IX.

Reaksi dan Perhitungan

9.1 Reaksi
R – CHO + 2CuO Cu2O + RCOOH
CuO + H2SO4 CuSO4 + H2O
2CuSO4 + 4KI CuI2 + 2K2SO4 + I2
I2 + 2Na2S2O3 Na2SO4O6 + 2NaI
9.2 Perhitungan
9.2.1 Sampel A (Susu Kental Manis)
Vblanko - Vsampel
V(d-a) = x NNa-thiosulfat
0,1 N
11,9 mL-8,3 mL
= x 0,1 N
0,1 N

= 3,6 mL
ΔGlukosa = 3,6 mg
Massa = ( Vsampel + ∆glukosa )+ V(d-a)

= (8,3 mL x 3,6 mg)+3,6

= 33,48 mg
= 0,03348 gram
gram karbohidrat
%Karbohidrat = gram sampel x Fp x 100
0,03348 gr
= x 1 x 100%
2 gr

= 0,016%
= 1,886%
9.2.2 Sampel B (Susu Cair)
Vblanko - Vsampel
V(d-c) = x NNa-thiosulfat
0,1 N
11,9 mL - 4 mL
= x 0,1 N
0,1 N

= 7,9 mL
Δglukosa = 7,9 mg
Massa = ( Vsampel + ∆glukosa )+ V(d-c)

= (4 mL x 7,9 mg)+ 7,9 mg

= 39,5 mg
 = 0,0395 gram
gram karbohidrat
%Karbohidrat = gram sampel x Fp x 100%

0,0395gr
= x 1 x 100%
2 gr
= 0,019%
9.2.3 Sampel C (Susu Bubuk)
Vblanko - Vsampel
V(d-c) = x NNa-thiosulfat
0,1 N
11,9 mL - 2,8 mL
= x 0,1 N
0,1 N

= 9,1 mL
Δ glukosa = 9,1 mg
Massa = ( Vsampel + ∆glukosa )+ V(d-c)

= (2,8 mL x 9,1 mg)+ 9,1 mg

= 34,58 mg
= 0,0345 gram
gram karbohidrat
%Karbohidrat = x Fp x 100%
gram sampel
0,0345gr
= x 1 x 100%
2 gr

= 0,017%