ORGANIC CHEMISTRY Total Marks : 35 D P P DPP No. 31 Max. Time : 37 min. Topic : Hydrocarbon Type of Questions Single choice Objective (‘-1' negative marking) Q.1 to 0.6 Comprehension ('—1' negative marking) Q7 to Q.9 Match the Following (no negative marking) Q. 10 4. Which acid will not decarboxylate on heating ° Il I C-OH C-OH oO oO “ ® ©) cH, 2. The major product of the following reaction is Min, (3 marks 3 min.) ——_[18, 18] @marks 3 min) —_—[9, 9} (@marks 10min.) —_—[8, 10} COOH cooH need Na/ether Br, / ho 1 @ a a ® U © wv 3. The end product of following reaction is (05 (B)LIAIH, (5) PBta (excess) (@)Me,SHO” ~ (4)R Ba LIB 4. Which of the following will form cyclohexane on reaction with two moles of Na in ether. — = (©) Br-CH,-cH.-cI ©) CHy¢-CH,-COOH ° CH.0°/C.H.OH, A @ © oO Mgfether tq HCOOEt (6) HeI7) , ofr ; -CH-CH,-CH.-Cl © a) ey cH, 6. Ho—p —_Bp/hv products, products may be H.C—H GH, CH, CH, CH, Hp H—p p+ (a) HC—}—Br ®@Br——cH, (©) CH} Br (©) Both and B CH, GH, CH.cl Which of the following is / are the possible products “ One) ®) 3 © CO ©) Co Comprehension # (Q. No. 7 to 9) 10. ‘Observe the following sequence of reactions. 9 eine [7 Y (maior product) N2/Emer, 7 Aa cntsols 09 20 on Y, (minor product) Identity ° AAA oy ony © AY None ‘The no, of major product/s (Y,) and number of minor product/s (Y.) will be respectively (Include stereoisomers) (A) 2,2 2,1 ©1,3 (1,2 The structure of Z (obtained from major product Y,) will be ack @AnW~Y ook © ay Column- Column-tt (A) Bakelite () Butadiene and styrene ©) Dacron (@ Phenol and methanal (©) Nylon-66 (9 1,2-dihydroxyethane and dimethyl terepthalate (0) Buna-s (8) 1,6-hexanedioic acid and 1 6-diamine hexaneDPP No. # 31 1 &W 2 ®) Cn) 4 © a} 6* (AB) z © a @ 2 # 10. (A-a); 8-9; (C-5);O-p) DPP No. #31 1. Bridge has carbon sp* __Na/ether Br, tho ge C.H,C°/ C.H,OH. & BRAK ay @) 3) 0 (005 _ ual % a (2)Me.$ 1 HO aH H? MOP Hage tee Oe Ma/Ether o So ait Brg: @ick) pe | © Cl Cl. CO » Com OO OC a+ oO a Sooaime , \~ _ Bry /no —T Na/ether x OH (-CO,) (x) (2) Br (3) a +(V) @) “Spr Y)