EC Exercise -1 J ‘At constant temperature, in 2 given mass of an ideal gas - (A) The ratio of pressure and volume always remains constant (8) Volume always remains constant (C) Pressure always remains constant (0) The product of pressure and volume always remains constant Three flasks of equal volumes contain CH, CO; and Cl, gases respectively. They will contain equal number of molecules if - (A) the mass of all the gases is same (B) the moles of all the gas is same but temperature Is different (C) pressure of all the flasks are same (0) temperature, pressure are same in the frasks. A certain mass of a gas occupies a volume of 2 litres at STP. Keeping the pressure constant at what temperature would the 92s occupy a volume of 4 litres - (A) 546°C (8) 273°C (C) 1009¢ (0) Soe If 500 mi of a gas, ‘A’ at 1000 torr”and 1000 ml.of gas:8 at 800 torr are placed in 2 2L container, the final pressure will be- (A) 10Dstorr (8), 650 torr (C) 1800 torr (D) 2400 torr Two flasks A and B of S00 mi each are respectively filled with 0, and SO, at 300 K and 1 atm. pressure. The flasks will contain- (A) The same number of atoms (8) The same number of molecules (C) More number of moles in flask A as compared to flask B () The same amount of gases In the gas equation PV = MRT, the value of universal gas constant would depend only (A) The nature of the gas (B) The pressure of the gas (C) The temperature of the gas (D) The units of measurement 7. a. 13. OBJECTIVE PROBLEMS (JEE MAIN) ] A0.5 dm? flask contains gas ‘A’ and 1 dm? flask contains gas ‘8’ at the same temperature. If density of A = 3.0 gm dm? and that of B = 1.5 gm dm-3 and the molar mass of A = 1/2 of B, then the ratio of pressure exerted by gases is- (A) Pi/Py = 2 (8) Py/Py = 1 (C) P,/Py = 4 (D) P,/Py = 3. When the pressure of SL of N, is doubled and its temperature is raised from 300K to 600K, the final volume of the gas would be- (A) 10.L (O15 L (8) SL (0) 200 If the pressure of a gas contained in a closed vessel in increased by 0.4% when heated by 1°C its initial temperature must be = (A) 250k. (8) 250°C (c) 25°€ (0) 25k ‘A thin ballon filled with air at 47°C has a vol- lume of 3 litre. If on placing it in a cooled room its volume becomes 2.7 litre, the tempera- ture of room is (a) 422 (cy asec (8) 100°C (D) 200°C If a mixture containing 3 moles of hydrogen ‘and 1 mole of nitrogen is converted completely into ammonia, the ratio of initial and final volume under the same temperature and pres~ sure would be: (A321 (Ey2ia (ay1:3 (o)1:2 ‘SO, at STP contained in a flask was repleced by'©, under identical conditions of pressure, temperature and volume. Then the weight of 0, will be $0, (A) hat (C) twice (8) one fourth (D) four times Assuming that O, molecule Is spherical in shape with radius’ 2X, the percentage of the volume of ©, molecules to the total volume of 2s at S.T.P is : (A) 0.09% (C) 0.009% (8) 0.9% (2) 0.045%14. 15. 16. 17. 18. 19. ‘Two flasks of equal volume are connected by a narrow tude (of negligible volume) all at 27°C and contain 0.70 mole of H, at 0.5 atm. One of the flask is then immersed into a bath kept at 127°C, while the other remains at 27°C. The final pressure in each flask is (A) Final pressure = 0.5714 atm (B) Final pressure = 1.5714 atm (C) Final pressure = 0.5824 atm (0) None of these ‘Two flasks of equal volume are connected by 2 narrow tube (of negligible volume) all at 27°C and contain 0.70 moles of H, at 0.5 atm. One of the flask is then immersed into a bath kept at 127° C, while the other remains at 27°C . The number of moles of H, in flask 1 and flask 2 are : (A) Moles in flask 1 = 0.4, Moles in flask 2 = 0.3 (6) Moles in lask 1 = 0.2, Moles in flask 2 = 0.3 (C) Moles in flask 1 = 0.3, Moles in flask 2 = 0.2 (0) Motes in flask = 1.0.3, Moles in flask 2 = 0.2 ‘Agas is heated from 0°C to 100°C at 0.1 atm Pressure .If the initial volume of the gas is 10.0 /, its final volume would be : (A) 7.32 / (8) 10.00 + (C) 13.66 + () 20.00, Under what'€onditions will.a pure:sample of an ideal gas not only exhibit a pressure of 1 ‘atm but also a concentration of 1 mol litre”. [R = 0.0892 litre atm mot K-!] (A) at STP (B) when V = 22.42 L (C) when T = 12K (0) impossible under any condition ‘A.and B are two identical vessels. A contains 15 g ethane at 1atm and 298K. The vessel 8 contains 75 g of a gas X, at same tempera- ture and pressure. The vapour density of X, is: (A) 75, (8) 150 (c) 37.5 (0) 45 The density of neon will be highest at : (a) STP (8) 0°C, 2 atm (C) 273°C. 1 atm (D) 273°C.2 atm 20. A0.5 dm flask contains gas A and 1 dm’ flask contains gas B at the same temperature. If density of A = 3 g/dm? and that of B= 1.5 9/ dm? and the molar mass of A = 1/2 of B, the ratio of pressure exerted by gases is: ®, °, 2 (8) eet , (ce -4 (0) 3 DALTONS LAW OF PARTIAL PRESSURE 22. Acylinderis filled with a gaseous mixture con- taining equal masses of CO and N,. The par- tial pressure ratio is : (A) Pr, = Peo (8) Peo = 0.875Fy, (C)Peo=2Py (0) Feo = 3, 22. A gas X diffuses three. times faster than another gas ¥ the ratio of their densities ise, Dy Dy iss at Pot ms 230" AtSTP, acontainer has 1 mole of Ar, 2 moles, of CO, 3 moles of O, and 4 moles of N,. Without changing the total pressure if one mole of O, is removed, the partial pressure of 0, : (A) Is changed by about 26 % (8) is halved (C) is unchanged (0) changed by 33 % 24, Equal weights of ethane & hydrogen are mixed in an empty container at 25°C, the fraction of the total pressure exerted by hydrogen is : ~ (ayaa (c) 1:16 (0) 15: 16 25. Amixture of hydrogen and oxygen at one bar Dressure contains 20% by weight of hydro- gen. Partical presure of hydrogen will be : (A) 0.2 bar (8) 0.4 bar (©) 0.6 bar (0) 0.8 bar‘A compound exists in the gaseous phase both ‘2s monomer (A) and dimer (A,). The atomic mass of Ais 48 and molecular mass of A, is 96. In an experiment 96 9 of the compound was confined in a vessel of volume 33.6 litre and heated to 237°C. The pressure developed If the compound exists as dimer to the extent of 50% by weight under these conditions will be (8) 2 atm (A) 1 atm (0) 4 atm (C)1.5 atm GRAHAMS LAW OF DIFFUSION 27. 3. Three footballs are respectively filled with ni trogen, hydrogen and helium. If the leaking ‘of the gas occurs with time from the filing hhole, then the ratio of the rate of leaking of 925€S (Th, ?THy :tHe) from three footballs (in ‘equal time interval) is (A) bi: Via= 07) (8) (Via 7:1) (C) 7:4: V4) (D) fa: V7: a) The rates of diffusion of SO,, CO,, PCI, and ‘SO, are in the following order- (A) PCL, > $0, > $0, > CO, (8) CO, > 50, > Pa, > SO, {C) 0, > SO, > PCI, > CO, (0) CO; > SO} > SO} > Pat, 20 / of S0,, diffé8es through a porous parti- tion in 60 Seconds. Volume of O, diffuse un- der similar conditions in 30 seconds will be : (A) 12444 (8) 14.14¢ (C) 18.147 (0) 28.147 See the figure “He The valves of X and Y opened simultaneously. The white furnes of NH,CI will first form at (AA eB mc (D) A,B and C simultaneously X mi of H, gas of effuses through a hole in a container'in 5 sec. The time taken for the ef- fusion of the same volume of the gas speci- fied below under identical conditions is : (A) 10sec. He (B) 20 sec. 0, (C) 25sec. Co, (0) $5 sec. Cd, KINETIC THEORY OF GASES 32. 33. 37. ‘At what temperature will the total KE of 0.3 ‘mol of He be the same as the total KE of 0.40 mol of Ar at 400K ? (A) 533 K (C) 346K (8) 400 K (0) 300 k By how many folds the temp of a gas would Increase when the rm.s. velocity of gas molecules in a dosed container of fixed volume Is increased from 5 x 104 cm s“! to 10 x 104 cm sl~ (A) 0.5 times (©) 4 times (8) 2 times (0) 16 times. The root mean square velocity of an ideal gas in a closed container of fixed volume Is increased from 5 x 104 cm. s“! to 10 x 10* cm. s“!. Which of the following statements might correctly explain how the change accomplished - (A) By heating the ga doubled (B), By" heating the gas, the pressure is made four times (C) Bysheating the gas, the volume is tripled (D) By heating the ga: doubled. the temperature is the pressure is The temperature of an ideal gas is increased from 140 K to $60 K. If at 140 K the root-mean square velocity of the gas molecules is V, at 560 K it becomes : (a) SV (8) 2V (C) W2 (0) wa Which of the following gas molecules has the longest mean-free path ? a) H, (8) N () 0, (0) ci, Temperature at which rm.s. speed of O, is ‘equal to that of neon at 300 K Is : (a) 280k (8) 480k (c) 680K (0) 180k The R.M.S speed of the molecules of 9 gas of density 4 kg rr? and pressure 1.2 % 10% Nm? is: (A) 120 mst (8) 300 ms (C) 600 ms" (D) 900 ms-*