Examples: Glucose ma
Glucenic add es hoy NONHCas
Glucaric avid (also called saccharic acid) t + R-C-R’
Glucuranic acid (a
Gluctl (aio cad sorb) {
Osone Phenylhydrazone.
Mannose
Mannonie acid 5 aera)
Monnarie acid (al acchane ai Aa
Monger ecto agen Aan er synthesis (lengthening of carbon chain
Manito) of aldese)
(1) HEN
Reachons of aldoses & ketases: 0 a Boe Ho
ita (
oa y
(®) Oxidation using Tollens’, Fehling’s , and Benedicts rt, (eHor, 02 Nala), Con (CHOW net
‘Aldose Tollens’/Fehling/ Benedict rah leer HOH CHOW
ore Composition —(¢) Ruff ion (shortening the carb aldose)
ie
Tollens gt. = Ag(NHS)E cu,0 a a en pie tt
Fehling’s rgt. = copper(I) tartrate , OH 1 (9 Ha0, Feo* {
Benedict’ rat, = copper(It) citrate, OH” (200 ae (CHO
( Oxidation wsing bromine water vo Ca0H
Aldose re Aldonic acid
ea 2. Disacchanides
Kebse —2@2_, nore
: () ()-Maltose. - eammanly known as alt sugar
(8) Oxidation using HNOs = obtained by partial hydciysis of starch
Aidore ENOL A\daric acid
Ketose N03, no nin
(4) Osazone formation
1 ‘
beo E=N-NHC Hs
1 BCalishite
, > CN=NHC CH,
a phenphydrazine ots
Aldose Osazone
+ CGHsNly + Nit
in aqueous acid, or by diastase -cata—
lyzed hydrolysis of starch in its fermen~
tation 4p yield ethan.
~ @ reducing sugar:
Stach 82" 5 -Mattse
Stach 20 5 EtOH + (-Maltose
diastare
ut
maltese + 120 D-()-Gluave
(2 mel)
Mattase