 0.9402784 0.0298608 0.0597216 91.301504 2.89949865
    2 800 -23698.40 35.2480683 0.8896339 0.8896339 0.05518305 0.1103661 84.3108596 5.22971346
    3 850 -19165.05 15.051602 0.8143600 0.81436 0.09282 0.18564 74.519134 8.49362201
    4 900 -14631.70 7.06456993 0.7141450 0.714145 0.1429275 0.285855 62.4838408 12.5053864
    5 950 -10098.35 3.59064822 0.5955701 0.5955701 0.20221495 0.4044299 49.5394023 16.8201992
    6 1000 -5565.000 1.95274734 0.47166 0.47166 0.26417 0.52834 37.3098555 20.8967148
    7 1061.3784 0.00 1 0.33334 0.33334 0.33333 0.66666 25.0005625 24.9998125

    PRESION DE 5
    atm
    TEMPERATURA ΔG(J) K X ȠSO3 ȠO2 ȠSO2 SO3 % O2 %
    1 750 -28231.75 9.2462E+01 0.83587 0.83587 0.082065 0.16413 77.24767 7.58411001
    2 800 -23698.40 3.5248E+01 0.713813 0.713813 0.1430935 0.286187 62.4457229 12.5180924
    3 850 -19165.05 1.5052E+01 0.560881 0.560881 0.2195595 0.439119 45.990458 18.0031807
    4 900 -14631.70 7.0646E+00 0.403737 0.403737 0.2981315 0.596263 31.1013946 22.9662018
    5 950 -10098.35 3.5906E+00 0.27072 0.27072 0.36464 0.72928 19.8381991 26.7206003
    6 1000 -5565.000 1.9528E+00 0.174312 0.1743122 0.4128439 0.8256878 12.3376829 29.2207724
    7 1061.3784 0.00 1.0000E+00 0.10024 0.10024 0.44988 0.89976 6.91367561 31.0287748
    PRESION DE 7.5
    atm
    TEMPERATURA ΔG(J) K X ȠSO3 ȠO2 ȠSO2 SO3 % O2 %
    1 750 -28231.75 9.2462E+01 0.791239 0.79123879 0.10438061 0.20876121 71.6454804 9.45150653
    2 800 -23698.40 3.5248E+01 0.629589 0.6295885 0.18520575 0.3704115 53.120608 15.626464
    3 850 -19165.05 1.5052E+01 0.477385 0.477385 0.2613075 0.522615 37.8484232 20.7171923
    4 900 -14631.70 7.0646E+00 0.3216 0.3216 0.3392 0.6784 24.0143369 25.3285544
    5 950 -10098.35 3.5906E+00 0.203506 0.203506 0.398247 0.796494 14.554367 28.4818777
    6 1000 -5565.000 1.9528E+00 0.125572 0.125572 0.437214 0.874428 8.7371818 30.4209394
    7 1061.3784 0.00 1.0000E+00 0.069873 0.069873 0.4650635 0.930127 4.76928133 31.7435729

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    750 800 850 900
    ) RANGO T. [718-2273],K

    SO2 % ǷSO3 ǷO2 ǷSO2 ΔG(J) K X K


    5.7989973 0.91301504 0.02899499 0.05798997 -28231.8 92.4631232 0.94027885 92.4631402165
    10.4594269 0.8431086 0.05229713 0.10459427 -23698.40 35.2480683 0.8896337 35.2480765281
    16.987244 0.74519134 0.08493622 0.16987244 -19165.1 15.051602 0.81436 15.0521455505
    25.0107728 0.62483841 0.12505386 0.25010773 -14631.70 7.06456993 0.714145 7.064672752
    33.6403985 0.49539402 0.16820199 0.33640398 -10098.4 3.59064822 0.595501 3.5893732102
    41.7934297 0.37309855 0.20896715 0.4179343 -5565.000 1.95274734 0.47166 1.9528844469
    49.999625 0.25000563 0.24999812 0.49999625 0.00 1 0.33334 1.0000337504

    SO2 % ǷSO3 ǷO2 ǷSO2 ΔG(J) K X K


    15.16822 0.7724767 0.0758411 0.1516822 -28231.8 92.4631232 0.83587 92.4631024002
    25.0361847 0.62445723 0.12518092 0.25036185 -23698.40 35.2480683 0.713813 35.2480811525
    36.0063613 0.45990458 0.18003181 0.36006361 -19165.1 15.051602 0.560881 15.0516421404
    45.9324036 0.31101395 0.22966202 0.45932404 -14631.70 7.06456993 0.403737 7.0645760846
    53.4412006 0.19838199 0.267206 0.53441201 -10098.4 3.59064822 0.27072 3.5906488644
    58.4415447 0.12337683 0.29220772 0.58441545 -5565.000 1.95274734 0.1743122 1.9527024683
    62.0575496 0.06913676 0.31028775 0.6205755 0.00 1 0.10024 1.0000047584
    SO2 % ǷSO3 ǷO2 ǷSO2 ΔG(J) K X K
    18.9030131 0.7164548 0.09451507 0.18903013 -28231.8 92.4631232 0.7912388 92.4631125331
    31.252928 0.53120608 0.15626464 0.31252928 -23698.40 35.2480683 0.6295885 32.2480330627
    41.4343846 0.37848423 0.20717192 0.41434385 -19165.1 15.051602 0.477385 15.0516015562
    50.6571087 0.24014337 0.25328554 0.50657109 -14631.70 7.06456993 0.3216 7.0645786216
    56.9637553 0.14554367 0.28481878 0.56963755 -10098.4 3.59064822 0.203506 3.5906383456
    60.8418788 0.08737182 0.30420939 0.60841879 -5565.000 1.95274734 0.125572 1.9527367902
    63.4871458 0.04769281 0.31743573 0.63487146 0.00 1 0.069873 1.000001148

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    900 950 1000 1061.3784

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