Sones ouice Dpetimet 7 ATO (Chem 31.1) 1. Give Fhe balanced equations of all the reaches. AcLucas Test \-Etnyt alconel | CasOR + HOA BS Ao oun (clear colorees soln) Feo.27, 2019 assem 2 eal nee 2. \sopmpyt ateohel: (CH3),CHOH + ACK 2 (omg), CHA £ HO eee 9 Tert-boty| aledkel: Cat sCOH F Hel 2 Condscea +H.0 20 Sees 4. Benay\ cde! Cos caOW + HOA Be Co Hg CHIC FO Cree OP .OKydakon of Moshols 2 Erver A \. Hm) Kloohol . CatgOH + eNnOg 9 CH, COOH + tho + Maar K 3. Wepogyt otcohed’ & (CHs)aCHOH + KMACa —> ACOs aCe + 2 HO F MnOr+ KY 4, Text: buty| atednol apo + Mada 7 NVR 4. Benny! adcahol | Cos ClHa OH 4 KMn Og > Cols COOH + Ha OFMAO2 FKY 5. Diethy\ etner (cargpO + Kinoy 9 NVR C. Reackion of Phenols \+ Phenol &- Cots ON + 3Br2 7 CottsOW Br, + BHF b. Cots OH + KMnOg > Cota?a + WnOa + HzO +e €. GCgHgOH + FEC, > Tee Core teed + 344 43cr a. p> Nittephencl A: SCoBSNOg + FeO3 7 FeCCoM4NO3), + 3H 3. 97 Brome phenol a DBrCatson * As 7 Fe Cerca t4O), + HCI 4.b- Nogathol OO. 3 CyoHOH tT FeCy 7 Fe CCrey)5 + BRC] a. Explain why Locas test eg yicable only 40 alekels contoiriing, Sor less carbons, pan dak 6 pec Mor rene Ree SRP EAT iad, ORE eo Se ere og tre reagot for *he react Yo hapgen. 1+ applies ony to atcohds that cre, sobble with the reocjent Wn or d& gr the chloamadion Ccaction of the alcobcl to occur. Lycos ceagers (ZnCl, ond Helis polar ond only AissoWer fo hight polar alcohols o compourss with les non-polar rps. Howing Mere Seca 7 5S coubors makes 0 NONPIO ohadral, making Lucas test only applicable +o ahoondls w/ 5 carkons-3. txplain why sero olconds ond erhecs comet undergo oxidady ust petassim permonganare on RON reaction Oxidation ccovre depending on stawility om alcohols i+ increases as “the no. oF Aiky| Suestitvert of tre carbon where tne Wydronide 1s loonctecdd i Ncreases, It can ren we arranged in terme of increading stability ax: tertony alcohol 7 secon dovy odceha ) pamowy alcohol - Per: con oxidize pam ony oohols but net tertiory alcohols because of Vis ofeak stability iy cannot remove viectvons from it. This oso applies 40 ethers. Festiony alconals C&C -OR) comndt BO VE oxdized because Ws corbon chow ‘eondedd, jo cupen doesn's bear a. hydrogen Om. Red gor chess ( R-O-R), the CxUEN en cxrom cot hay O CREME ester intermediate Cor ctrer aiitoiole fearing QrvP nate) fours. com 6 nor bonded TOF 4, Exploin tne cClakonstiig between Yhe Stwctvees of He phenolic compounds with Weir expecttd pH valves: ave retive oddity af phenck defends On the substtetion af te hydroxyl hytege arom, and by electron withdrawing substivers te Awe hychoxy| yO? - Ke Yre, decton- nrdroniing, aor ncreases; Khe benzene mg becomes Moe postively cheged Aherefore making tre comparnd more acid \n phenol, tere As ong, tection withdrawing PrHiWopherol, there Ore pice acid , Here ore ce gmp (-0n) fwo (+ CH and -NO2) making Hrmere acidic than pre! gor (ro and daree - NOz) making * the stongeT Regescnccs st // scr nee s-ecto/paibtavan (2425 \4. 995 «http: // chem. Xe0u. edu.on/teach! yj Wx / chem /O22 wins turbid sole B. Oxidation of Alcohols and Ether Test Sample ‘Observation Ethyf alcohol dealotization occur agier heating Isopropyl alcohol decolofzation scour w/ block precipitate Tert-butyl alcohol we Benzyl alcohol dealorg ation wi) bIock preciyitnle Diethyl ether ave C. Reaction of Phenols* Test Sample | pH Brz in H20 Neutral KMinO. FeCl Phenol 3 | wie pecipiate] aecsioiention wwtite ‘P-Nitrophenol 2 = = pope Picric acid \ = = = p-Bromophenol | — am = Bacio ioasiebie -Naphthol = = = yellow ‘indicate observations for applicable phenol derivatives only